DOI QR코드

DOI QR Code

Electrical and Thermal Properties of Poly(p-phenylene sulfide) Reduced Graphite Oxide Nanocomposites

  • Chae, Byung-Jae (Institute of Advanced Composites Materials, Korea Institute of Science and Technology) ;
  • Kim, Do Hwan (Korea Institute for Knit Industry) ;
  • Jeong, In-Soo (Korea Institute of Science and Technology Information) ;
  • Hahn, Jae Ryang (Department of Chemistry and Research Institute of Physics and Chemistry, Chonbuk National University) ;
  • Ku, Bon-Cheol (Institute of Advanced Composites Materials, Korea Institute of Science and Technology)
  • Received : 2012.08.08
  • Accepted : 2012.10.01
  • Published : 2012.10.31

Abstract

Graphite oxide (GO) was produced using the modified Hummer's method. Poly(p-phenylene sulfide) (PPS)/reduced graphite oxide (RGO) composites were prepared by in situ polymerization method. The electrical conductivity of the PPS/RGO composites was no more than 82 S/m. It was found that as GO content increased in the PPS/RGO composites, the crystallization temperature and electrical conductivity of the composites increased and the percolation threshold value was at 5-8 wt% of GO content.

Keywords

Acknowledgement

Supported by : Korea Institute of Science and Technology (KIST)

References

  1. Lee S, Kim YJ, Kim DH, Ku BC, Joh HI. Synthesis and properties of thermally reduced graphene oxide/polyacrylonitrile composites. J Phys Chem Solids, 73, 741 (2012). http://dx.doi.org/10.1016/j. jpcs.2012.01.015.
  2. Zheng D, Tang G, Zhang HB, Yu ZZ, Yavari F, Koratkar N, Lim SH, Lee MW. In situ thermal reduction of graphene oxide for high electrical conductivity and low percolation threshold in polyamide 6 nanocomposites. Comp Sci Technol, 72, 284 (2012). http:// dx.doi.org/10.1016/j.compscitech.2011.11.014.
  3. Wang X, Zhi L, Mullen K. Transparent, conductive graphene electrodes for dye-sensitized solar cells. Nano Lett, 8, 323 (2008). http://dx.doi.org/10.1021/nl072838r.
  4. Moon IK, Lee JH, Rouff RS, Lee HY. Reduced graphene oxide by chemical graphitization. Nat Commun, 1, 73 (2010). http://dx.doi. org/10.1038/ncomms1067.
  5. Hernandez Y, Nicolosi V, Lotya M, Blighe FM, Sun Z, De S, Mc- Govern IT, Holland B, Byrne M, Gun'Ko YK, Boland JJ, Niraj P, Duesberg G, Krishnamurthy S, Goodhue R, Hutchison J, Scardaci V, Ferrari AC, Coleman JN. High-yield production of graphene by liquid-phase exfoliation of graphite. Nat Nanotechnol, 3, 563 (2008). http://dx.doi.org/10.1038/nnano.2008.215.
  6. Li D, Muller MB, Gilje S, Kaner RB, Wallace GG. Processable aqueous dispersions of graphene nanosheets. Nat Nanotechnol, 3, 101 (2008). http://dx.doi.org/10.1038/nnano.2007.451.
  7. Becerril HA, Mao J, Liu Z, Stoltenberg RM, Bao Z, Chen Y. Evaluation of solution-processed reduced graphene oxide films as transparent conductors. ACS Nano, 2, 463 (2008). http://dx.doi. org/10.1021/nn700375n.
  8. Park OK, Hahm MG, Lee S, Joh HI, Na SI, Vajtai R, Lee JH, Ku BC, Ajayan PM. In situ synthesis of thermochemically reduced graphene oxide conducting nanocomposites. Nano Lett, 12, 1789 (2012). http://dx.doi.org/10.1021/nl203803d.
  9. Margolis JM. Engineering thermoplastics: properties and applications, Dekker, New York (1985).
  10. Park LS, Lee SC, Nam JI. Synthesis and thermal-properties of random- copoly(p-phenylene/biphenylene sulfide)s. Polymer, 37, 1339 (1996). http://dx.doi.org/ 10.1016/0032-3861(96)81130-X.
  11. Campbell RW, Scoggins LE. US Patent, 3,869,434 (1975).
  12. Macallum AD. A dry synthesis of aromatic sulfides: phenylene sulfide resins. J Org Chem, 13, 154 (1948). http://dx.doi.org/10.1021/jo01159a020.
  13. Lenz RW, Handlovits CE, Smith HA. Phenylene sulfide polymers. III. The synthesis of linear polyphenylene sulfide. J Polym Sci, 58, 351 (1962). http://dx.doi.org/10.1002/pol.1962.1205816620.
  14. Edmonds JT Jr., Hill HW Jr.. US Patent, 3,524,835 (1970).
  15. Hummers WS. Offeman RE. Preparation of graphitic oxide. J Am Chem Soc, 80, 1339 (1958). http://dx.doi.org/10.1021/ ja01539a017.
  16. Zhao YF, Xiao M, Wang SJ, Ge XC, Meng YZ. Preparation and properties of electrically conductive PPS/expanded graphite nanocomposites. Comp Sci Technol, 67, 2528 (2007). http://dx.doi. org/10.1016/j.compscitech.2006.12.009.

Cited by

  1. A High-Performance Graphene Oxide-Doped Ion Gel as Gel Polymer Electrolyte for All-Solid-State Supercapacitor Applications vol.23, pp.26, 2013, https://doi.org/10.1002/adfm.201203556