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A Study of the Permeation Test Method for the Evaluation of Protective Clothing against Chemical Warfare Agent Simulants

화학보호복의 생화학 유사작용제 투과저항성 평가 방법 개발

  • Received : 2014.05.12
  • Accepted : 2014.10.20
  • Published : 2014.12.31

Abstract

Non-military researchers and civil manufacturers face several difficulties in the study of protective materials for chemical-biological defense. The performance of these materials cannot be estimated in non-governmental circles as the private use of chemical warfare agents (CWAs), such as GD (soman) and HD (mustard), by civilians is not permitted. The barrier properties of protective materials can be evaluated only in military laboratories, by the TOP 8-2-501 test method, using real CWAs. In this study, the permeation of CWA simulants such as dimethyl methyl phosphonate (DMMP), triethyl phosphate (TEP), and chloroethyl phenyl sulfide (CEPS) was investigated by the chemical permeation test method. Moreover, permeation of the CWA simulants through different samples of protective materials could be estimated by the proposed cumulative permeation measurements, using an absorbent tube.

Keywords

References

  1. ASTM F739, "Standard Test Method for Permeation of Liquids and Gases through Protective Clothing Materials under Conditions of Continuous Contact", 2012.
  2. EN 374-3, "Protective Gloves against Chemicals and Micro- Organisms. Determination of Resistance to Permeation by Chemicals", 2003.
  3. ISO 6529, "Protective Clothing - Protection against Chemicals - Determination of Resistance of Protective Clothing Materials to Permeation by Liquids and Gases", 2013.
  4. J. A. Glaser, "Chemical Warfare Agent Stimulants", Crti Rev Environ Sci Technol, 2008, 38, 112-136. https://doi.org/10.1080/10643380701643650
  5. Y. Sun and K. Y. Ong, "Detection Technologies for Chemical Warfare Agents and Toxic Vapors", CRC Press, Florida, 2005.
  6. W. E. Steiner, S. J. Klopsch, W. A. English, B. H. Clowers, and H. H. Hill, "Detection of Chemical Warfare Agent Simulant in Various Aerosol Matrixes by Ion Mobility Time of Flight Mass Spectrometry", Anal Chem, 2005, 77, 4792-4799. https://doi.org/10.1021/ac050278f
  7. D. Matatagui, J. Marti, M. J. Fernandez, J. L. Fontecha, J. Gutierrez, I. Racia, C. Cane, and M. C. Horrillo, "Chemical Warfare Agents Simulants Detection with an Optimized SAW Sensor Array", Eurosensors XXIII, 2011, 154, 199-205.
  8. T. Pal, G. D. Griffin, G. H. Miller, A. P. Watson, M. L. Daugherty, and T. V. Dinh, "Permeation Measurements of Chemical Agent Simulants through Protective Clothing Materials", J Hazard Mater, 1993, 33, 123-141. https://doi.org/10.1016/0304-3894(93)85067-O
  9. E. J. Park and Y. D. Kim, "Adsorption and Desorption of Chemical Warfare Agent Simulants on Silica Surfaces with Hydrophobic Coating", Bull Korean Chem Soc, 2013, 34, 1967-1971. https://doi.org/10.5012/bkcs.2013.34.7.1967
  10. D. Rivin, R. S. Lindsay, W. J. Shuely, and A. Rodriguez, "Liquid Permeation Through Nonporous Barrier Materials", J Memb Sci, 2005, 246, 39-47. https://doi.org/10.1016/j.memsci.2004.06.057
  11. R. A. Jenkins, M. V. Buchanan, R. Merriveather, R. H. Iigner, T. M. Gayle, J. H. Moneyhun, and A. P. Watson, "Protocol for Determination of Chemical Warfare Agent Simulant Movement through Porous Media", Oak Ridge National Laboratory, Tennessee, 1992.
  12. TOP 8-2-501, "Permeation and Penetration Testing of Air- Permeable, Semipermeable and Impermeable Materials with Chemical Agents or Stimulants(Swatch testing)", U.S. Army Test and Evaluation Command Test Operation Procedure, AD No. A322329, 1997.
  13. "Chempack Fabric, Selectively Permeable Chemical Warfare Protective Material - The Science behind the Technology", Brochure of Chempack Fabric, W. L. Gore, Associates, Inc., Elkton, MD, 2001.
  14. NFPA 1994, "Standard on Protective Ensembles for First Responders to CBRN Terrorism Incidents", National Fire Protection Association, USA, 2012.