Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Ionic Liquids Containing 1,1-Dicyano-1-acetylmethanide Anion as Potential Electrolytes

  • Winoto, Haryo Pandu (Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University) ;
  • Agarwal, Shalu (Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University) ;
  • Im, Jin-Kyu (Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University) ;
  • Cheong, Min-Serk (Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University) ;
  • Lee, Je-Seung (Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University)
  • Received : 2012.05.04
  • Accepted : 2012.06.15
  • Published : 2012.09.20
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Abstract

Various types of room temperature ionic liquids (RTILs) containing 1,1-dicyano-1-acetylmethanide anion ($[C(CN)_2(COCH_3)]^-$, $[DCNAcC]^-$) were prepared and their physical and electrochemical properties were studied. All of these ILs exhibited high thermal stabilities over $200^{\circ}C$ and relatively high ionic conductivities up to 29.4 $mS\;cm^{-1}$ at $80^{\circ}C$. Although the ionic conductivity of IL containing bis(trifluoromethanesulfonyl)-imide ($[Tf_2N]^-$) anion is higher than that of ILs bearing $[DCNAcC]^-$ anion, the specific capacitance of ILs bearing $[DCNAcC]^-$ anion are higher than that of IL containing $[Tf_2N]^-$ anion and showed high temperature dependence. Such favorable electrochemical properties of these ILs are likely to be attributed to the efficient dissociation of cation and anion at higher temperature and enhanced electrosorption of $[DCNAcC]^-$ anion at the electrode.

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References

  1. Pognon, G.; Brousse, T.; Demarconnay, L.; Belanger, D. J. Power Sources 2011, 196, 4117. https://doi.org/10.1016/j.jpowsour.2010.09.097
  2. Zhang, L. L.; Zhao, X. S. Chem. Soc. Rev. 2009, 38, 2520. https://doi.org/10.1039/b813846j
  3. Inagaki, M.; Konno, H.; Tanaike, O. J. Power Sources 2010, 195, 7880. https://doi.org/10.1016/j.jpowsour.2010.06.036
  4. Wang, X.; Lee, J. S.; Tsouris, C.; DePaoli, D. W.; Dai, S. J. Mater. Chem. 2010, 20, 4602. https://doi.org/10.1039/b925957k
  5. Pognon, G.; Brousse, T.; Bélanger, D. Carbon 2011, 49, 1340. https://doi.org/10.1016/j.carbon.2010.11.055
  6. Zhou, J.; Yuan, X.; Xing, W.; Si, W.; Zhuo, S. Carbon 2010, 48, 2765. https://doi.org/10.1016/j.carbon.2010.04.004
  7. Wei, L.; Yushin, G. J. Power Sources 2011, 196, 4072. https://doi.org/10.1016/j.jpowsour.2010.12.085
  8. Balducci, A.; Dugas, R.; Taberna, P. L.; Simon, P.; Plee, D.; Mastragostino, M.; Passerini, S. J. Power Sources 2007, 165, 922. https://doi.org/10.1016/j.jpowsour.2006.12.048
  9. Mastragostino, M.; Soavi, F. J. Power Sources 2007, 174, 89. https://doi.org/10.1016/j.jpowsour.2007.06.009
  10. Pushparaj, V. L.; Shaijumon, M. M.; Kumar, A.; Murugesan, S.; Ci, L.; Vajtai, R.; Linhardt, R. J.; Nalamasu, O.; Ajayan, P. M. Proc. Natl. Acad. Sci. 2007, 104, 13574. https://doi.org/10.1073/pnas.0706508104
  11. Zhang, H.; Cao, G.; Yang, Y.; Gu, Z. Carbon 2008, 46, 30. https://doi.org/10.1016/j.carbon.2007.10.023
  12. Zhang, H.; Cao, G. P.; Yang, Y. S.; Gu, Z. N. J. Electrochem. Soc. 2008, 155, K19. https://doi.org/10.1149/1.2811864
  13. Lazzari, M.; Soavi, F.; Mastragostino, M. J. Power Sources 2008, 178, 490. https://doi.org/10.1016/j.jpowsour.2007.12.029
  14. Orita, A.; Kamijima, K.; Yoshida, M. J. Power Sources 2010, 195, 7471. https://doi.org/10.1016/j.jpowsour.2010.05.066
  15. Matsumoto, K.; Hagiwara, R. J. Electrochem. Soc. 2010, 157, A578. https://doi.org/10.1149/1.3336831
  16. Denshchikov, K. K.; Izmaylova, M. Y.; Zhuk, A. Z.; Vygodskii, Y. S.; Novikov, V. T.; Gerasimov, A. F. Electrochim. Acta 2010, 55, 7506. https://doi.org/10.1016/j.electacta.2010.03.065
  17. Lazzari, M.; Mastragostino, M.; Pandolfo, A. G.; Ruiz, V.; Soavi, F. J. Electrochem. Soc. 2011, 158, A22. https://doi.org/10.1149/1.3514694
  18. Arbizzani, C.; Biso, M.; Cericola, D.; Lazzari, M.; Soavi, F.; Mastragostino, M. J. Power Sources 2008, 185, 1575. https://doi.org/10.1016/j.jpowsour.2008.09.016
  19. Frackowiak, E. Phys. Chem. Chem. Phys. 2007, 9, 1774. https://doi.org/10.1039/b618139m
  20. Bonhôte, P.; Dias, A. P.; Papageorgiou, N.; Kalyanasundaram, K.; Graetzel, M. Inorg. Chem. 1996, 35, 1168. https://doi.org/10.1021/ic951325x
  21. Parnham, E. R.; Morris, R. E. Chem. Mater. 2006, 18, 4882. https://doi.org/10.1021/cm0615929
  22. Kim, K.-S.; Choi, S.; Demberelnyamba, D.; Lee, H.; Oh, J.; Lee, B.-B.; Mun, S.-J. Chem. Commun. 2004, 828.
  23. Schrekker, H. S.; Silva, D. O.; Gelesky, M. A.; Stracke, M. P.; Schrekker, C. M. L.; Gonçalves, R. S.; Dupont, J. J. Braz. Chem. Soc. 2008, 19, 426. https://doi.org/10.1590/S0103-50532008000300009
  24. Zou, T.; Lu, L.; Liu, X.-L.; Zhang, Z.; Wang, L.-B.; Fu, X.-L.; Gao, G.-H.; Kou, Y.; He, M.-Y. Chinese J. Chem. 2008, 26, 1469. https://doi.org/10.1002/cjoc.200890267
  25. Fuller, J.; Carlin, R. T.; Osteryoung, R. A. J. Electrochem. Soc. 1997, 144, 3881. https://doi.org/10.1149/1.1838106
  26. Suarez, P. A. Z.; Selbach, V. M.; Dullius, J. E. L.; Einloft, S.; Piatnicki, C. M. S.; Azambuja, D. S.; de Souza, R. F.; Dupont, J. Electrochim. Acta 1997, 42, 2533. https://doi.org/10.1016/S0013-4686(96)00444-6
  27. Koch, V. R.; Dominey, L. A.; Nanjundiah, C.; Ondrechen, M. J. J. Electrochem. Soc. 1996, 143, 798. https://doi.org/10.1149/1.1836540
  28. Nishida, T.; Tashiro, Y.; Yamamoto, M. J. Fluorine Chem. 2003, 120, 135. https://doi.org/10.1016/S0022-1139(02)00322-6
  29. in: www.molinspiration.com, 2011.
  30. Lockett, V.; Sedev, R.; Ralston, J.; Horne, M.; Rodopoulos, T. J. Phys. Chem. C 2008, 112, 7486. https://doi.org/10.1021/jp7100732
  31. Hou, C.-H.; Taboada-Serrano, P.; Yiacoumi, S.; Tsouris, C. J. Chem. Phys. 2008, 129, 224703. https://doi.org/10.1063/1.3033562
  32. Kharton, V. V.; Naumovich, E. N. Russ. J. Electrochem. 1993, 29, 1297.
  33. Bukun, N. G.; Tkacheva, N. S.; Ukshe, E. A. Sov. Electrochem. 1970, 6, 1215.
  34. Ukshe, E. A.; Bukun, N. G.; Leikis, D. I.; Frumkin, A. N. Electrochim. Acta 1964, 9, 431. https://doi.org/10.1016/0013-4686(64)80049-9
  35. Holovko, M.; Kapko, V.; Henderson, D.; Boda, D. Chem. Phys. Lett. 2001, 341, 363. https://doi.org/10.1016/S0009-2614(01)00505-X