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Thermoelectric Properties of AlN-doped SiC Ceramics

AlN 첨가 SiC 세라믹스의 열전변환특성

  • Pai, Chul-Hoon (Department of Nano Engineering, University of Incheon)
  • 배철훈 (인천대학교 나노공학과)
  • Received : 2012.04.09
  • Published : 2012.11.25

Abstract

The effect of an AlN additive on the thermoelectric properties of SiC ceramics was studied. Porous SiC ceramics with 48-54% relative density were fabricated by sintering the pressed ${\alpha}-SiC$ powder compacts with AlN at $2100-2200^{\circ}C$ for 3 h in an Ar atmosphere. In the undoped specimens, the Seebeck coefficients were positive (p-type semiconducting) possibly due to a dominant effect of the acceptor impurities (Al, Fe) contained in the starting powder. With AlN addition, the reverse phase transformation of 6H-SiC to 4H-SiC was observed during the sintering process. The electrical conductivity of the AlN doped specimen was larger than that of the undoped specimen under the same conditions, which might be due to a reverse phase trans-formation. The Seebeck coefficient of the AlN doped specimen was also larger than that of the undoped specimen. The density of specimen and the amount of addition had significant effects on the thermoelectric properties.

Keywords

Acknowledgement

Supported by : 인천대학교

References

  1. D. M. Rowe and C. M. Bhandari, Modern Thermoelectrics, pp.35-48, Holt, Rinehart and Winston Ltd., London (1983).
  2. I. B. Cadoff and E. Miller, Thermoelectric Materials and Devices, pp.173-183, Chapman and Hall Ltd., London (1960).
  3. K. Uemura and I. Nishida, Thermoelectric Semiconductors and Their Applications, pp.1-11, Nikkan Kogyo Shinbun (1988).
  4. C. H. Pai and H. J. Park, J. Kor. Inst. Met. & Mater. 46, 315 (2008).
  5. C. H. Pai and J. G. Kim, J. Kor. Inst. Met. & Mater. 47, 860 (2009).
  6. K. Koumoto, C. H. Pai, S. Takeda, and H. Yanagida, Proceedings of the 8th International Conference on Thermoelectric Energy Conversion, pp.107-112 (1989).
  7. Y. Suga(Ed.), Thermoelectric Semiconductors, pp.295- 355, Makishyoten, Tokyo (1966).
  8. W. S. Seo, C. H. Pai, K. Koumoto, and H. Yanagida, J. Ceram. Soc. Jpn. 99, 1179 (1991).
  9. V. Munch, Silicon Carbide, pp.132-142, Landolt- Bornstein (1982).
  10. T. Kawamura, Miner. J. 4, 333 (1965).
  11. W. F. Knippenberg and G. Verspui, Mater. Res. Bull. 4, 45 (1969).
  12. M. Mitomo, Y. Inomata, and M. Kumanomido, J. Ceram. Soc. Jpn. 78, 224 (1970).
  13. N. W. Jepps and T. F. Page, J. Am. Ceram. Soc. 64, c-177 (1981).
  14. C. H. Pai, K. Koumoto, and H. Yanagida, J. Ceram. Soc. Jpn. 97, 1170 (1989).
  15. J. Y. W. Seto, J. Appl. Phys. 46, 5247 (1975).
  16. C. H. Seager and T. G. Castner, J. Appl. Phys. 49, 3879 (1978).
  17. M. L. Tarng, J. Appl. Phys. 49, 4069 (1978).
  18. G. Baccarani, B. Ricco, and G. Spadini, J. Appl. Phys. 49, 5565 (1978).
  19. J. Y. M. Lee and I. C. Cheng, J. Appl. Phys. 53, 490 (1980).
  20. P. R. Emtage, J. Appl. Phys. 48, 4372 (1977).
  21. K. Eda, J. Appl. Phys. 49, 2964 (1978).