Bulletin of the Korean Chemical Society

  • 제33권11호
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  • Pages.3640-3644
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  • 2012
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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The First Report on Chemoselective Biguanide-Catalyzed Henry Reaction under Neat Conditions

  • Alizadeh, Abdolhamid (Department of Organic Chemistry, Faculty of Chemistry, Razi University) ;
  • Khodaei, Mohammad M. (Department of Organic Chemistry, Faculty of Chemistry, Razi University) ;
  • Abdi, Gisya (Department of Organic Chemistry, Faculty of Chemistry, Razi University) ;
  • Kordestani, Davood (Department of Organic Chemistry, Faculty of Chemistry, Razi University)
  • 투고 : 2012.05.23
  • 심사 : 2012.08.11
  • 발행 : 2012.11.20
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초록

An efficient synthetic method for direct Henry reaction catalyzed by a biguanide; namely metformin, as an organosuper-base, between a variety of aromatic and aliphatic aldehydes and nitromethane under neat conditions has been developed. Convenient procedure for removal of the catalyst, chemoselective acquiring of ${\beta}$-nitroalcohols as predominant products, as far as possible short reaction time with excellent conversions are advantages of the developed protocol.

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참고문헌

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