Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Catalytic Pyrolysis of Cellulose over SAPO-11 Using Py-GC/MS

  • Lee, In-Gu (Korea Institute of Energy Research) ;
  • Jun, Bo Ram (Graduate School of Energy and Environmental System Engineering, University of Seoul) ;
  • Kang, Hyeon Koo (Graduate School of Energy and Environmental System Engineering, University of Seoul) ;
  • Park, Sung Hoon (Department of Environmental Engineering, Sunchon National University) ;
  • Jung, Sang-Chul (Department of Environmental Engineering, Sunchon National University) ;
  • Jeon, Jong-Ki (Department of Chemical Engineering, Kongju National University) ;
  • Ko, Chang Hyun (School of Applied Chemical Engineering, Chonnam National University) ;
  • Park, Young-Kwon (Graduate School of Energy and Environmental System Engineering, University of Seoul)
  • Received : 2013.04.20
  • Accepted : 2013.05.17
  • Published : 2013.08.20
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Abstract

The catalytic pyrolysis of cellulose was carried out over SAPO-11 for the first time. Pyrolyzer-gas chromatography/mass spectroscopy was used for the in-situ analysis of the pyrolysis products. The acid sites of SAPO-11 converted most levoglucosan produced from the non-catalytic pyrolysis of cellulose to furans. In particular, the selectivity toward light furans, such as furfural, furan and 2-methyl furan, was high. When the catalyst/cellulose ratio was increased from 1/1 to 3/1 and 5/1, the increase in the quantity of acid sites led to the promotion of deoxygenation and the resultant increase of the contents of light furan compounds. Because furans can be used as basic feedstock materials, the augmentation of the economical value of bio-oil through the catalytic upgrading over SAPO-11 is considerable.

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