Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Fabrication of Amino Acid Based Silver Nanocomposite Hydrogels from PVA- Poly(Acrylamide-co-Acryloyl phenylalanine) and Their Antimicrobial Studies

  • Cha, Hyeong-Rae (Anastro Laboratory, Department of Chemistry, Changwon National University) ;
  • Babu, V. Ramesh (Anastro Laboratory, Department of Chemistry, Changwon National University) ;
  • Rao, K.S.V. Krishna (Anastro Laboratory, Department of Chemistry, Changwon National University) ;
  • Kim, Yong-Hyun (Anastro Laboratory, Department of Chemistry, Changwon National University) ;
  • Mei, Surong (Anastro Laboratory, Department of Chemistry, Changwon National University) ;
  • Joo, Woo-Hong (Department of Biology, Changwon National University) ;
  • Lee, Yong-Ill (Anastro Laboratory, Department of Chemistry, Changwon National University)
  • Received : 2012.05.07
  • Accepted : 2012.07.02
  • Published : 2012.10.20
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Abstract

New silver nanoparticle (AgNP)-loaded amino acid based hydrogels were synthesized successfully from poly (vinyl alcohol) (PVA) and poly(acryl amide-co-acryloyl phenyl alanine) (PAA) by redox polymerization. The formation of AgNP in hydrogels was confirmed by using a UV-Vis spectrophotometer and XRD. The structure and morphology of silver nanocomposite hydrogels were studied by using a scanning electron microscopy (SEM), which demonstrated scattered nanoparticles, ca. 10-20 nm. Thermogravimetric analysis revealed large differences of weight loss (i.e., 48%) between the prestine hydrogel and silver nanocomposite. The antibacterial studies of AgNP-loaded PAA (Ag-PAA) hydrogels was evaluated against Escherichia coli (Gram-negative) and Staphylococcus aureus (Gram-positive) bacteria. These Ag-PAA hydrogels showed significant activities against all the test bacteria. Newly developed hydrogels could be used for medical applications, such as artificial burn dressings.

Keywords

References

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