Membrane Journal (멤브레인)

The Membrane Society of Korea (한국막학회)
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Supported Ionic Liquid Membrane Preparation for Carbon Dioxide Separation

이산화탄소 분리를 위한 이온성액체 지지분리막의 제조

  • Choi, Mi Young (Department of Chemical and Biomolecular Engineering Seoul National University of Technology & Science) ;
  • Chung, Kun Yong (Department of Chemical and Biomolecular Engineering Seoul National University of Technology & Science)
  • 최미영 (서울과학기술대학교 화공생명공학과) ;
  • 정건용 (서울과학기술대학교 화공생명공학과)
  • Received : 2012.08.27
  • Accepted : 2012.08.30
  • Published : 2012.08.31
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Abstract

The study is aiming to prepare supported ionic liquid membranes for carbon dioxide separation efficiently. The ionic liquid, [bmim][${PF_6}^-$] (1-butyl-3-methyl-imidazolium hexafluorophosphate) was fixed in the pores of PVDF micro-filtration membrane with a nominal pore size 0.1 ${\mu}m$. The permeabilities of $N_2$, $H_2$ and $CO_2$ gases through the prepared ionic liquid membrane were 0.075, 0.203 and 1.380 GPU, respectively. The selectivities of $CO_2/N_2$, $H_2/N_2$ were 14.2 and 2.69, respectively. Also, the supported ionic liquid membrane could be operated stably up to 2.0 bar with the immobilization of ionic liquid in the pores.

본 연구는 이산화탄소를 효율적으로 분리하기 위한 이온성액체 지지분리막 제조를 목적으로 한다. 공칭크기 0.1 ${\mu}m$ PVDF 정밀여과막에 이온성액체인 [bmim][${PF_6}^-$] (1-butyl-3-methylimidazolium hexafluorophosphate)를 분리막 세공내로 흡입시켜 고정화하였다. 제조된 이온성액체 지지막에 대한 $N_2$, $H_2$, $CO_2$ 기체의 투과도는 0.075, 0.203, 1.380 GPU로 측정되었으며 $CO_2/N_2$, $H_2/N_2$의 선택도는 각각 14.2와 2.69이었다. 또한 이온성액체 지지분리막은 이온성 액체가 운전압력 2.0 bar까지 세공 내에 고정되어 안정적으로 운전 가능하였다.

Keywords

Acknowledgement

Supported by : 서울과학기술대학교

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