DOI QR코드

DOI QR Code

Preparation and Characterization of Cotton Linter Based Regenerated Cellulose Fiber by Dry Jet-wet Spinning

기격 습식 방사를 이용한 면 린터 기반 셀룰로스 재생 섬유 제조 및 평가

  • Kim, Ik Mo (Department of Advanced Polymer and Fiber Materials, Graduate School, Kyung Hee University) ;
  • Yoo, Mi Kyong (Department of Advanced Materials Engineering for Information & Electronics, College of Engineering, Kyung Hee University) ;
  • Kim, Kap Jin (Department of Advanced Polymer and Fiber Materials, Graduate School, Kyung Hee University)
  • 김익모 (경희대학교 일반대학원 고분자섬유신소재학과) ;
  • 유미경 (경희대학교 공과대학 정보.전자 신소재공학과) ;
  • 김갑진 (경희대학교 일반대학원 고분자섬유신소재학과)
  • Received : 2012.12.28
  • Accepted : 2013.02.01
  • Published : 2013.02.28

Abstract

Compared to the conventional viscose rayon process, Lyocell process using NMMO as a solvent provides a naturally-friendly, less toxic, relatively simple method for producing regenerated cellulose fiber with excellent properties. Existing wood pulp based Lyocell, however, shows some disadvantages such as forest destruction. So, in this study, a novel regenerated cellulose fiber, cotton linter based Lyocell, was prepared by dry jet-wet spinning with a lab scale equipment changing concentration of cellulose/NMMO solution, take-up speed, etc, which are strongly related with fiber properties and its properties were compared with wood pulp based Lyocell fiber. The tenacity and strain at break of the resultant fibers were correlated with the intrinsic fiber properties such as birefringence, crystallinity, and crystalline orientation index.

Keywords

References

  1. 홍영근, "신 셀룰로오스 섬유", 고분자과학과 기술, 1996, 7, 41-52.
  2. H.-P. Fink, P. Weigel, H. J. Purz, and J. Ganster, "Structure Formation of Regenerated Cellulose Materials from NMMO-Solutions", Prog Polym Sci, 2001, 26, 1473-1524. https://doi.org/10.1016/S0079-6700(01)00025-9
  3. T. Rosenau, A. Potthast, H. Sixta, and P. Kosma, "The Chemistry of Side Reactions and Byproduct Formation in the System NMMO/cellulose (Lyocell process)", Prog Polym Sci, 2001, 26, 1763-1837. https://doi.org/10.1016/S0079-6700(01)00023-5
  4. B. H. Moon, S. K. Lim, T. W. Son, Y. M. Jeon, C. J. Yoon, and Y. S. Oh, "Study on the Preparation and Properties of Regenerated Cellulose Fibers from MMNO/Water/Cellulose", J Korean Fiber Soc, 1997, 34, 477-488.
  5. 김기수, "셀룰로오스와 라이오셀(Lyocell) 섬유", 한국과학기술정보연구원 기술동향분석보고서, 2003.
  6. D. W. Chae, K. R. Choi, B. C. Kim, and Y. S. Oh, "Effect of Cellulose Pulp Type on the Mercerizing Behavior and Physical Properties of Lyocell Fibers", Text Res J, 2003, 73, 541-545. https://doi.org/10.1177/004051750307300613
  7. K. E. Perepelkin, "Lyocell Fibres Based on Direct Dissolution of Cellulose in N-methylmorpholine N-oxide: Development and Prospects", Fibre Chem, 2007, 39, 163-172. https://doi.org/10.1007/s10692-007-0032-9
  8. D. Loubinoux and S. Chaunis, "An Experimental Approach to Spinning New Cellulose Fibers with N-Methylmorpholine-Oxide as a Solvent", Text Res J, 1987, 57, 61-65. https://doi.org/10.1177/004051758705700201
  9. E. Borbely, "Lyocell, the New Generation of Regenerated Cellulose", Acta Polytechnica Hungarica, 2008, 5, 11-18.
  10. 김갑진, "광학현미경에 의한 섬유 및 필름의 굴절률 및 복굴절률 측정", 한국섬유공학회지, 1984, 21, 59-79.
  11. W. Udomkichdecha and S. Chiarakorn, "Factors to Predict the Fibrillation Tendency of Lyocell Fibers", J Sci Res Chula Univ, 2001, 26, 49-56.
  12. S. Park, J. O. Baker, M. E. Himmel, P. A. Parilla, and D. K. Johnson, "Cellulose Crystallinity Index: Measurement Techniques and Their Impact on Interpreting Cellulase Performance", Biotechnol Biofuels, 2010, 3, 1-10. https://doi.org/10.1186/1754-6834-3-1
  13. H. S. Paek, J. S. Park, S. M. Jo, W. S. Lee, and K. J. Kim, "The Effects of Preparation Conditions of Cellulose/NMMO (N-Methylmorpholine N-Oxide) Solutions on Physical Properties of Fibers", J Korean Fiber Soc, 1993, 30, 569-577.
  14. Y. J. Jung, B. J. An, H. S. Kim, H. W. Choi, E. P. Lee, J. H. Lee, H. D. Kim, S. M. Park, and S. D. Kim, "Preparation and Properties of Regenerated Composite Fibers Made from Styela Clava Tunics/PVA Blending(II)", J Korean Soc Dyers Finishers, 2008, 20, 31-38. https://doi.org/10.5764/TCF.2008.20.3.031
  15. P. H. Hermans, "Degree of Lateral Order in Various Rayons as Deduced from X-ray Measurements", J Polym Sci, 1949, 4, 145-151. https://doi.org/10.1002/pol.1949.120040204
  16. R. Ibbett, J. Taylor, K. C. Schuster, and M. Cox, "Interpretation of Relaxation and Swelling Phenomena in Lyocell Regenerated Cellulosic Fibres and Textiles Associated with the Uptake of Solutions of Sodium Hydroxide", Cellulose, 2008, 15, 393-406. https://doi.org/10.1007/s10570-007-9180-6
  17. Y. J. Jung, B. J. An, H. S. Kim, H. W. Choi, E. P. Lee, J. H. Lee, H. D. Kim, S. M. Park, and S. D. Kim, "Preparation and Properties of Regenerated Composite Fibers Made from Styela Clava Tunics/PVA Blending(I)", J Korean Soc Dyers Finishers, 2008, 20, 1-8. https://doi.org/10.5764/TCF.2008.20.2.001
  18. F. Carrillo, X. Colom, J. J. Sunol, and J. Saurina, "Structural FTIR Analysis and Thermal Characterisation of Lyocell and Viscose-type Fibres", Eur Polym J, 2004, 40, 2229-2234. https://doi.org/10.1016/j.eurpolymj.2004.05.003
  19. M. L. Nelson and R. T. O'Connor, "Relation of Certain Infrared Bands to Cellulose Crystallinity and Crystal Lattice Type. Part I. Spectra of Lattice Types I, 11, I11 and of Amorphous Cellulose", J Appl Polym Sci, 1964, 8, 1311-1324. https://doi.org/10.1002/app.1964.070080322
  20. Y. Kataoka and T. Kondo, "FT-IR Microscopic Analysis of Changing Cellulose Crystalline Structure during Wood Cell Wall Formation", Macromolecules, 1998, 31, 760-764. https://doi.org/10.1021/ma970768c
  21. A. C. O'Sullivan, "Cellulose: The Structure Slowly Unravels", Cellulose, 1997, 4, 173-207. https://doi.org/10.1023/A:1018431705579

Cited by

  1. Preparation and characterization of persistent luminescence of regenerated cellulose fiber vol.28, pp.1, 2017, https://doi.org/10.1007/s10854-016-5622-y
  2. Densifying and strengthening of electrospun polyacrylonitrile-based nanofibers by uniaxial two-step stretching vol.133, pp.37, 2016, https://doi.org/10.1002/app.43945
  3. Physical properties and fibrillation tendency of regenerated cellulose fiber dry jet-wet spun from high-molecular weight cotton linter Pulp/NMMO solution vol.16, pp.8, 2015, https://doi.org/10.1007/s12221-015-5313-y