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Thin Metal Electrodes for Semitransparent Organic Photovoltaics

  • Lee, Kyu-Sung (School of Engineering for Matter, Transport, and Energy (SEMTE), Arizona State University (ASU), Components & Materials Research Laboratory, ETRI) ;
  • Kim, Inho (SEMTE, ASU, Electronic Materials Research Center, KIST) ;
  • Yeon, Chang Bong (Components & Materials Research Laboratory, ETRI, Department of Advanced Device Engineering, University of Science and Technology) ;
  • Lim, Jung Wook (Components & Materials Research Laboratory, ETRI, Department of Advanced Device Engineering, University of Science and Technology) ;
  • Yun, Sun Jin (Components & Materials Research Laboratory, ETRI, Department of Advanced Device Engineering, University of Science and Technology) ;
  • Jabbour, Ghassan E. (SEMTE, ASU, Solar and Alternative Energy Engineering Research Center, King Abdullah University of Science and Technology)
  • Received : 2012.12.13
  • Accepted : 2013.06.19
  • Published : 2013.08.01

Abstract

We demonstrate semitransparent organic photovoltaics (OPVs) based on thin metal electrodes and polymer photoactive layers consisting of poly(3-hexylthiophene) and [6,6]-phenyl $C_{61}$ butyric acid methyl ester. The power conversion efficiency of a semitransparent OPV device comprising a 15-nm silver (Ag) rear electrode is 1.98% under AM 1.5-G illumination through the indium-tin-oxide side of the front anode at 100 $mW/cm^2$ with 15.6% average transmittance of the entire cell in the visible wavelength range. As its thickness increases, a thin Ag electrode mainly influences the enhancement of the short circuit current density and fill factor. Its relatively low absorption intensity makes a Ag thin film a viable option for semitransparent electrodes compatible with organic layers.

Keywords

References

  1. G. Li, R. Zhu, and Y. Yang, "Polymer Solar Cells," Nature Photonics, vol. 6, Mar. 2012, pp. 153-161. https://doi.org/10.1038/nphoton.2012.11
  2. N.-M. Park, H.S. Lee, and J. Kim, "Reactive Sputtering Process for $CuIn_{1-x}Ga_xSe_2$ Thin Film Solar Cells," ETRI J., vol. 34, no. 5, Oct. 2012, pp. 779-782. https://doi.org/10.4218/etrij.12.0212.0062
  3. S.-I. Na et al., "Efficient and Flexible ITO-Free Organic Solar Cells Using Highly Conductive Polymer Anodes," Adv. Mater., vol. 20, no. 21, Nov. 2008, pp. 4061-4067. https://doi.org/10.1002/adma.200800338
  4. F.C. Krebs, "Roll-to-Roll Fabrication of Monolithic Large-Area Polymer Solar Cells Free from Indium-Tin-Oxide," Solar Energy Mater. Solar Cells, vol. 93, no. 9, Sept. 2009, pp. 1636-1641. https://doi.org/10.1016/j.solmat.2009.04.020
  5. R.F. Bailey-Salzman, B.P. Rand, and S.R. Forrest, "Semitransparent Organic Photovoltaic Cells," Appl. Phys. Lett., vol. 88, no. 23, June 2006, pp. 233502.1-233502.3.
  6. F.-C. Chen et al., "Polymer Photovoltaic Devices with Highly Transparent Cathodes," Organic Electron., vol. 9, no. 6, Dec. 2008, pp. 1132-1135. https://doi.org/10.1016/j.orgel.2008.08.007
  7. K.-S. Chen et al., "Semi-transparent Polymer Solar Cells with 6% PCE, 25% Average Visible Transmittance and a Color Rendering Index Close to 100 for Power Generating Window Applications," Energy Environ. Sci., vol. 5, no. 11, Aug. 2012, pp. 9551-9557. https://doi.org/10.1039/c2ee22623e
  8. J.-Y. Lee et al., "Semitransparent Organic Photovoltaic Cells with Laminated Top Electrode," Nano Lett., vol. 10, no. 4, Mar. 2010, pp. 1276-1279. https://doi.org/10.1021/nl903892x
  9. D. Han et al., "Realization of Efficient Semitransparent Organic Photovoltaic Cells with Metallic Top Electrodes: Utilizing the Tunable Absorption," Opt. Express, vol. 18, no. S4, Nov. 2010, pp. A513-A521. https://doi.org/10.1364/OE.18.00A513
  10. V. Shrotriya et al., "Efficient Light Harvesting in Multiple-Device Stacked Structure for Polymer Solar Cells," Appl. Phys. Lett., vol. 88, no. 6, Feb. 2006, pp. 064104.1-064104.3.
  11. J. van de Lagemaat et al., "Organic Solar Cells with Carbon Nanotubes Replacing $In_2O_3$:Sn as the Transparent Electrode," Appl. Phys. Lett., vol. 88, no. 23, June 2006, pp. 221008.1-221008.3.
  12. X. Wang, L. Zhi, and K. Müllen, "Transparent, Conductive Graphene Electrodes for Dye-Sensitized Solar Cells," Nano Lett., vol. 8, no. 1, Dec. 2008, pp. 323-327. https://doi.org/10.1021/nl072838r
  13. B. O'Connor et al., "Transparent and Conductive Electrodes Based on Unpatterned, Thin Metal Films," Appl. Phys. Lett., vol. 93, no. 22, Dec. 2008, pp. 223304.1-223304.3.
  14. M.C. Scharber et al., "Design Rules for Donors in Bulk-Heterojunction Solar Cells-Towards 10% Energy-Conversion Efficiency," Adv. Mater., vol. 18, no. 6, Mar. 2006, pp. 789-794. https://doi.org/10.1002/adma.200501717
  15. P. Zhao et al., "Properties of Thin Silver Films with Different Thickness," Physica E, vol. 41, no. 3, Jan. 2009, pp. 387-390. https://doi.org/10.1016/j.physe.2008.08.062
  16. J. Meiss, M.K. Riede, and K. Leo, "Optimizing the Morphology of Metal Multilayer Films for Indium Tin Oxide (ITO)-Free Inverted Organic Solar Cells," Appl. Phys. Lett., vol. 105, no. 6, Mar. 2009, pp. 063108.1-063108.3.
  17. H.B. Yang et al., "New Architecture for Accurate Characterization of the Behavior of Individual Sub-Cells within a Tandem Organic Solar Cell," Energy Environ. Sci., vol. 1, no. 3, June 2008, pp. 389-394. https://doi.org/10.1039/b805140b

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