Advances in materials Research

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One-pot synthesis of gold trisoctahedra with high-index facets

  • Kim, Do Youb (Department of Chemical and Biomolecular Engineering (BK21 graduate program), Korea Advanced Institute of Science and Technology (KAIST)) ;
  • Choi, Kyeong Woo (Department of Chemical and Biomolecular Engineering (BK21 graduate program), Korea Advanced Institute of Science and Technology (KAIST)) ;
  • Im, Sang Hyuk (KRICT-EPFL Global Research Laboratory, Advanced Materials Division, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Park, O Ok (Department of Chemical and Biomolecular Engineering (BK21 graduate program), Korea Advanced Institute of Science and Technology (KAIST)) ;
  • Zhong, Xiao-Lan (Institute of Physics, Chinese Academy of Science) ;
  • Li, Zhi-Yuan (Institute of Physics, Chinese Academy of Science)
  • Received : 2011.09.30
  • Accepted : 2012.03.16
  • Published : 2012.03.25
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Abstract

There have been many efforts on the generating metal nanocrystals enclosed by high-index facets for the use as highly active catalysts. This paper describes a facile synthesis of Au trisoctahedra with high-index facets. In brief, the Au trisoctahdra were prepared by reduction of $HAuCl_4$ in N,N-dimethylformamide (DMF) containing poly (vinyl pyrrolidone) (PVP) and trace amount of $AgNO_3$. The Ag ions in the reaction solution played a critical role in controlling the trisoctahedral shape of the final product by underpotential deposition (UPD) on the Au surfaces. The as-prepared Au trisoctahedra were single crystal and enclosed by high-index {441}, {773} and {331} facets.

Keywords

Acknowledgement

Supported by : National Research Foundation of Korea (NRF)

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