Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Montmorillonite/Poly(acrylic acid-co-2-acrylamido-2-methyl-1-propane sulfonic acid) Superabsorbent Composite and the Study of its Adsorption

  • Zhu, Linhui (College of Chemical and Environmental Engineering, Shandong University of Science and Technology) ;
  • Zhang, Lili (College of Chemical and Environmental Engineering, Shandong University of Science and Technology) ;
  • Tang, Yaoji (College of Chemical and Environmental Engineering, Shandong University of Science and Technology)
  • Received : 2011.10.07
  • Accepted : 2012.02.16
  • Published : 2012.05.20
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Abstract

A novel superabsorbent composite was prepared by intercalation polymerization of acrylic acid (AA) and 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) in the presence of montmorillonite (MMT), using ammonium persulfate (APS) as an initiator and $N,N'$-methylenebisacrylamide (MBA) as a cross linker. The superabsorbent composite was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). Maximum absorbency of the composite in distilled water and 0.9% sodium chloride solution was 722 and 108 g/g, respectively. The composite was used for removal of heavy metal ions from aqueous solutions. Maximum amount of adsorption for $Ni^{2+}$, $Cu^{2+}$ and $Pb^{2+}$ was 211.0, 159.6 and 1646.0 mg/g, respectively, and the adsorption was in accordance with both Langmuir and Freundlich model. The composite could be regenerated and reused in wastewater treatment.

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References

  1. Chen, Q. Y.; Luo, Z.; Hills, C.; Xue, G.; Tyrer, M. Water Res. 2009, 43, 2605-2614. https://doi.org/10.1016/j.watres.2009.03.007
  2. Landaburu-Aguirre, J.; García, V.; Pongracz, E.; Keiski, R. L. Desalination 2009, 240, 262-269. https://doi.org/10.1016/j.desal.2007.11.077
  3. Duan, J. C.; Lu, Q.; Chen, R. W.; Duan, Y. Q.; Wang, L. F.; Gao, L.; Pan, S. Y. Carbohydr. Polym. 2010, 80, 436-441. https://doi.org/10.1016/j.carbpol.2009.11.046
  4. Nanseu-Njiki, C. P.; Tchamango, S. R.; Ngom, P. C.; Darchen, A.; Ngameni, E. J. Hazard. Mater. 2009, 168, 1430-1436. https://doi.org/10.1016/j.jhazmat.2009.03.042
  5. Doula, M. K. Water Res. 2009, 43, 3659-3672. https://doi.org/10.1016/j.watres.2009.05.037
  6. Jiang, M. Q.; Jin, X. Y.; Lu, X. Q.; Chen, Z. L. Desalination 2010, 252, 33-39. https://doi.org/10.1016/j.desal.2009.11.005
  7. Liu, M. Z.; Liang, R.; Zhan, F. L.; Liu, Z.; Niu, A. Z. Polym. Advan. Technol. 2006, 47, 430-438.
  8. Kosemund, K.; Schlatter, H.; Ochsenhirt, J. L.; Krause, E. L.; Marsman, D. S.; Erasala, G. N. Regul. Toxicol. Pharmacol. 2009, 53, 81-89. https://doi.org/10.1016/j.yrtph.2008.10.005
  9. Wang, Q.; Zhang, J. P.; Wang, A. Q. Carbohydr. Polym. 2009, 78, 731-737. https://doi.org/10.1016/j.carbpol.2009.06.010
  10. Kasguz, H.; Durmus, A. Polym. Advan. Technol. 2008, 19, 838- 845. https://doi.org/10.1002/pat.1045
  11. Su, X. F.; Zhang, G.; Xu, K.; Wang, J. H.; Song, C. L.; Wang, P. X. Polym. Bull. 2008, 60, 69-78. https://doi.org/10.1007/s00289-007-0843-0
  12. Li, A.; Wang, A. Q. Eur. Polym. J. 2005, 41, 1630-1637. https://doi.org/10.1016/j.eurpolymj.2005.01.028
  13. Guclu, G.; Al, E.; Emik, S.; yim, T. B.; Ozgümü , S.; Ozyurek, M. Polym. Bull. 2010, 65, 333-346. https://doi.org/10.1007/s00289-009-0217-x
  14. Bao, Y.; Ma, J. Z.; Li, N. Carbohydr. Polym. 2011, 84, 76-82 https://doi.org/10.1016/j.carbpol.2010.10.061
  15. Wu, X. J.; Yu, Y. F.; Yuan, J. Z. Non-Metallic Mines 2008, 31, 1-2, 61.
  16. Su, X. F.; Zhang, G.; Xu, K.; Wang, J. H.; Song, C. L.; Wang, P. X. Polym. Bull. 2008, 60, 69-78. https://doi.org/10.1007/s00289-007-0843-0
  17. Zhang, J.; Li, A.; Wang, A. Q. Carbohydr. Polym. 2006, 65, 150- 158. https://doi.org/10.1016/j.carbpol.2005.12.035
  18. Molu, Z. B.; Seki, Y.; Yurdako , K. Polym. Bull. 2010, 64, 171- 183. https://doi.org/10.1007/s00289-009-0155-7
  19. Zhang, Y.; Fan, L.; Cheng, L.; Zhang, L.; Chen, H. Polym. Eng. Sci. 2009, 49, 264-271. https://doi.org/10.1002/pen.21252
  20. Tong, X.; Zhao, H.; Tang, T.; Feng, Z.; Huang, B. J. Polym. Sci. Part. A: Polym. Chem. 2002, 40, 1706-1711. https://doi.org/10.1002/pola.10251
  21. Liang, R.; Liu, M. Z.; Wu, L. React. Funct. Polym. 2007, 67, 769- 779. https://doi.org/10.1016/j.reactfunctpolym.2006.12.007
  22. Kabiri, K.; Zohuriaan-Mehr, M. J. Polym. Adv. Technol. 2003, 14, 438-444. https://doi.org/10.1002/pat.356
  23. Gao, J. Z.; Ma, D. L.; Lu, Q. F.; Li, Y.; Li, X. F.; Yang, W. Plasma Chem. Plasma Process 2010, 30, 1-11. https://doi.org/10.1007/s11090-009-9207-x
  24. Yang, R. C.; Mu, Y. C.; Yun, D.; Yang, J. Polym. Mater. Sci. Eng. 2009, 25, 64-67.
  25. Lin, Y. B.; Xing, J.; Shi, Y. F.; Cai, T. J. Environmental Protection Science 2008, 34, 21-24.

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