Bulletin of the Korean Chemical Society

  • 제33권11호
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  • Pages.3740-3744
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  • 2012
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synthesis and Characterizations of Bis-Spiropyran Derivatives

  • Lee, Sungmin (Department of Chemistry, Research Institute for Natural Sciences, and Institute of Nano Science and Technology) ;
  • Ji, Seungwook (Department of Chemistry, Research Institute for Natural Sciences, and Institute of Nano Science and Technology) ;
  • Kang, Youngjong (Department of Chemistry, Research Institute for Natural Sciences, and Institute of Nano Science and Technology)
  • 투고 : 2012.06.27
  • 심사 : 2012.08.24
  • 발행 : 2012.11.20
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초록

We synthesized three different derivatives of bis-spiropyran using simple organic reactions with high yields. BSP1, a derivative of bis-spiropyran having a connection at the position 6' and BSP2, a derivative of bis-spiropyran having a connection at the position 5 and BSP3, a derivative of bis-spiropyran containing a dithienylethene group between two spiropyran moieties were synthesized. The optical properties of BSPs were characterized. UV-Vis spectra showed that BSPs exhibit reversible photo-isomerization and the efficiency of photo-isomerization is highly dependent on the position of nitro group. BSPs having nitro group at para position of hydroxy group showed the higher efficiency of photo-isomerization that the one having nitro group at ortho position. The optical microscope images obtained under ultraviolet or visible light exposure demonstrated that the formation of nanorods can be reversibly controlled by optical signal.

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피인용 문헌

  1. Multiphotochromic molecular systems vol.44, pp.11, 2015, https://doi.org/10.1039/C5CS00137D
  2. Reverse Photochromism of Nitrosubstituted Bisspiropyran Based on Benzopyrroloindole vol.53, pp.1, 2012, https://doi.org/10.1134/s0018143919010089
  3. 3,3,3′,3′-Tetramethyl-2,2′-diphenyl-3H,3′H-5,5′-biindole vol.2020, pp.3, 2012, https://doi.org/10.3390/m1146
  4. Synthesis and study of new photochromic unsymmetrical bis-spiropyrans with nonequivalent heteroarene fragments conjugated through the common 2H,8H-pyrano[2,3-f]chromene moiety vol.1221, pp.None, 2012, https://doi.org/10.1016/j.molstruc.2020.128808