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SWRO 해수담수화 공정에서 전처리된 수질조건이 SDI에 미치는 영향

Effect of Pretreated Seawater Quality on SDI in SWRO Desalination Process

  • Son, Dong-Min (Department of Environmental Engineering, Pukyong National University) ;
  • Kang, Lim-Seok (Department of Environmental Engineering, Pukyong National University)
  • 투고 : 2012.05.11
  • 심사 : 2013.03.05
  • 발행 : 2013.03.30

초록

전처리 공정은 막의 오염 정도를 제어할 수 있는 유일한 방법이다. 막의 오염 현상은 피할 수 없는 중요한 문제이며 RO 공급수로 적합한 전처리 공정의 선택이 중요하다. 본 연구는 pH, 해수의 탁도, 수온, 응집제 주입량 그리고 SDI 측정 막재질과 같은 SDI 값에 영향을 미치는 인자들을 평가 하기위해 수행되었다. 그 결과 해수의 탁도는 여과수의 SDI 값에 약간의 영향을 미친것으로 조사되었다. 0.45 um 공극 크기를 가지는 SDI 측정 막은 소수성 막 보다 동일한 재질의 친수성 막을 이용하는 것이 분석 결과의 신뢰성과 재현성을 확보할 수 있었다. pH 7.0 이하의 조건에서 pH가 감소할수록 SDI 값은 증가한 것으로 나타났다. 그리고 수온은 SDI 값은 큰 영향을 미친것으로 조사되었다.

Pretreatment process is the critical step of RO (Reverse Osmosis) membrane desalination plant in order to prevent RO membrane fouling. The pretreatment as a key component of RO process must be designed to produce a constant and high quality RO feedwater which has low silt density index (SDI). This experiment was conducted to assess parameters affecting SDI value, such as pH, seawater turbidity, temperature, and coagulant dose. The experimental results indicated that the source seawater turbidity did cause little effects on SDI values of filtered water. The 0.45 um hydrophilic membrane was more appropriate than the hydrophobic membrane for measuring SDI. The SDI value was increased with decreasing pH under the condition of below pH 7.0. In addition, the water temperature significantly affected the SDI values, showing higher SDI value with lower water temperature.

키워드

참고문헌

  1. Bates, W. T. and Cuozzo, R., Integrated membrane systems. Hydranautics Available from: http://www.membranes.com/ docs/papers/01_ims.pdf (accessed 17.05.08.)(2000).
  2. Brehant, A., Bonnelye, V. and Perez, M., "Assessment of ultrafiltration as a pretreatment of reverse osmosis membranes for surface seawater desalination," Water Sci. Technol.: Water Supply, 3(5-6), 437-445(2003).
  3. Bonnelye, V., Sanz, M. A., Durand, J. -P., Plasse, L., Gueguen, F. and Mazounie, P., "Reverse osmosis on open intake seawater: pre-treatment strategy," Desalination, 167, 191-200 (2004). https://doi.org/10.1016/j.desal.2004.06.128
  4. Reverter, J. A., Talo, S. and Alday, J., "Las Palmas III-the success story of brine staging," Desalination, 138, 207-217 (2001). https://doi.org/10.1016/S0011-9164(01)00266-1
  5. Rybar, S., Vodnar, M., Vartolomei, F. L., Me´ndez, R. L. and Ruano, J. B. L., "Experience with Renewable Energy Source and SWRO Desalination in Gran Canaria," SP05-100. International Desalination Association World Congress. Available from: http://www.membranes.com/docs/papers/New%20Folder/Soslaires%20Canarias%20Desalination%20Plant.pdf (accessed 25.05.08.)(2005).
  6. Bu-Rashid, K. A. and Czolkoss, W., "Pilot tests of multipore UF membrane at Addur SWRO desalination plant," Bahrain. Desalination, 203, 229-242(2007). https://doi.org/10.1016/j.desal.2006.04.010
  7. Chua, K. T., Hawlader, M. N. A. and Malek, A., "Pretreatment of seawater: results of pilot trials in Singapore," Desalination, 159, 225-243(2003). https://doi.org/10.1016/S0011-9164(03)90075-0
  8. Ando, M., Ishiara, S., Iwahori, H. and Tada, N., "Peculiar or Unexpected Behavior of Silt Density Index of Pretreated Seawater for RO Desalination," Proceedings of IDA World Congress, Bahamas BAH03-071(2003).
  9. Mosset, A., Bonnelye, V., Petry, M. and Sanz, M. A., "The sensitivity of SDI analysis: from RO feed water to raw water," Desalination, 222, 17-23(2008). https://doi.org/10.1016/j.desal.2007.01.125
  10. Fritzmann, C., Wenberg, J., Wintgens, T. and Melin, T., "State- of-the-art of reverse osmosis desalination," Desalination, 216, 1-76(2007). https://doi.org/10.1016/j.desal.2006.12.009
  11. Standard Test Method for Silt Density Index (SDI) of water, D 4189-95 ASTM.
  12. Wilf, M. and Bartels, C., "Integrated membrane desalination systems-current status and projected development," Hydranautics Available from: http://www.membranes.com/docs/papers/ New%20Folder/Abstract%20for%20Tianjin%20-%20Hydrana utics.pdf (accessed 17.05.08.)(2006).
  13. Amirtharajah, A. and O'Melia, C. R., "Coagulation process: destabilization, mixing, and flocculation," In Water Quality and Treatment, 4th Ed., McGraw-Hill, NY(1990).
  14. Kim, S., Lee, I. S., Kim, K. J., Shon, D. M. and Kang, L. S., "Dual media filtration and ultrafiltration as pretreatment options of low-turbidity seawater reverse osmosis processes," Desalination and Water Treatment., 33, 329-336(2011). https://doi.org/10.5004/dwt.2011.2661
  15. Wolf, P. H., Sivenns, S. and Monti, S., "UF membranes for RO desalination pretretment," Desalination, 182, 293-300 (2005). https://doi.org/10.1016/j.desal.2005.05.006
  16. Crittenden, J. C., Luft, P. J. and Hand, D. W., "Prediction of multicomponent adsorption equilibria in background mixtures of unknown composition," Water Res., 19(12), 1547-1548(1985).
  17. Tipping, E. and Malcolm, R., "Aggregation of Aquatic Humic Substance," Chem. Geol., 15(4), 463(1981).
  18. Hasson, D., Drak, A. and Semiat, R., "Inception of $CaSO_4$ scaling on RO membranes at various water recovery levels," Desalination 139, 73-81(2001). https://doi.org/10.1016/S0011-9164(01)00296-X
  19. Rahardianto, A., Shih, W. Y., Lee, R. W. and Cohen, Y., "Diagnostic characterization of gypsum scale formation and control in RO membrane desalination of brackish water," J. Membr. Sci., 279, 655-668(2006). https://doi.org/10.1016/j.memsci.2005.12.059
  20. Alhadidi, A., Kemperman, A. J. B., Blankert, B., Schippers, J. C. and Wessling, W. G. J., "Silt Density Index and Modified Fouling Index relation, and effect of pressure, temperature and membrane resitance," Desalination, 273, 48-56(2011). https://doi.org/10.1016/j.desal.2010.11.031
  21. Morris, J. K. and Knocke, W. R., "Temperature effects on the use of metal ion coagulants for water treatment," J. Am. Water Works Assoc., 76(3), 74-79(1984).
  22. Lynn, C., "Hydrolysis of Inorganic Iron(III) satls," Chem. Rev., 84, 31-41(1984). https://doi.org/10.1021/cr00059a003
  23. Hem, J. D. and Roverson, C. E., "Aluminum Hydrolysis Reaction and Products in Mildly Acidic Aqueous System," Chem. Modeling of Aqueous Syst. II, Proc., ACS Symposium Series, 416, 429-449(1990).
  24. Kang, L. S. and Cleasby, J. L., "Temperature effects on flocculation kinetics using Fe(III) coagulant," J. Environ. Eng., ASCE, 121, 893-910(1995). https://doi.org/10.1061/(ASCE)0733-9372(1995)121:12(893)