Bulletin of the Korean Chemical Society

  • 제33권11호
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  • Pages.3777-3787
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  • 2012
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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A Series of 3D Lanthanide Complexes Containing (La(III), Sm(III) and Gd(III)) Metal-organic Frameworks: Synthesis, Structure, Characterization and Their Luminescent Properties

  • Zhang, Huai-Min (Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University) ;
  • Yang, Hao (Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University) ;
  • Wu, Lan-Zhi (Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University) ;
  • Song, Shuang (Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University) ;
  • Yang, Li-Rong (Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University)
  • 투고 : 2012.07.16
  • 심사 : 2012.08.28
  • 발행 : 2012.11.20
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초록

Three kinds of 3D isomorphous and isostructural coordination polymers, namely, $\{[Ln_2(PDA)_3(H_2O)_3]{\cdot}0.25H_2O\}_{\infty}$ (Ln = La(1), Sm(2), and Gd(3)) ($PDA^{2-}$ = pyridine-2,6-dicarboxylate anion) have been synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectroscopy, thermal analyses and single crystal X-ray diffraction. In these MOFs, Ln(III) centers adopt eight-coordinated and nine-coordinated with the $N_1O_7$ and $N_2O_7$ donor sets to construct distorted trianglar dodecahedron geometry and tricapped trigonal prism configurations, respectively. Based on the building block of tetranuclear homometallic $Ln_4C_4O_8$ unit (16-membered ring), 1-3 are connected into highly ordered 2D sheets via O-C-O linkers and further constructed into 3D architectures through hydrogen bonds. Crystallographic parameters suggest that the lanthanide contraction effect exist in these coordination polymers. Luminescent properties of the lanthanide-based MOFs (metal-organic frameworks) have been measured at room temperature, which reveal that they presenting ionselective characters toward certain metals, such as $Mg^{2+}$, $Cd^{2+}$ and $Pb^{2+}$ ions.

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