감마선을 이용한 케나프 펄프 표면의 Poly(ethylene glycol) Methacrylate 그라프트 중합반응

Surface Graft Polymerization of Poly(ethylene glycol) Methacrylate onto Kenaf Pulp using Gamma-ray Irradiation

  • 오두리 (한국원자력연구원 공업환경연구부) ;
  • 전준표 (한국원자력연구원 공업환경연구부) ;
  • 강필현 (한국원자력연구원 공업환경연구부)
  • Oh, Doori (Radiation Research Division for Industry and Environment, Korea Atomic Energy Research Institute) ;
  • Jeun, Joon Pyo (Radiation Research Division for Industry and Environment, Korea Atomic Energy Research Institute) ;
  • Kang, Phil Hyun (Radiation Research Division for Industry and Environment, Korea Atomic Energy Research Institute)
  • 투고 : 2012.07.18
  • 심사 : 2012.08.10
  • 발행 : 2012.09.30

초록

Pulp is typically used for paper industry to manufacturing various types of papers. However simply chemical modification makes enable the pulp to a wide range of application in various industrial fields. To bring the polymerization the gamma ray irradiated on the mixture of kenaf and PEGMA in various dose ranges from 20 to 60 kGy. As a results, the graft degree of 20.0% was obtained from 475 g of gamma ray irradiated pulp and PEGMA. After the polymerization, the chemical structure and morphology of the surfaces were examined by Fourier transform infrared spectroscopy, thermogravimetric analysis, and scanning electron microscope. Chemical structure of grafted pulp has significantly growth in carbonyl content with increasing the radiation dose. Also surface morphology was distinctly changed with decreased the degree of roughness and increasing the diameter. These results were explained gamma ray irradiation improve performance of graft polymerization efficiency.

키워드

과제정보

연구 과제 주관 기관 : 교육과학기술부