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실리카졸의 표면 전하 밀도와 염료 흡착과의 상관성

Relationship between the Adsorption of Dye and the Surface Charge Density of Silica Sol

  • 조경숙 (한국세라믹기술원 에너지환경소재본부) ;
  • 이동현 (한국세라믹기술원 에너지환경소재본부) ;
  • 임형미 (한국세라믹기술원 에너지환경소재본부) ;
  • 김대성 (한국세라믹기술원 에너지환경소재본부) ;
  • 이승호 (한국세라믹기술원 에너지환경소재본부)
  • Cho, Gyeong Sook (Energy Environment Materials Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Lee, Dong-Hyun (Energy Environment Materials Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Lim, Hyung Mi (Energy Environment Materials Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Dae Sung (Energy Environment Materials Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Lee, Seung-Ho (Energy Environment Materials Division, Korea Institute of Ceramic Engineering and Technology)
  • 투고 : 2014.11.12
  • 심사 : 2014.12.23
  • 발행 : 2014.12.27

초록

In this study, we investigated the relationship between the adsorption property of Methyl violet or Tartrazine dye onto silica sol surface and surface charge density of the sol. The adsorption ratio of Methyl violet dye on silica sol decreased to 74% and 92% for the 68nm and 94nm silica sol, respectively, at dye concentration of $175{\mu}g/m^2$. However, the adsorption ratio of Tartrazine dye on 68nm and 94nm silica sol was about 0% for both of them. The surface charge density is $-0.40C/m^2$, $-0.26C/m^2$ for 68nm and 94nm silica sol, respectively. The amount of Methyl violet dye adsorbed on silica sol increased with an increase of surface charge density of particle at the same concentration of the dye. The adsorbed amount of the silica having high surface charge density is larger at high pH domain. But adsorbed amount of the silica having low surface charge density is larger at low pH domain.

키워드

참고문헌

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피인용 문헌

  1. Enhancement of Dyeing Fastness of Artificial Suede (3) vol.28, pp.4, 2016, https://doi.org/10.5764/TCF.2016.28.4.280
  2. Surface Modification of Nanofiltration Membrane with Silane Coupling Agents for Separation of Dye vol.28, pp.6, 2018, https://doi.org/10.14579/MEMBRANE_JOURNAL.2018.28.6.414