Membrane and Water Treatment

Techno-Press (테크노프레스)
권호 표지
DOI QR코드

DOI QR Code

Adsorptive separation of adipic acid from aqueous solutions by perlite or its composites by manganese or copper

  • Uslu, Hasan (Beykent University, Engineering and Architecture Faculty, Chemical Engineering Department) ;
  • Demir, Goksel (Bahcesehir University, Engineering Faculty, Environmental Engineering Department) ;
  • Bayat, Cuma (Istanbul Esenyurt University, Engineering and Architecture Faculty, Industrial Engineering Department) ;
  • Wasewar, Kailas L. (Advance Separation and Analytical Laboratory (ASPAL), Department of Chemical Engineering, Visvesvaraya National Institute of Technology) ;
  • Bamufleh, Hisham S. (Department of Chemical & Materials Engineering, Faculty of Engineering, King Abdulaziz University)
  • Received : 2014.05.16
  • Accepted : 2014.10.30
  • Published : 2014.10.25
⟨ Previous Next ⟩

Abstract

Adipic acid (hexane-1,6-dioic acid) is one of the most used chemical in industrial applications. This must be separated from any environmental contaminant. In this study, adipic acid separation from wastewater by adsorption method onto Perlite or Perlite + Mn or Perlite + Cu composites was investigated. Adsorption of Adipic acid was investigated in terms of equilibrium, and thermodynamic conditions. For thermodynamic investigations the experiments carried out at three different temperatures (298 K, 318 K, 328 K). In the equilibrium studies, 2 g of perlite and its composites were determined as the optimal adsorbent amount. Freundlich and Langmuir isotherms were applied to the experimental data. Freundlich isotherms for all temperatures used in this work gave some deviations with R square values under 0.98 where as Langmuir isotherm gave good results with R square values upper 0.99 at different temperatures. As a result of thermodynamic studies, adsorption enthalpy (${\Delta}H$), adsorption entropy (${\Delta}S$), and adsorption free energy (${\Delta}G$) have been calculated for each adsorbents.

Keywords

References

  1. Akkaya, R. (2013), "Effects of pH, concentration and temperature on radionuclides sorption onto polyhydroxyethyl methacrylate-expanded perlite composite", J. Radio. Nucl. Chem., 295(1), 351-355. https://doi.org/10.1007/s10967-012-1868-x
  2. Demirbas, A., Sari, A. and Isildak, O. (2006), "Adsorption thermodynamics of stearic acid onto bentonite", J. Hazard. Mat., 135(1-3), 226-231. https://doi.org/10.1016/j.jhazmat.2005.11.056
  3. Freundlich, H. (1906), Uber die Adsorption in Losungen, Wilhelm Engelmann, Germany, 57, pp. 385-470.
  4. Ghassabzadeh, H., Torab-Mostaedi, M. and Ghaemi, A. (2010), "Characterizations of Co (II) and Pb (II) removal process from aqueous solutions using expanded perlite", Desalination, 261(1-2), 73-79. https://doi.org/10.1016/j.desal.2010.05.028
  5. Khan, A.A. and Singh, R.P. (1987), "Adsorption thermodynamics of carbofuran on Sn (IV) arsenosilicate in $H^+$, $Na^+$ and $Ca^{2+}$ forms", Colloid Surf., 24(1), 33-42. https://doi.org/10.1016/0166-6622(87)80259-7
  6. Khoiruddin, K., Hakim, A.N. and Wenten, I.G. (2014), "Advances in electrodeionization technology for ionic Separation-A review". Membr. Water Treat., Int. J., 5(2), 87-108. https://doi.org/10.12989/mwt.2014.5.2.087
  7. Langmuir, I. (1916), "Constitution and fundamental properties of solids and liquids", J. Am. Chem. Soc., 38(11), 2221-2295. https://doi.org/10.1021/ja02268a002
  8. Melita, L., Gumrah, F. and Amaeanu, M. (2014), "Porous polymer membranes used for wastewater treatment", Membr. Water Treat., Int. J., 5(2), 147-170. https://doi.org/10.12989/mwt.2014.5.2.147
  9. Norwitz, G., Nataro, N. and Keliher, P.N. (1987), "Steam distillation of phenolic compounds in the presence of a large amount of sodium chloride", Microche. J., 35(2), 240-243. https://doi.org/10.1016/0026-265X(87)90081-6
  10. Rajoriya, R.K., Prasad, B., Mishra, I.M. and Wasewar, K.L. (2007), "Adsorption of benzaldehyde on granular activated carbon: Kinetics, equilibrium, and thermodynamic", Chem. Biochem. Eng. Q., 21(3), 219-226.
  11. Sari, A., Sahinoglu, G. and Tuzen, M. (2012), "Antimony(III) adsorption from aqueous solution using raw perlite and Mn-modified perlite: Equilibrium, thermodynamic, and kinetic studies", Ind. Eng. Chem. Res., 51(19), 6877-6886. https://doi.org/10.1021/ie300243n
  12. Silber, A., Bar-Yosef, B. and Suryano, S. (2011), "Zinc adsorption by perlite: Effects of pH, ionic strength, temperature, and pre-use as growth substrate", Geoderma, 170, 159-167.
  13. Thanh, D.N., Mandeep, S. and Ulbrich, P. (2011), "Perlite incorporating gamma-Fe2O3 and alpha-MnO2 nanomaterials: Preparation and evaluation of a new adsorbent for As(V) removal", Sep. Pur. Tech., 82, 93-101. https://doi.org/10.1016/j.seppur.2011.08.030
  14. Terry, R.E., Li, N.N. and Ho, W.S. (1982), "Extraction of phenolic compounds and organic acids by liquid membranes", J. Memb. Scien., 10(2-3), 305-323. https://doi.org/10.1016/S0376-7388(00)81416-7
  15. Torab-Mostaedi, M., Ghaemi, A. and Ghassabzadeh, H. (2011), "Removal of strontium and barium from aqueous solutions by adsorption onto expanden perlite", Canad. J. Chem. Eng., 89(5), 1247-1254. https://doi.org/10.1002/cjce.20486
  16. Tuyun, A.F. and Uslu, H. (2001), "Extraction equilibria of picolinic acid from aqueous solution by tridodecylamine (TDA)", Desalination, 268(1-3), 134-140.
  17. Uslu, H. and Demir, G. (2010), "Adsorption of Picric Acid from Aqueous Solution by the Weakly Basic Adsorbent Amberlite IRA-67", J. Chem. Eng. Data, 55(9), 3290-3296. https://doi.org/10.1021/je100088u
  18. Uslu, H., Gok, A. and Kirbaslar, S.I. (2008), "Phase equilibria of (water + levunilic acid + alcohol) ternary systems", Fluid Phase Equilibria, 273(1-2), 21-26. https://doi.org/10.1016/j.fluid.2008.08.004
  19. Uslu, H., Inci, I. and Bayazit, S.S. (2010), "Adsorption Equilibrium Data for Acetic Acid and Glycolic Acid onto Amberlite IRA-67", J. Chem. Eng. Data, 55(3), 1295-1299. https://doi.org/10.1021/je900635z
  20. Zvezdelina, Y., Bogdana, K. and Nedyalka, G. (2012), "Study of the mechanism of nitrophenols sorption on expanded perlite-equilibrium and kinetic modelling", Maced. J. Chem. Chem. Eng., 31(1), 101-104.

Cited by

  1. Equilibrium and kinetic studies on the adsorption of copper onto carica papaya leaf powder vol.7, pp.5, 2016, https://doi.org/10.12989/mwt.2016.7.5.403