Corrosion Science and Technology

The Corrosion Science Society of Korea (한국부식방식학회)
권호 표지
DOI QR코드

DOI QR Code

Improvement of anti-corrosive property for alloy plated steel sheet by UV curable organic-inorganic hybrid coatings

합금도금강판 내식성 향상을 위한 UV 경화형 유무기 하이브리드 코팅

  • Park, Jongwon (Ulsan Industrial Technology Research Center, Research Institute of Industrial Science & Technology) ;
  • Lee, Kyunghwang (Ulsan Industrial Technology Research Center, Research Institute of Industrial Science & Technology) ;
  • Na, Hyunju (Ulsan Industrial Technology Research Center, Research Institute of Industrial Science & Technology) ;
  • Park, Byungkyu (Surface Treatement Department, AK ChemTech Co., Ltd.) ;
  • Nam, Yeungsub (Surface Treatement Department, AK ChemTech Co., Ltd.) ;
  • Hong, Shinhyub (Surface Treatement Department, AK ChemTech Co., Ltd.)
  • 박종원 (포항산업과학연구원 울산플랜트연구본부) ;
  • 이경황 (포항산업과학연구원 울산플랜트연구본부) ;
  • 나현주 (포항산업과학연구원 울산플랜트연구본부) ;
  • 박병규 (에이케이켐텍 표면처리부) ;
  • 남영섭 (에이케이켐텍 표면처리부) ;
  • 홍신협 (에이케이켐텍 표면처리부)
  • Received : 2012.11.12
  • Accepted : 2012.12.21
  • Published : 2013.02.15
Download PDF
⟨ Previous Next ⟩

Abstract

According to its merits about high curing speed and low emission of volatile organic compounds, UV curable inorganic-organic coating technology has been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. Based on the tetra-ethylorthosilicate(TEOS) and methacryloxypropyl trimethoxysilane(MPTMS), inorganic sol was synthesized and formed hybrid networks with UV curable acrylic monomer, 6-hexanediol diacrylate(HDDA), trimethylolpropane triacrylate(TMPTA), pentaerylthritol triacrylate(PETA). Several methods were used to test their properties such as salt spray test, potentiodynamic measurement, tape peel test, etc. It was shown that anti-corrosive property and stability of storage were affected by the molecular ratios of inorganic and organic compounds. It was not only the stability of storage, but had a excellent anti-corrosive, paint adhesive, and anti-solvent properties in a final molar ratios of 0.6/0.04/0.86/0.005 (TEOS/MPTMS/Acetone/HNO3) and 0.08/0.106/0.081/0.02 (TMPTA/HDDA/PETA/photo initiator).

Keywords

References

  1. M. S. Lee and N. J. Jo, J. Korean Ind. Eng. Chem., 12(6), 643 (2001).
  2. S. Kwak, J. Shim, H. G. Yoon, and K. H. Lee, Polymer Sci. Tech., 14(2), 181 (2003).
  3. J. D. Mackenzie and E. P. Bescher, J. Sol-Gel Sci. Tech., 19, 23 (2000). https://doi.org/10.1023/A:1008701903087
  4. G. Schottner, K. Rose and U. Posset, J. Sol-Gel Sci. Tech., 27, 71 (2003). https://doi.org/10.1023/A:1022684011222
  5. J. K. Park, K. C. Song, H. U. Kang and S. H. Kim, Hwahak Konghak, 40(6), 735 (2002).
  6. S. K. Oh, Ph.D Thesis, Preparation of UV-curable organic-inorganic hybrid hard coating solutions by sol-gel method, Kungyang Univ. (2009).
  7. O. H. Park, Y. J. Park, Y. K. Choi, B. S. Bak, J. Sol-Gel Sci. Tech., 16, 235 (1999). https://doi.org/10.1023/A:1008717219952
  8. Y. J. Eo, D. J. Kim, S. J. Park, Sol-Gel Sci. Tech., 13, 409 (1998). https://doi.org/10.1023/A:1008665010016
  9. C. J. Brinker and G. W. Scherer, Sol-Gel Science: The physics and chemistry of sol-gel processing, Academic Press, San Diego (1990).
  10. B. Wessling, H. S. Nalwa(Ed.), Handbook of Nanostructured materials and nanotechnology, Academic Press, New York (1999).
  11. K. Rose, S. Amberg-Schwab, M. Heinrich, N. Auner, J. Weis(Eds.), Organosilicon chemistry IV, VCH Weinheim, Germany (1999).
  12. C. Sanchez, B. Julian, P. Belleville and M. Popall, J. Mater. Chem., 15, 3559 (2005). https://doi.org/10.1039/b509097k
  13. D. Wang and G. P. Bierwagen, Prog. Org. Coat., 64, 327 (2009). https://doi.org/10.1016/j.porgcoat.2008.08.010
  14. H. Wang and R. Akid, Corros. Sci., 49, 4491 (2007). https://doi.org/10.1016/j.corsci.2007.04.015
  15. H. E. Bergna and W. O. Roberts, Surf. Sci., 131, 139 (2006).
  16. P. Ocon, A. B. Cristobal, P. Herrasti and E. Fatas, Corros. Sci., 47, 649 (2005). https://doi.org/10.1016/j.corsci.2004.07.005
  17. Z. W. Wicks, F. N. Jones and S. P. Pappas, Inorganic coatings: Science and Technology, Wiley-Vch, New York (1994).
  18. S. Tasic, B. Bozic and B. Dunzie, Prog. Org. Coat., 51, 321 (2004).
  19. P. Favia, G. Cicala, A. Milella, F. Palumbo, R. Rossini and R. Agostino, Surf. Coat. Technol., 169, 609 (2003).
  20. W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan and C. H. Kan, Thin Solid Films, 358, 16 (2000). https://doi.org/10.1016/S0040-6090(99)00683-5
  21. Y. J. Ji, Y. J. Shin, Y. R. Shin, J. Y. Kim, Y. S. Yoon and J. S. Shin, J. Adhesion Interface, 7, 234 (2006).
  22. ASTM G3-89, Standard practice for conventions applicable to electrochemical measurement in corrosion testing.
  23. ASTM G3359, Standar test methods for measuring adhesion tape test.
  24. P. Kiruthika, R. Subasri, A. Jyothirmayi, K. Sarvani, and N. Y. Hebalkar, Surf. Coating Tech., 204, 1270 (2010). https://doi.org/10.1016/j.surfcoat.2009.10.017

Cited by

  1. Development of Zn-Al thermal diffusion coating technology for improving anti-corrosion of various metal products vol.13, pp.5, 2014, https://doi.org/10.14773/cst.2014.13.5.195