Bulletin of the Korean Chemical Society

  • 제34권2호
  • /
  • Pages.389-393
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  • 2013
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Turn-On Type Fluorogenic and Chromogenic Probe for the Detection of Trace Amount of Nitrite Ion in Water

  • 투고 : 2012.10.10
  • 심사 : 2012.11.09
  • 발행 : 2013.02.20
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초록

A rhodamine B-based fluorescent probe for nitrite ion ($NO{_2}^-$) has been designed, synthesized, characterized and its properties for recognition of $NO{_2}^-$ were studied. Nearly non fluorescent probe upon reaction with nitrite ion significantly triggered the fluorescence. Fluorescence response is based on ring opening of the spirolactam of rhodamine B phenyl hydrazide showing maximum absorbance at 552 nm and maximum emission at 584 nm. Probe 3 exhibited high sensitivity and extreme selectivity for nitrite ion over other common ions and oxidants ($Cl^-$, $ClO^-$, $ClO{_2}^-$, $ClO{_3}^-$, $ClO{_4}^-$, $SO{_4}^{2-}$, $SiO{_3}^{2-}$, $NO{_3}^{2-}$, $CO{_3}^{2-}$) examined in methanol water (1:1, v/v) at pH 7.0. The probe might be a new efficient tool for detection of nitrite ion in natural water and biological system.

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피인용 문헌

  1. Shape‐controlled Electrodeposition of Standing Pt Nanoplates on Gold Substrates as a Sensor Platform for Nitrite Ions vol.40, pp.6, 2013, https://doi.org/10.1002/bkcs.11723