Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Preparation and Catalytic Application of Pd Loaded Titanate Nanotube: Highly Selective α Alkylation of Ketones with Alcohols

  • Jang, Jum-Suk (Department of Chemical Engineering and School of Environmental Science and Engineering, Pohang University of Science and Technology (POSTECH)) ;
  • Kwon, Min-Serk (Department of Chemistry, Pohang University of Science and Technology (POSTECH)) ;
  • Kim, Hyun-Gyu (Busan Center, Korea Basic Science Institute (KBSI)) ;
  • Park, Jae-Wook (Department of Chemistry, Pohang University of Science and Technology (POSTECH)) ;
  • Lee, Jae-Sung (Department of Chemical Engineering and School of Environmental Science and Engineering, Pohang University of Science and Technology (POSTECH))
  • Received : 2012.01.19
  • Accepted : 2012.01.19
  • Published : 2012.05.20
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Abstract

The titanate nanotube (TNT) was hydrothermally synthesized in 10 M NaOH aqueous solution at $150^{\circ}C$ for 72 h. Titanate nanotube with high surface area (292 $m^2$/g) is a good candidate as a support for catalytic reaction or organic synthesis. Palladium nanoparticles with an average size of $ca$. 3 nm were well dispersed onto the surface of TNT nanotubes. Palladium loaded catalyst with high surface area shows a highly efficient ${\alpha}$ alkylation of ketones with primary alcohols.

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References

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