SI 열화학 수소 생산 공정의 분석을 위한 열역학 모델의 적용

Application of Thermodynamic Models for Analysis on SI Thermochemical Hydrogen Production Process

  • 이준규 (한국교통대학교 화공생물공학과) ;
  • 김기섭 (한국교통대학교 화공생물공학과) ;
  • 박병흥 (한국교통대학교 화공생물공학과)
  • Lee, Jun Kyu (Department of Chemical and Biological Engineering, Korea National University of Transportation) ;
  • Kim, Ki-Sub (Department of Chemical and Biological Engineering, Korea National University of Transportation) ;
  • Park, Byung Heung (Department of Chemical and Biological Engineering, Korea National University of Transportation)
  • 투고 : 2012.10.08
  • 심사 : 2012.11.02
  • 발행 : 2012.11.30

초록

The SI thermochemical cycle process accomplishes water splitting through distinctive three chemical reactions. We focused on thermodynamic models applicable to the process. Recently, remarkable models based on the assumed ionic species have been developed to describe highly nonideal behavior on the liquid phase reactions. ElecNRTL models with ionic reactions were proposed in order to provide reliable process simulation results for phase equilibrium calculations in Section II and III. In this study, the current thermodynamic models of SI thermochemical cycle process were briefly described and the calculation results of the applied ElecNRTL models for phase equilibrium calculations were illustrated for binary systems.

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