Korean Journal of Food Science and Technology (한국식품과학회지)

Korean Society of Food Science and Technology (한국식품과학회)
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Study of Molecular and Crystalline Structure and Physicochemical Properties of Rice Starch with Varying Amylose Content

아밀로오스 함량이 다른 쌀 전분의 분자 및 결정 구조와 이화학적 특성

  • You, Su-Yeon (Department of Food and Nutrition and Research Institute for Human Ecology, Chonnam National University) ;
  • Lee, Eun-Jung (Department of Food and Nutrition and Research Institute for Human Ecology, Chonnam National University) ;
  • Chung, Hyun-Jung (Department of Food and Nutrition and Research Institute for Human Ecology, Chonnam National University)
  • 유수연 (전남대학교 식품영양학과.생활과학연구소) ;
  • 이은정 (전남대학교 식품영양학과.생활과학연구소) ;
  • 정현정 (전남대학교 식품영양학과.생활과학연구소)
  • Received : 2014.07.14
  • Accepted : 2014.09.01
  • Published : 2014.12.31
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Abstract

The in vitro digestibility and molecular and crystalline structures of rice starches (Seilmi, Dasan1, and Segoami) with differing amylose content were investigated. Segoami had the highest amylose content (30.9%), whereas Dasan1 had the lowest amylose content (21.2%). The molecular weight ($\bar{M}_w$) of amylose and amylopectin in Segoami was much lower than that of the other two rice starches. Segoami had the highest proportion (8.7%) of amylopectin short branch chains (DP 6-12) and the lowest proportion of B1 chains (DP 13-24). The relative crystallinity, intensity ratio of $1047-1022cm^{-1}$ (1047/1022) and gelatinization enthalpy followed the order: Segoami>Seilmi~Dasan1. Segoami showed substantially low pasting viscosity. Rapidly digestible starch (RDS), slowly digestible starch (SDS), and resistant starch (RS) contents showed the highest value in Seilmi, Dasan1, and Segoami, respectively. The expected glycemic index (eGI) of Segoami was lower than that of the other two rice starches. Overall results suggested that the digestibility of rice starch could be highly influenced by their molecular and crystalline structure.

국내에서 육종된 아밀로오스 함량이 다른 3가지 쌀 품종의 전분 특성을 살펴봄으로써 새로운 식품 소재의 개발을 위한 기초자료로 활용하고자 전분의 분자 및 결정 구조적 특성과 소화 특성을 조사하였다. 새고아미 전분은 다산1호나 새일미에 비해 아밀로오스 함량, 아밀로펙틴의 짧은 사슬(DP 6-12) 함량, 페이스팅 온도, RS 함량이 유의적으로 높았으며 반대로 아밀로오스의 중합도, 아밀로오스와 아밀로펙틴의 분자량, 아밀로펙틴의 B1사슬(DP 13-24), 상대적 결정성, 입자표면 결정성(1047/1022), 팽윤력, 호화 온도($T_o$, $T_p$, $T_c$), 호화 엔탈피, 페이스팅 점도(최고점도, 최종점도, 강하점도, 치반점도), RDS 함량, eGI값이 유의적으로 낮았다. 다산1호는 새일미에 비해 낮은 RDS 함량과 높은 SDS 함량을 보였다. 두 쌀 전분의 소화율의 차이는 분자 구조적 특성(아밀로오스 함량, 아밀로오스 중합도, 분자량, 아밀로펙틴 분자의 가지사슬 길이 분포)과 결정 구조적 특성(상대적 결정성, 1047/1022, 호화 온도와 엔탈피)의 차이에 근거하였다. 결과적으로 3가지 국내산 쌀 품종들의 전분 분자 및 결정 구조적 특성과 소화율 결과는 다양한 유형의 쌀을 이용한 가공제품 개발의 기초자료로 활용될 수 있을 것으로 기대된다.

Keywords

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