Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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CuI Nanoparticles as New, Efficient and Reusable Catalyst for the One-pot Synthesis of 1,4-Dihydropyridines

  • Safaei-Ghomi, Javad (Department of Organic Chemistry, Faculty of Chemistry, University of Kashan) ;
  • Ziarati, Abolfazl (Department of Organic Chemistry, Faculty of Chemistry, University of Kashan) ;
  • Teymuri, Raheleh (Department of Organic Chemistry, Faculty of Chemistry, University of Kashan)
  • Received : 2012.05.05
  • Accepted : 2012.05.16
  • Published : 2012.08.20
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Abstract

A simple one-pot synthesis of two derivatives of 1,4-dihydropyridines has been described under reflux conditions using copper iodide nanoparticles (CuI NPs) as a catalyst in high yields. This method demonstrated four-component coupling reactions of aldehydes and ammonium acetate via two pathways. In one route, the reaction was performed using 2 eq ethyl acetoacetate while in the other one 1 eq ethyl acetoacetate and 1 eq malononitrile were used. The CuI NPs was reused and recycled without any loss of activity and product yield. It is noteworthy to state that wide range of the 1,4-dihydropyridines have attracted large interest due to pharmacological and biological activities.

Keywords

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