한국지하수토양환경학회지:지하수토양환경 (Journal of Soil and Groundwater Environment)

  • 제18권1호
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  • Pages.46-56
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  • 2013
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  • 1598-6438(pISSN)
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  • 2287-8831(eISSN)
한국지하수토양환경학회 (Korean Society of Soil and Groundwater Environment)
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Bacillus drentensis sp. 사균과 polysulfone으로 이루어진 미생물담체를 이용한 수용액 내 벤젠 제거

Removal of Benzene in Solution by using the Bio-carrier with Dead Bacillus drentensis sp. and Polysulfone

  • 박상희 (부경대학교 지구환경과학과) ;
  • 이민희 (부경대학교 지구환경과학과)
  • Park, Sanghee (Department of Earth Environmental Sciences, Pukyong National University) ;
  • Lee, Minhee (Department of Earth Environmental Sciences, Pukyong National University)
  • 투고 : 2012.11.02
  • 심사 : 2013.02.12
  • 발행 : 2013.02.28
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초록

Laboratory scale experiments to remove benzene in solution by using the bio-carrier composed of dead biomass have been performed. The immobilized bio-carrier with dead Bacillus drentensis sp. and polysulfone was manufactured as the biosorbent. Batch sorption experiments were performed with bio-carriers having various quantities of biomass and then, their removal efficiencies and uptake capacities were calculated. From results of batch experiments, 98.0% of the initial benzene (1 mg/L) in 1 liter of solution was removed by using 40 g of immobilized bio-carrier containing 5% biomass within 1 hour and the biosorption reaction reached in equilibrium within 2 hours. Benzene removal efficiency slightly increased (99.0 to $99.4%{\pm}0.05$) as the temperature increased from 15 to $35^{\circ}C$, suggesting that the temperature rarely affects on the removal efficiency of the bio-carrier. The removal efficiency changed under the different initial benzene concentration in solution and benzene removal efficiency of the bio-carrier increased with the increase of the initial benzene concentration (0.001 to 10 mg/L). More than 99.0% of benzene was removed from solution when the initial benzene concentration ranged from 1 to 10 mg/L. From results of fitting process for batch experimental data to Langmuir and Freundlich isotherms, the removal isotherms of benzene were more well fitted to Freundlich model ($r^2$=0.9242) rather than Langmuir model ($r^2$=0.7453). From the column experiment, the benzene removal efficiency maintained over 99.0% until 420 pore volumes of benzene solution (initial benzene concentration: 1 mg/L) were injected in the column packed with bio-carriers, investigating that the immobilized carrier containing Bacillus drentensis sp. and polysulfone is the outstanding biosorbent to remove benzene in solution.

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