DOI QR코드

DOI QR Code

Adsorption of cationic dye (MB) and anionic dye (AG 25) by physically and chemically activated carbons developed from rice husk

  • Youssef, A.M. (Department of Chemistry, Faculty of Science, Mansoura University) ;
  • Ahmed, A.I. (Department of Chemistry, Faculty of Science, Mansoura University) ;
  • El-Bana, U.A. (Department of Chemistry, Faculty of Science, Mansoura University)
  • Received : 2012.01.25
  • Accepted : 2012.04.02
  • Published : 2012.04.30

Abstract

Dye removal from waste water via adsorption by activated carbons (ACs) developed from agricultural wastes represents an ideal alternative to other expensive treatment options. Physical and chemical ACs were prepared from rice husks. The textural properties of the ACs were characterized by Brunauer-Emmett-Teller-$N_2$ adsorption and scanning electron microscopy. The chemistry of the carbon surface was investigated by Fourier transform infrared spectroscopy, base and acid neutralization capacities, pH of the active carbon slurry, and $pH_{pzc}$. The adsorption capacities of the ACs for the basic dye (methylene blue) and acid dye (acid green 25) were determined using parameters such as contact time, pH, and temperature. NaOH-ACs showed the highest surface area and total pore volume, whereas steam-ACs showed the lowest ones.

Keywords

References

  1. Youssef AM, Radwan NRE, Abdel-Gawad I, Singer GAA. Textural properties of activated carbons from apricot stones. Colloids Surf A: Physicochem Eng Aspects, 252, 143 (2005). http://dx.doi.org/10.1016/j.colsurfa.2004.09.008.
  2. Youssef AM, El-Nabarawy T, Samra SE. Sorption properties of chemically-activated carbons: 1. Sorption of cadmium(II) ions. Colloids Surf A: Physicochem Eng Aspects, 235, 153 (2004). http://dx.doi.org/10.1016/j.colsurfa.2003.12.017.
  3. Baccar R, Bouzid J, Feki M, Montiel A. Preparation of activated carbon from Tunisian olive-waste cakes and its application for adsorption of heavy metal ions. J Hazard Mater, 162, 1522 (2009). http://dx.doi.org/10.1016/j.jhazmat.2008.06.041.
  4. Liou TH, Wu SJ. Characteristics of microporous/mesoporous carbons prepared from rice husk under base- and acid-treated conditions. J Hazard Mater, 171, 693 (2009). http://dx.doi.org/10.1016/j. jhazmat.2009.06.056.
  5. Anson A, Lafuente E, Urriolabeitia E, Navarro R, Benito AM, Maser WK, Martinez MT. Hydrogen capacity of palladium-loaded carbon materials. J Phys Chem B, 110, 6643 (2006). http://dx.doi. org/10.1021/jp057206c.
  6. Lozano-Castello D, Cazorla-Amoros D, Linares-Solano A. Powdered activated carbons and activated carbon fibers for methane storage: a comparative study. Energy Fuels, 16, 1321 (2002). http://dx.doi.org/10.1021/ef020084s.
  7. Darkrim FL, Malbrunot P, Tartaglia GP. Review of hydrogen storage by adsorption in carbon nanotubes. Int J Hydrogen Energy, 27, 193 (2002). http://dx.doi.org/10.1016/s0360-3199(01)00103-3.
  8. Chang CF, Chang CY, Tsai WT. Effects of burn-off and activation temperature on preparation of activated carbon from corn cob agrowaste by $CO_{2}$ and steam. J Colloid Interface Sci, 232, 45 (2000). http://dx.doi.org/10.1006/jcis.2000.7171.
  9. Guo J, Lua AC. Textural and chemical characterizations of adsorbent prepared from palm shell by potassium hydroxide impregnation at different stages. J Colloid Interface Sci, 254, 227 (2002). http://dx.doi.org/10.1006/jcis.2002.8587.
  10. Hamdaoui O, Saoudi F, Chiha M, Naffrechoux E. Sorption of malachite green by a novel sorbent, dead leaves of plane tree: equilibrium and kinetic modeling. Chem Eng J, 143, 73 (2008). http://dx.doi.org/10.1016/j.cej.2007.12.018.
  11. Aksu Z. Application of biosorption for the removal of organic pollutants: a review. Process Biochem, 40, 997 (2005). http://dx.doi.org/10.1016/j.procbio.2004.04.008.
  12. Balathanigaimani MS, Shim WG, Park KH, Lee JW, Moon H. Effects of structural and surface energetic heterogeneity properties of novel corn grain-based activated carbons on dye adsorption. Microporous Mesoporous Mater, 118, 232 (2009). http://dx.doi.org/10.1016/j.micromeso.2008.08.028.
  13. Wu FC, Tseng RL. High adsorption capacity NaOH-activated carbon for dye removal from aqueous solution. J Hazard Mater, 152, 1256 (2008). http://dx.doi.org/10.1016/j.jhazmat.2007.07.109.
  14. Wu JS, Liu CH, Chu KH, Suen SY. Removal of cationic dye methyl violet 2B from water by cation exchange membranes. J Membr Sci, 309, 239 (2008). http://dx.doi.org/10.1016/j.memsci.2007.10.035.
  15. Sharma YC, Uma. Optimization of parameters for adsorption of methylene blue on a low-cost activated carbon. J Chem Eng Data, 55, 435 (2009). http://dx.doi.org/10.1021/je900408s.
  16. McKay G. Waste color removal from textile effluents. Am Dyest Rep, 68, 29 (1979).
  17. Khare SK, Panday KK, Srivastava RM, Singh VN. Removal of victoria blue from aqueous solution by fly ash. J Chem Technol Biotechnol, 38, 99 (1987). http://dx.doi.org/10.1002/jctb.280380206.
  18. Gupta VK, Suhas, Ali I, Saini VK. Removal of rhodamine B, fast green, and methylene blue from wastewater using red mud, an aluminum industry waste. Ind Eng Chem Res, 43, 1740 (2004). http://dx.doi.org/10.1021/ie034218g.
  19. Hameed BH, Daud FBM. Adsorption studies of basic dye on activated carbon derived from agricultural waste: Hevea brasiliensis seed coat. Chem Eng J, 139, 48 (2008). http://dx.doi.org/10.1016/j.cej.2007.07.089.
  20. Alaya MN, Hourieh MA, Youssef AM, El S, El-Sejariah F. Adsorption properties of activated carbons prepared from olive stones by chemical and physical activation. Adsorpt Sci Technol, 18, 27 (2000). http://dx.doi.org/10.1260/0263617001493251.
  21. Youssef AM, Alaya MN, Nawar N. Adsorption properties of activated carbon from polymer wastes. Adsorp Sci Technol, 11, 225 (1994). https://doi.org/10.1177/026361749401100405
  22. Lillo-Rodenas MA, Lozano-Castello D, Cazorla-Amoros D, Linares- Solano A. Preparation of activated carbons from Spanish anthracite: II. Activation by NaOH. Carbon, 39, 751 (2001). http://dx.doi.org/10.1016/s0008-6223(00)00186-x.
  23. Orfao JJM, Silva AIM, Pereira JCV, Barata SA, Fonseca IM, Faria PCC, Pereira MFR. Adsorption of a reactive dye on chemically modified activated carbons-Influence of pH. J Colloid Interface Sci, 296, 480 (2006). http://dx.doi.org/10.1016/j.jcis.2005.09.063.
  24. Boehm HP. Surface oxides on carbon and their analysis: a critical assessment. Carbon, 40, 145 (2002). http://dx.doi.org/10.1016/ s0008-6223(01)00165-8.
  25. Valdes H, Sanchez-Polo M, Rivera-Utrilla J, Zaror CA. Effect of ozone treatment on surface properties of activated carbon. Langmuir, 18, 2111 (2002). http://dx.doi.org/10.1021/la010920a.
  26. Brunauer S, Deming LS, Deming WE, Teller E. On a theory of the van der Waals adsorption of gases. J Am Chem Soc, 62, 1723 (1940). http://dx.doi.org/10.1021/ja01864a025.
  27. Youssef AM, El-Khouly AI, Ahmed AI, El-Shafey EI. Changes in adsorption properties of activated carbons due to partial oxidation of the surface. Adsorp Sci Technol, 12, 211 (1995). https://doi.org/10.1177/026361749501200305
  28. Brunauer S, Emmett PH, Teller E. Adsorption of gases in multimolecular layers. J Am Chem Soc, 60, 309 (1938). http://dx.doi. org/10.1021/ja01269a023.
  29. Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Roquerol J, Siemieniewska T. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl Chem, 57, 603 (1985). http:// dx.doi.org/10.1351/pac198557040603.
  30. Selles-Perez MJ, Martin-Martinez JM. Application of $\alpha$ and n plots to N2 adsorption isotherms of activated carbons. J Chem Soc Faraday Trans, 87, 1237 (1991). http://dx.doi.org/10.1039/ FT9918701237.
  31. Kennedy LJ, Vijaya JJ, Sekaran G. Electrical conductivity study of porous carbon composite derived from rice husk. Mater Chem Phys, 91, 471 (2005). http://dx.doi.org/10.1016/j.matchemphys. 2004.12.013.
  32. El-Sharkawy EA, Soliman AY, Al-Amer KM. Comparative study for the removal of methylene blue via adsorption and photocatalytic degradation. J Colloid Interface Sci, 310, 498 (2007). http:// dx.doi.org/10.1016/j.jcis.2007.02.013.
  33. Kennedy LJ, Vijaya JJ, Sekaran G. Effect of two-stage process on the preparation and characterization of porous carbon composite from rice husk by phosphoric acid activation. Ind Eng Chem Res, 43, 1832 (2004). http://dx.doi.org/10.1021/ie034093f.
  34. Guo Y, Rockstraw DA. Physical and chemical properties of carbons synthesized from xylan, cellulose, and Kraft lignin by $H_{3}PO_{4}$ activation. Carbon, 44, 1464 (2006). http://dx.doi.org/10.1016/j. carbon.2005.12.002.
  35. Wang S, Zhu ZH, Coomes A, Haghseresht F, Lu GQ. The physical and surface chemical characteristics of activated carbons and the adsorption of methylene blue from wastewater. J Colloid Interface Sci, 284, 440 (2005). http://dx.doi.org/10.1016/j.jcis.2004.10.050.
  36. Malik PK. Use of activated carbons prepared from sawdust and rice-husk for adsorption of acid dyes: a case study of Acid Yellow 36. Dyes Pigments, 56, 239 (2003). http://dx.doi.org/10.1016/s0143-7208(02)00159-6.
  37. Langergren S, Svenska BK. Zur theorie der sogenannten adsorption geloester stoffe. Veternskapsakad Handlingar, 24, 1 (1898).
  38. Ho YS, Chiang CC. Sorption studies of acid dye by mixed sorbents. Adsorption, 7, 139 (2001). http://dx.doi.org/10.1023/a:1011652224816.
  39. Weber WJ, Morris JC. Kinetics of adsorption on carbon from solution. J San Eng Div ASCE, 89, 31 (1963).
  40. Langmuir I. The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc, 40, 1361 (1918). http://dx.doi. org/10.1021/ja02242a004.
  41. Bhattacharyya KG, Sharma A. Kinetics and thermodynamics of Methylene Blue adsorption on Neem (Azadirachta indica) leaf powder. Dyes Pigments, 65, 51 (2005). http://dx.doi.org/10.1016/j.dyepig.2004.06.016.

Cited by

  1. Modeling and Characterization of Steam-Activated Carbons Developed from Cotton Stalks vol.14, pp.1, 2013, https://doi.org/10.5714/CL.2012.14.1.014
  2. Removal of deltamethrin insecticide over highly porous activated carbon prepared from pistachio nutshells vol.14, pp.4, 2013, https://doi.org/10.5714/CL.2013.14.4.234
  3. Preparation and characterization of microporous NaOH-activated carbons from hydrofluoric acid leached rice husk and its application for lead(II) adsorption vol.15, pp.1, 2014, https://doi.org/10.5714/CL.2014.15.1.057
  4. Adsorption of endocrine disrupting ethylparaben from aqueous solution by chemically activated biochar developed from oil palm fibre pp.1520-5754, 2018, https://doi.org/10.1080/01496395.2018.1520723