Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Effect of Calcination Temperature on the Structure and Electrochemical Performance of LiMn1.5Ni0.5O4 Cathode Materials

  • Ju, Seo Hee (Department of Chemical Engineering, Hanyang University) ;
  • Kim, Dong-Won (Department of Chemical Engineering, Hanyang University)
  • Received : 2012.09.03
  • Accepted : 2012.10.02
  • Published : 2013.01.20
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Abstract

Spinel $LiMn_{1.5}Ni_{0.5}O_4$ cathode powders with different morphologies were synthesized by a co-precipitation method using oxalic acid. The calcination temperature affected the morphologies, crystalline structure and electrochemical properties of the $LiMn_{1.5}Ni_{0.5}O_4$ powders. The $LiMn_{1.5}Ni_{0.5}O_4$ powders obtained at a calcination temperature of $850^{\circ}C$ exhibited the highest initial discharge capacity with good capacity retention and high rate capability.

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