한국세라믹학회지 (Journal of the Korean Ceramic Society)

  • 제50권4호
  • /
  • Pages.251-256
  • /
  • 2013
  • /
  • 1229-7801(pISSN)
  • /
  • 2234-0491(eISSN)
한국세라믹학회 (The Korean Ceramic Society)
권호 표지
DOI QR코드

DOI QR Code

Easy and Fast Synthesis of Pd-MWCNT/TiO2 by the Sol-Gel Method and its Recyclic Photodegradation of Rhodamine B

  • Ye, Shu (Department of Advanced Materials Science & Engineering, Hanseo University) ;
  • Ullah, Kefayat (Department of Advanced Materials Science & Engineering, Hanseo University) ;
  • Zhu, Lei (Department of Advanced Materials Science & Engineering, Hanseo University) ;
  • Meng, Ze-Da (Department of Advanced Materials Science & Engineering, Hanseo University) ;
  • Sun, Qian (Department of Advanced Materials Science & Engineering, Hanseo University) ;
  • Oh, Won-Chun (Department of Advanced Materials Science & Engineering, Hanseo University)
  • 투고 : 2013.05.22
  • 심사 : 2013.07.17
  • 발행 : 2013.07.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Multiwalled carbon nanotubes (MWCNTs) modified with Pd and $TiO_2$ composite catalysts were synthesized by the sol-gel method followed by solvothermal treatment at low temperature. The chemical composition and surface structure were characterized by X-ray diffraction (XRD), energy-dispersive X-ray (EDX) spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Photocatalytic recycle degradation experiments were carried out under both UV and visible light irradiation in the presence of MWCNT/$TiO_2$ and Pd-MWCNT/$TiO_2$ composites. As expected, the nanosized Pd-MWCNT/$TiO_2$ photocatalysts had enhanced activity over the non Pd treated MWCNT/$TiO_2$ material in the degradation of a rhodamine B (Rh.B) solution. An increase in photocatalytic activity was observed and attributed to an increase in the photo-absorption effect by MWCNTs and the cooperative effect of Pd and $TiO_2$ nanoparticles. According to the recycled results, the as-prepared Pd-MWCNT/$TiO_2$ sample had a good effect on it.

키워드

참고문헌

  1. A. Fujishima and K. Honda, "Electrochemical Photolysis of Water at a Semiconductorelectrode," Nature, 238 37-38 (1972). https://doi.org/10.1038/238037a0
  2. A. L. Linsebigler, G. Lu, and J.T. Yates, "Photocatalysis on $TiO_2$ Surfaces: Principles, Mechanisms, and Selected Results," Chem. Rev., 95 735-58 (1995). https://doi.org/10.1021/cr00035a013
  3. K. Hirai, Y. Nagata, and Y. Maeda, "Decomposition of Chlorofluorocarbons and Hydrofluorocarbons in Water by Ultrasonic Irradiation," Ultrason. Sonochem., 3 205-08 (1996). https://doi.org/10.1016/S1350-4177(96)00027-2
  4. Y. Mizukoshi, K. Okitsu, Y. Maeda, T.A. Yamamoto, R. Oshima, and Y. Nagata, "Characterization and Catalytic Activity of CoreShell Structured Gold/Palladium Bimetallic Nanoparticles Synthesized by the Sonochemical Method," J. Phys. Chem. B., 101 7033-37 (1997). https://doi.org/10.1021/jp9638090
  5. X. K. Wang, J. G. Wang, P.Q. Guo, W.L. Guo, and C. Wang, "Degradation of Rhodamine B in Aqueous Solution by Using Swirling Jet-induced Cavitation Combined with $H_2O_2$," J. Hazardous Materials., 169 486-91 (2009). https://doi.org/10.1016/j.jhazmat.2009.03.122
  6. Z. D. Meng, K. Zhang, and W.C.Oh, "Preparation of Fe-AC/$TiO_2$ Composites and pH Dependence of Their Photocatalytic Activity for Methylene Blue," J. Korean Crystal Grow Crystal Technique, 19 268 (2009).
  7. R. Hiller, K. Weninger, S. J. Putterman, and B.P. Barber, "Effect of Noble Gas Doping in Single-Bubble Sonoluminescence," Science, 266 248-50 (1994). https://doi.org/10.1126/science.266.5183.248
  8. R. A. Hiller, S. J. Putterman, and K. R. Weninger, "Time-Resolved Spectra of Sonoluminescence," Phys. Rev. Lett., 80 1090-93 (1998). https://doi.org/10.1103/PhysRevLett.80.1090
  9. H. Nakui, K. Okitsu, Y. Maeda, and R. Nishimura, "Hydrazine Degradation by Ultrasonic Irradiation," J. Hazard. Mater., 146 636-39 (2007). https://doi.org/10.1016/j.jhazmat.2007.04.080
  10. A. Z. Abdullah and P.Y. Ling, "Heat Treatment Effects on the Characteristics and Sonocatalytic Performance of $TiO_2$ in the Degradation of Organic Dyes in Aqueous Solution," J. Hazard. Mater., 173 159-67 (2010). https://doi.org/10.1016/j.jhazmat.2009.08.060
  11. N. Shimizu, C. Ogino, M.F. Dadjour, and T. Murata, "Sonocatalytic Degradation of Methylene Blue with $TiO_2$ Pellets in Water," Ultrason. Sonochem., 14 184-90 (2007). https://doi.org/10.1016/j.ultsonch.2006.04.002
  12. J. Wang, T. Ma, Z. H. Zhang, X. D. Zhang, Y. F. Jiang, G. Zhang, G. Zhao, H. D. Zhao, and P. Zhang, "Investigation on Transition Crystal of Ordinary Rutile $TiO_2$ Powder and Its Sonocatalytic Activity," Ultrason. Sonochem., 14 246-52 (2007). https://doi.org/10.1016/j.ultsonch.2006.05.003
  13. W. Zhang, X. L. Cui, and Z. Y. Jiang, "Effect of Composite-Modes on Photoelectrochemical Properties of MWCNTs/$TiO_2$ Nanocomposite Films," Acta Phys.-Chim. Sinica., 24 [11] 1975-80 (2008).
  14. Z. D. Meng, J. G. Choi, and W. C. Oh, "Photocatalytic Degradation of Methylene Blue on Fe-fullerene/$TiO_2$ Under Visible-light Irradiation," Asian J. Chem., 23847 (2011).
  15. H. Park and W. Choi, "Effects of $TiO_2$ Surface Fluorination on Photocatalytic Reactions and Photoelectrochemical Behaviors," J. Phys. Chem. B., 108 4086-93 (2004). https://doi.org/10.1021/jp036735i
  16. P. V. Kamat, "Photophysical, Photochemical and Photocatalytic Aspects of Metal Nanoparticles," J. Phys. Chem. B., 106 7729-44 (2002). https://doi.org/10.1021/jp0209289
  17. K. Nagaveni, M. S. Hegde, N. Ravishankar, G. N. Subbanna, and G. Madrad, "Synthesis and Structure of Nanocrystalline $TiO_2$ with Lower Band Gap Showing High Photocatalytic Activity," Langmuir, 20 2900-07 (2004). https://doi.org/10.1021/la035777v
  18. Z. Zou, J. Ye, K. Sayama, and H. Arakawa, "Direct Splitting of Water Under Visible Light Irradiation with an Oxide Semiconductor Photocatalyst," Nature., 414 625-27 (2001). https://doi.org/10.1038/414625a
  19. W. C. Oh, F. J. Zhang, M. L. Chen, Y. M. Lee, W. B. Ko, "Characterization and Relative Photonic Efciencies of a new Fe-ACF/$TiO_2$ Composite Photocatalysts Designed for Organic Dye Decomposition," J. Ind. Eng. Chem., 15 190-195 (2009). https://doi.org/10.1016/j.jiec.2008.09.019
  20. M.L. Chen, J.S. Bae, and W.C. Oh, "Characterization of AC/$TiO_2$ Composite Prepare with Pitch Binder and Their Photocatalytic Activity," Bull. Korean Chem. Soc., 27 1423-28 (2006). https://doi.org/10.5012/bkcs.2006.27.9.1423
  21. J. C. Charlier, "Defects in Carbon Nanotubes," Acc. Chem. Res., 35 1063-69 (2002). https://doi.org/10.1021/ar010166k
  22. X. Z. Li, F. B. Li, C. L. Yang, and W. K. Ge, "Photocatalytic Activity of WOx-$TiO_2$ under Visible Light Irradiation," J. Photochem. Photobiol. A: Chem., 141 209-17 (2001). https://doi.org/10.1016/S1010-6030(01)00446-4
  23. C. J. Barrelet, Y. Wu, D. C. Bell, and C. M. Lieber, "Synthesis of CdS and ZnS Nanowires Using Single-Source MolecuLar Precursors," J. Am. Chem. Soc., 125 11498-499 (2003). https://doi.org/10.1021/ja036990g
  24. Z. L. Wang, "Characterizing the Structure and Properties of Individual Wire-Like Nanoentities," Adv. Mater., 12 1295-98 (2000). https://doi.org/10.1002/1521-4095(200009)12:17<1295::AID-ADMA1295>3.0.CO;2-B
  25. N. Ghows and M. H. Entezari, "Fast and Easy Synthesis of Core-shell Nanocrystal (CdS/$TiO_2$) at Low Temperature by Micro-emulsion under Ultrasound," Ultrason. Sonochem., 18 629-34 (2011). https://doi.org/10.1016/j.ultsonch.2010.08.003
  26. X. K. Wang, J. G. Wang, P. Q. Guo, W. L. Guo, and C. Wang, "Degradation of Rhodamine B in Aqueous Solution by Using Swirling Jet-Induced Cavitation Combined with $H_2O_2$," J. Hazard. Mater., 169 486-91 (2009). https://doi.org/10.1016/j.jhazmat.2009.03.122
  27. W. Shangguan and A. Yoshida, "Photocatalytic Hydrogen Evolution from Water on Nanocomposites Incorporating Cadmium Sulfide into the Interlayer," J. Phys. Chem. B.,106 1227-30 (2002).
  28. G. Q. Guan, K. Tetsuya, K. Katsuki, K. Kunio, A. Eiichi, and A. Yoshida, "Photocatalytic Activity of CdS Nanoparticles Incorporated in Titanium Silicate Molecular Sieves of ETS-4 and ETS-10," Appl. Catal. A: General, 295 [1] 71-8 (2005). https://doi.org/10.1016/j.apcata.2005.08.010
  29. A. Bhattacharyya, S. Kawi, and M. B. Ray, "Photocatalytic Degradation of Orange II by $TiO_2$ Catalysts Supported on Adsorbents," Catal. Today, 98 431-39 (2004). https://doi.org/10.1016/j.cattod.2004.08.010