DOI QR코드

DOI QR Code

Electrochemical Diagnosis of Magnesium Ion in Fish Liver and Mice Droppings

  • Lee, Chang-Hyun (Division of General Education, Pyeongtaek University) ;
  • Ly, Suw Young (Biosensor Research Institute, Seoul National University of Technology)
  • 투고 : 2014.11.19
  • 심사 : 2014.12.11
  • 발행 : 2014.12.30

초록

An in-vivo diagnosis of trace Mg(II) ion was performed using a low-cost and environment-friendly voltammetric method, using a graphite counter and reference electrodes and a fluorine-immobilized graphite working electrode, and clean deep seawater was used as an electrolyte solution. Under optimum conditions, the analytical working ranges attained microgram ranges, and a detection limit of $80.6ugL^{-1}$ was obtained using stripping voltammety with 60 sec accumulation time. Ex-vivo application was performed on fish liver and mice droppings. The developed techniques can be applicable to tumor cell analysis.

키워드

참고문헌

  1. M. Benamor, N. Aguerssif imultaneous determination of calcium and magnesium by derivative spectrophotometry in pharmaceutical products", Spectrochimica Acta Part A 69; 676-681 (2008). https://doi.org/10.1016/j.saa.2007.05.020
  2. Sema Bagdat Yasar, Seref Gucer Fractionation analysis of magnesium in olive products by atomic absorption spectrometry", Analytica Chimica Acta 505; 43-49 (2004). https://doi.org/10.1016/S0003-2670(03)00573-7
  3. Federica I. Wolf, Achille R.M. Cittadini, Jeanette A.M. Maier Magnesium and tumors: Ally or foe, Cancer Treatment Reviews 35; 378-382 (2009). https://doi.org/10.1016/j.ctrv.2009.01.003
  4. Nils-Erik L. Saris, Eero Mervaala, Heikki Karppanen, Jahangir A. Khawaja, Andrzei Lewenstam Magnesium An update on physiological, clinical and analytical aspects", Clinica Chimica Acta 294; 1-26 (2000). https://doi.org/10.1016/S0009-8981(99)00258-2
  5. Pierre Bracconi, Cyrille Andres, Augustin N'iaye, Yvette Pourcelot Thermal analyses of commercial magnesium stearate pseudopolymorphs", Thermochimica Acta 429; 43-51 (2005). https://doi.org/10.1016/j.tca.2004.11.021
  6. Yukitaka kato, Fu-uta Takahashi, Akihiko watanabe, Yoshio Yoshizawa Thermal analysis of a magnesium oxide/water chemical heat pump for congeneration", Applied Thermal Engineering 21; 1067-1081 (2001). https://doi.org/10.1016/S1359-4311(00)00103-4
  7. S.Y. Liu, J.D. Hu, Y. Yang, Z.X. Guo, H.Y. Wang Microstructure analysis of magnesium alloy melted by laser irradiation, Applied Surface Science 252 ; 1723-1731 (2005). https://doi.org/10.1016/j.apsusc.2005.03.110
  8. M. BenamorS, N. Aguerssif Simultaneous determination of calcium and magnesium by derivative spectrophotometry in pharmaceutical products", Spectrochimica Acta Part A 69; 676-681 (2008). https://doi.org/10.1016/j.saa.2007.05.020
  9. S. Motellier, S. Petit, P. Decambox Quantitative capillary electrophoretic analysis for calcium and magnesium in sodium-atrix waters", Analytica Chimica Acta 410; 11-23 (2000). https://doi.org/10.1016/S0003-2670(99)00897-1
  10. Yueying Zhen, Kay B. Franz, Steven W. Graves novel assay of cell rubidium uptake using graphite furnace atomic absorption: Application to rats on a magnesium-deficient diet", Journal of Nutritional Biochemistry 16; 291-296 (2005). https://doi.org/10.1016/j.jnutbio.2005.01.005
  11. S. Motellier, S. Petit, P. Decambox Quantitative capillary electrophoretic analysis for calcium and magnesium in sodium-atrix waters", Analytica Chimica Acta 410; 11-3 (2000). https://doi.org/10.1016/S0003-2670(99)00897-1
  12. Sema Bagdat Yasar, Seref Gucer Fractionation analysis of magnesium in olive products by atomic absorption spectrometry", Analytica Chimica Acta 505; 43-49 (2004). https://doi.org/10.1016/S0003-2670(03)00573-7
  13. Shi Ouyang, Murthy A. Vairavamurthy Effect of magnesium ion in the analysis of carboxylated compounds by electrospray-mass spectrometry", Analytica Chimica Acta 422; 101-112 (2000). https://doi.org/10.1016/S0003-2670(00)01059-X
  14. Brett Paull, Miroslav Macka, Paul R. Haddad Determination of calcium and magnesium in water samples by high-performance liquid chromatography on a graphitic stationary phase with a mobile phase containing o-cresolphthalein complexone", Journal of Chromatography A 789; 329-337 (2009).
  15. Toyohide Takeuchi, Shiro Inoue, Mamie Yamamoto, Miharu Tsuji, Tomoo Miwa Fluorimetric determination of magnesium and aluminum via complexation with oxine in high-performance liquid chromatography", Journal of Chromatography A 910; 373-76 (2001). https://doi.org/10.1016/S0021-9673(00)01209-7
  16. Zeriet O. Tesfaldet, Jacobus F. van Staden, Raluca I. Stefan Spectrophotometric determination of magnesium in pharmaceutical preparations by cost-effective sequential injection analysis", Talanta 64; 981-988 (2004). https://doi.org/10.1016/j.talanta.2004.04.026
  17. N. Abo El-Maali, D. Abd El-Hady, M. Abd El-Hamid, M.M. Seliem Use of adsorptive stripping voltammetry at the glassy carbon electrode for the simultaneous determination of magnesium(II) and aluminium(III) Application to some industrial samples", Analytica Chimica Acta 417; 67-75 (2000). https://doi.org/10.1016/S0003-2670(00)00916-8
  18. Wen Qian, Ji-Hua Zhuang, Yun-Hua Wang, Zhong-Xian Huang The effect of magnesium ion on the electrochemistry of cytochrome and cytochrome b5 at a gold electrode modified with cysteine", Journal of Electroanalytical Chemistry 447; 187-199 (1998). https://doi.org/10.1016/S0022-0728(98)00043-6
  19. Othman A. Farghaly "A novel method for determination of magnesium in urine and water samples with mercury film-plated carbon paste electrode", Talanta 63; 497-501 (2004). https://doi.org/10.1016/j.talanta.2003.12.022
  20. Wei Gao, Junfeng Song, Naiying Wu Voltammetric behavior and square-wave voltammetric determination of trepibutone at a pencil graphite electrode", Journal of Electroanalytical Chemistry 576; 1-7 (2005). https://doi.org/10.1016/j.jelechem.2004.09.026
  21. Alan M. Peter J. Mahona, Jorg Schiewe Victoria Vicente-Beckett "An inexpensive and renewable pencil electrode for use in field-based stripping voltammetry", Analytica Chimica Acta 345; 67-74 (1997). https://doi.org/10.1016/S0003-2670(97)00102-5
  22. D. Demetriades, A. Economou, A. Voulgaropoulos "A study of pencil-lead bismuth-film electrodes for the determination of trace metals by anodic stripping voltammetry", Analytica Chimica Acta 519; 167-172 (2004). https://doi.org/10.1016/j.aca.2004.05.008
  23. Suw Young Ly Diagnosis of copper ions in vascular tracts using a fluorine-doped carbon nanotube sensor, Talanta 74; 1635-164 (2008). https://doi.org/10.1016/j.talanta.2007.10.017