Bulletin of the Korean Chemical Society

  • 제34권8호
  • /
  • Pages.2461-2465
  • /
  • 2013
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

The Complete Oxidation of Ethanol at Low Temperature over a Novel Pd-Ce/γ-Al2O3-TiO2 Catalyst

  • Wang, Yanping (College of Chemistry and Chemical Engineering, Taiyuan University of Technology) ;
  • Zhao, Jinshuang (College of Chemistry and Chemical Engineering, Taiyuan University of Technology) ;
  • Wang, Xiaoli (College of Chemistry and Chemical Engineering, Taiyuan University of Technology) ;
  • Li, Zhe (College of Chemistry and Chemical Engineering, Taiyuan University of Technology) ;
  • Liu, Pengfei (College of Chemistry and Chemical Engineering, Taiyuan University of Technology)
  • 투고 : 2013.04.04
  • 심사 : 2013.05.27
  • 발행 : 2013.08.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Pd-$Ce/{\gamma}-Al_2O_3-TiO_2$ catalysts were prepared by combined sol-gel and impregnation methods. Transmission electron microscopy, X-ray diffraction, $H_2$-temperature-programmed reduction, $O_2$-temperature-programmed desorption, and ethanol oxidation experiments were conducted to determine the properties of the catalysts. Addition of an optimal amount of Ce improved the performance of the $Pd/{\gamma}-Al_2O_3-TiO_2$ catalyst in promoting the complete oxidation of ethanol. The catalyst with 1% Ce exhibited the highest activity, and catalyzed complete oxidation of ethanol at $175^{\circ}C$; its selectivity to $CO_2$ reached 87%. Characterization results show that addition of appropriate amount of Ce could enrich the PdO species, and weaken the Pd-O bonds, thus enhancing oxidation ability of the catalyst. Meanwhile, the introduction of $CeO_2$ could make PdO better dispersed on ${\gamma}-Al_2O_3-TiO_2$, which is beneficial for the improvement of the catalytic oxidation activity.

키워드

참고문헌

  1. Bergamaski, K.; Gonzalez, E. R.; Nart, F. C. Electrochim. Acta 2008, 53, 4396. https://doi.org/10.1016/j.electacta.2008.01.060
  2. Sobolev, V. I.; Koltunov, K. Y.; Simakova, O. A.; Leino, A.-R.; Murzin, D. Y. Appl. Catal., A 2012, 433-434, 88. https://doi.org/10.1016/j.apcata.2012.05.003
  3. Yang, J.-Il.; Lee, D.-W.; Lee, J.-H.; Hyun, J. C.; Lee, K.-Y. Appl. Catal., A 2000, 194-195, 12.
  4. Li, H. J.; Qi, G. S.; Tana; Zhang, X. J.; Huang, X. M.; Li, W.; Shen, W. J. Appl. Catal., B 2011, 103, 54. https://doi.org/10.1016/j.apcatb.2011.01.008
  5. Li, K. T.; Wang, C. K. Appl. Catal., A 2012, 433-434, 275. https://doi.org/10.1016/j.apcata.2012.05.032
  6. Reddy, B. M.; Rao, K. N.; Reddy, G. K.; Bharali, P. J. Mol. Catal. A: Chem. 2006, 253, 44. https://doi.org/10.1016/j.molcata.2006.03.016
  7. Pitkaaho, S.; Matejova, L.; Jiratova, K.; Ojala, S.; Keiski, R. L. Appl. Catal., B 2012, 126, 215. https://doi.org/10.1016/j.apcatb.2012.07.025
  8. Bottino, A.; Capannelli, G.; Comite, A.; Felice, R. D. Catal. Today 2005, 99, 171. https://doi.org/10.1016/j.cattod.2004.09.037
  9. Avgouropoulos, G.; Oikonomopoulos, E.; Kanistras, D.; Ioannides, T. Appl. Catal., B 2006, 65, 62. https://doi.org/10.1016/j.apcatb.2005.12.016
  10. Wang, W.; Zhang, H. B.; Lin, G. D.; Xiong, Z. T. Appl. Catal., B 2000, 24, 219. https://doi.org/10.1016/S0926-3373(99)00106-X
  11. Santos, V. P.; Carabineiro, S. A. C.; Tavares, P. B.; Pereira, M. F. R.; Órfão, J. J. M.; Figueiredo, J. L. Appl. Catal., B 2010, 99, 198. https://doi.org/10.1016/j.apcatb.2010.06.020
  12. Burch, R.; Urbano, F. J. Appl. Catal., A 1995, 124, 121. https://doi.org/10.1016/0926-860X(94)00252-5
  13. Yang, L. F.; Shi, C. K.; He, X. E.; Cai, J. X. Appl. Catal., B 2002, 38, 117. https://doi.org/10.1016/S0926-3373(02)00034-6
  14. Wu, Q. S.; Yang, C. S.; Chen, X. J. Rare Earth 2007, 25, 295. https://doi.org/10.1016/S1002-0721(07)60491-8
  15. Fan, X.; Wang, F.; Zhu, T.; He, H. J. Environ Sci-China 2012, 24, 507. https://doi.org/10.1016/S1001-0742(11)60798-5
  16. Son, I. H. J. Power Sources 2006, 159, 1266. https://doi.org/10.1016/j.jpowsour.2005.12.014
  17. Padilla, J. M.; Del Angel, G.; Navarrete, J. Catal. Today 2008, 133-135, 541. https://doi.org/10.1016/j.cattod.2007.12.053
  18. Gates, S. M.; Russell, J. N., Jr.; Yates, J. T., Jr. Surf. Sci. 1986, 171, 111. https://doi.org/10.1016/0039-6028(86)90565-0
  19. Sexton, B. A.; Rendulic, K. D.; Huges, A. E. Surf. Sci. 1982, 121, 181. https://doi.org/10.1016/0039-6028(82)90245-X
  20. Davis, J. L.; Barteau, M. A. Surf. Sci. 1987, 187, 387. https://doi.org/10.1016/S0039-6028(87)80064-X
  21. Idriss, H. Adv. Catal. 2000, 45, 261. https://doi.org/10.1016/S0360-0564(02)45016-X
  22. Li, Z.; Wang, J.; He, K.; An, X.; Huang, W.; Xie, K. C. Journal of Natural Gas Chemistry 2011, 20, 167. https://doi.org/10.1016/S1003-9953(10)60159-4
  23. Li, Z.; Quan, Y. H. J. Mol. Catal. 2007, 21, 417.
  24. Yue, L.; He, C.; Zhang, X. Y.; Li, P.; Wang, Z.; Wang, H. L.; Hao, Z. P. J. Hazard. Mater. 2013, 244-245, 613. https://doi.org/10.1016/j.jhazmat.2012.10.048
  25. Weyrich, P. A.; Trevino, H.; Holderich, W. F.; Sachtler, W. M. H. Appl. Catal., A 1997, 163, 31. https://doi.org/10.1016/S0926-860X(97)00114-2
  26. Han, W. L.; Zhang, P.; Tang, Z. C.; Lu, G. X. Process Saf. Environ. Prot. Accepted date: 2013, 4, 19.
  27. Luo, Y. J.; Xiao, Y. H.; Cai, G. H.; Zheng, Y.; Wei, K. M. Appl. Catal., B 2013, 136-137, 317. https://doi.org/10.1016/j.apcatb.2013.02.020
  28. Klingstedt, F.; Neyestanaki, A. K.; Byggningsbacka, R.; Lindfors, L. E.; Lunden, M.; Petersson, M.; Tengström, P.; Ollonqvist, T.; Vayrynen, J. Appl. Catal., A 2001, 209, 301. https://doi.org/10.1016/S0926-860X(00)00768-7
  29. Zhou, R.; Zhao, B.; Yue, B. Appl. Surf. Sci. 2008, 254, 4701. https://doi.org/10.1016/j.apsusc.2008.01.075
  30. Chen, Y. T.; Zheng, H. J.; Guo, Z.; Zhou, C. M.; Wang, C.; Borgna, A. J. Catal. 2011, 283, 3.
  31. Sangeetha, P.; Shanthi, K.; Rama Rao, K. S.; Viswanathan, B.; Selvam, P. Appl. Catal., A 2009, 353, 160. https://doi.org/10.1016/j.apcata.2008.10.044
  32. Padmasri, A. H.; Venugopal, A.; Krishnamurthy, J.; Rama Rao, K. S.; Kanta Rao, P. J. Mol. Catal. A: Chem. 2002, 181, 73. https://doi.org/10.1016/S1381-1169(01)00346-6
  33. Kepinski, L.; Wolcyrz, M. J. Solid State Chem. 1997, 131, 121. https://doi.org/10.1006/jssc.1997.7364
  34. Gonzalez, I. D.; Navarro, R. M.; Wen, W.; Marinkovic, N.; Rodriguez, J. A.; Rosa, F.; Fierro, J. L. G. Catal. Today 2010, 149, 372. https://doi.org/10.1016/j.cattod.2009.07.100

피인용 문헌

  1. The double peaks and symmetric path phenomena in the catalytic activity of Pd/Al2O3-TiO2 catalysts with different TiO2 contents vol.262, pp.None, 2018, https://doi.org/10.1016/j.jssc.2018.03.036
  2. Catalytic Oxidation of Chlorobenzene over Pd-TiO2 /Pd-Ce/TiO2 Catalysts vol.10, pp.3, 2013, https://doi.org/10.3390/catal10030347
  3. Synthesis of palladium supported on mesoporous hydroxyapatite from oyster shells for use as efficient, green, and recyclable catalyst for Heck reactions vol.24, pp.1, 2013, https://doi.org/10.1007/s11051-021-05365-4