한국섬유공학회지 (Textile Science and Engineering)

  • 제49권1호
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  • Pages.56-65
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  • 2012
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  • 1225-1089(pISSN)
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  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
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PPS/PET 및 PPS/PA66 블렌드에 대한 상용화제의 영향

Effects of Compatibilizers on PPS/PET and PPS/PA66 Blends

  • 배꽃하얀 (숭실대학교 유기신소재.파이버공학과) ;
  • 함명조 (숭실대학교 유기신소재.파이버공학과) ;
  • 김영호 (숭실대학교 유기신소재.파이버공학과)
  • Bae, Ggot-Ha-Yan (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Ham, Myong-Jo (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Kim, Young-Ho (Department of Organic Materials and Fiber Engineering, Soongsil University)
  • 투고 : 2012.01.10
  • 심사 : 2012.02.09
  • 발행 : 2012.02.28
⟨ 이전 논문 다음 논문 ⟩

초록

Two commercial compatibilizers of ethylene glycidyl methacrylate (EGMA) and styrene-b-ethylene/butyleneb-styrene grafted with maleic anhydride (SEBS-g-MA) were added to poly(phenylene sulfide) (PPS)/poly(ethylene terephthalate) (PET) (80/20, weight ratio) and PPS/polyamide 66 (PA66) (80/20, weight ratio) mixture, respectively. This was done by using a twin screw extruder via a melt blending method and the blends of the three components were melt-pressed and quenched to the films of 200 ${\mu}m$. Changes in thermal, mechanical, chemical and morphological properties of the blend films were analyzed by using DSC, DMA, WAXS, SEM and UTM. DSC results showed that EGMA in PPS(80)/PET(20)/EGMA blends lowered $T_g$ of PPS. They hindered the crystallization of both PPS and PET. Addition of EGMA imparted partial miscibility to the immiscible PPS(80)/PET(20) blends but the total miscibility and compatibility were not enhanced. Mechanical and chemical properties of PPS80/PET20/EGMA blend films deteriorated more with an increase in EGMA content. SEBS-g-MA did not work as a compatibilizer at all for PPS(80)/PA66(20) blends rather it enduced phase separation of the blends.

키워드

참고문헌

  1. J. K. Fink, "High Performance Polymers", William Andrew Inc., USA, 2008, pp.175-207.
  2. M. Lewin, "High Technology Fibers", Part A, Dekker, New York, 1985, pp.335-348.
  3. J. P. Critchley, W. W. Wright, and G. J. Knight, "Heat Resistant Polymer", Plenum Press, New York, 1984, pp.151-160
  4. J. W. S. Hearle, Ed., "High-Performance Fibres", Woodhead Publishing Ltd., USA, 2001, pp.274-277.
  5. S. Houis, M. Schmid, and J. Lubben, "New Functional Bicomponent Fibers with Core/Sheath-Configuration Using Poly(phenylene sulfide) and Poly(ethylene terephthalate)", J Appl Polym Sci, 2007, 106, 1757-1767. https://doi.org/10.1002/app.26846
  6. N. Ytaka and S. Takuji, "Core-Sheath Conjugate Fiber", JP Patent, 1992327213, Toray Ind., Inc., November 16, 1992.
  7. K. Kubo and J. Masamoto, "Dispersion of Poly(phenylene ether) in a Poly(phenylene sufide)/Poly(phenylene ether) Alloy", Macromol Mater Eng, 2001, 286, 555-559. https://doi.org/10.1002/1439-2054(20010901)286:9<555::AID-MAME555>3.0.CO;2-W
  8. W. Tang, X. Hu, J. Tang, and R. Jin, "Toughening and Compatibilization of Polyphenylene Sulfide/Nylon 66 Blends with SEBS and Maleic Anhydride Grafted SEBS Triblock Copolymers", J Appl Polym Sci, 2007, 106, 2648-2655. https://doi.org/10.1002/app.26832
  9. T. Hisamatsu, S. Nakano, T. Adachi, M. Ishikawa, and K. Iwakura, "The Effect of Compatibility on Toughness of PPS/ SEBS Polymer Alloy", Polymer, 2000, 41, 4803-4809. https://doi.org/10.1016/S0032-3861(99)00489-9
  10. D. Wu, Y. Zhang, M. Zhang, and L. Wu, "Morphology, Nonisothermal Crystallization Behavior, and Kinetics of Poly(phenylene sulfide)/Polycarbonate Blend", J Appl Polym Sci, 2007, 105, 739-748. https://doi.org/10.1002/app.26096
  11. G. H. Bae, M. J. Ham, and Y. H. Kim, "Preparation and Characterization of Poly(phenylene sulfide)/Poly(ethylene terephthalate) Blends", Text Sci Eng, 2010, 47, 352-360.
  12. G. H. Bae, M. J. Ham, and Y. H. Kim, "Effect of the Addition of PA66 and TLCP on the Properties of Poly(phenylene sulfide) Film", Text Sci Eng, 2010, 47, 389-398
  13. M. M. Coleman, P. C. Painter, and J. F. Graf, "Specific Interactions and Miscibility of Polymer Blends", Technomic Publishing Co., Inc., Lancaster, Pennsylvania, 1991.
  14. O. Olabish, L. M. Robeson, and M. Shaw, "Polymer- Polymer Miscibility", Chap. 3, Academic Press, New York, 1979.
  15. C. H. Tasi and F. C. Chang, "Polymer Blends of PBT and PP Compatibilized by Ethyleneco-glycidyl Methacrylate Copolymers", J Appl Polym Sci, 1996, 61, 321-332. https://doi.org/10.1002/(SICI)1097-4628(19960711)61:2<321::AID-APP15>3.0.CO;2-6
  16. W. Tang, X. Hu, J. Tang, and R. Jin, "Toughening and Compatibilization of Polyphenylene Sulfide/Nylon 66 Blends with SEBS and Maleic Anhydride Grafted SEBS Triblock Copolymers", J Appl Polym Sci, 2007, 106, 2648-2655. https://doi.org/10.1002/app.26832

피인용 문헌

  1. Compatibilizing Effect of Epoxy Resin on the Phase Separation and Properties of Polyamide 6/poly(ethylene terephthalate) Blends vol.51, pp.1, 2014, https://doi.org/10.12772/TSE.2014.51.021
  2. Preparation and Properties of Poly(ethylene terephthalate)/Nylon 6 Alloy Fibers Using Epoxy as a Reactive Compatibilizer(II) -Preparation and Properties of Alloy Fibers- vol.51, pp.5, 2014, https://doi.org/10.12772/TSE.2014.51.252
  3. Preparation and Properties of Alloy Fibers Obtained from Poly(ethylene terephthalate)/Polyamide 6 Blends by Using a Reactive Compatibilizer(I) -Effect of Reactive Compatibilizer on Morphology, and Thermal and Rheological Properties- vol.51, pp.2, 2014, https://doi.org/10.12772/TSE.2014.51.084