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Toxicological Investigation of Radioactive Uranium in Seawater

  • Ly, Suw-Young (Biosensor Research Institute, Seoul National University of Science and Technology) ;
  • Bae, Jeong-Mi (Biosensor Research Institute, Seoul National University of Science and Technology) ;
  • Kim, Jin (Biosensor Research Institute, Seoul National University of Science and Technology)
  • Received : 2011.11.11
  • Accepted : 2012.03.29
  • Published : 2012.03.31

Abstract

Trace uranium detection measurement was performed using DNA immobilized on a graphite pencil electrode(DGE). The developed probe was connected to the portable handheld voltammetric systems used for seawater analysis. The sensitive voltammogram was obtained within only 30 s accumulation time, and the anodic stripping working range was attained at 100~800 ${\mu}g/l$ U and 10~50 ${\mu}g/l$. The statistic relative standard deviation of 30.0 mg/l with the $15^{th}$ stripping was 0.2115. Here, toxicological and analytical application was performed in the seawater survey in a contaminated power plant controlling water. The results were found to be applicable for real-time toxicological assay for trace control.

Keywords

References

  1. Cha, K.W., Park, C.I. and Park, S.H. (2000). Simultaneous determination of trace uranium(VI) and zinc(II) by adsorptive cathodic stripping voltammetry with aluminon ligand. Talanta., 52, 983-989. https://doi.org/10.1016/S0039-9140(00)00472-0
  2. Djogic, R., Pizeta, I. and Branica, M. (2001). Eelectrchemical Determination of Dissolved Uranium In Krka River. Water Res., 35, 1915-1920. https://doi.org/10.1016/S0043-1354(00)00459-0
  3. Goldberg, E.L., Grachev, M.A., Chebykin, E.P., Phedorin, M.A., Kalugin, I.A., Khlystov, O.M., Zolotarev, K.V. (2005). Scanning SRXF analysis and isotopes of uranium series from bottom sediments of Siberian lakes for high-resolution climate reconstructions. Nuclear Instruments and Methods in Physics Research A, 543, 250-254. https://doi.org/10.1016/j.nima.2005.01.216
  4. Kahr, M.S., Abney, K.D. and Olivares, J.A. (2001). Analysis of solid uranium samples using a small mass spectrometer. Spectrochimica Acta Part B, 56, 1127-1132. https://doi.org/10.1016/S0584-8547(01)00235-X
  5. Lestaevel, P., Houpert, P., Bussy, C., Dhieux, B., Gourmelon, B. and Paquet, F. (2005). The brain is a target organ after acute exposure to depleted uranium. Toxicology, 212, 219-226. https://doi.org/10.1016/j.tox.2005.05.002
  6. Lin, L., Thongngamdee, S., Wang, J., Lin, Y., Sadik, O.A. and Ly, S.Y. (2005). Adsorptive stripping voltammetric measurements of trace uranium at the bismuth film electrode. Analytica. Chimica. Acta., 535, 9-13. https://doi.org/10.1016/j.aca.2004.12.003
  7. Ly, S.Y. and Kim, M.J. (2009). Diagnostic assay of chromium (VI) in the ex vivo fluid of the urine of a smoker using a fluorinedoped handmade sensor. J. Clin. Lab. Anal., 23, 82-87. https://doi.org/10.1002/jcla.20294
  8. Ly, S.Y., Jung, Y.S., Lee, C.H. and Lee, B.W. (2008). Administering Pesticide Assays in In Vivo-Implanted Biosensors. Aust. J. Chem., 61, 826-832. https://doi.org/10.1071/CH08028
  9. Ly, S.Y., Kim, J.E. and Moon, W.Y. (2011). Diagnostic assay of carcinoembryonic antigen tumor markers using a fluorine immobilized biosensor with handmade voltammetric circuit. Eur. J. Cancer Prev., 20, 58-62. https://doi.org/10.1097/CEJ.0b013e328341e2e3
  10. Ly, S.Y., Lee, C.H. and Jung, Y.S. (2009). Voltammetric bioassay of caffeine using sensor implant. Neuromolecular. Med., 11, 20- 27. https://doi.org/10.1007/s12017-008-8057-7
  11. Ly, S.Y., Lee, J.H. and Jung, D.H. (2010). Radioactive uranium measurement in vivo using A HandheldD interfaced analyzer. Environ. Toxicol. Chem., 29, 1025-1030.
  12. Ly, S.Y., Yoo, H.S., Kim, N.J., Lee, J.H., Woo, S.S., Kwon, M.G. and Lee, S.H. (2011). Diagnostic assay of trace lead in an ex vivo tissue using a combination electrode. Environ. Toxicol. Pharmacol., 31, 51-56. https://doi.org/10.1016/j.etap.2010.09.005
  13. Murakami, H. (2011). 7 Japanese writer and translator, http://media.daum.net/.
  14. Pretty, J.R., Van Berkel, G.J. and Duckworth, D.C. (1998). Adsorptive stripping voltammetry as a sample pretreatment method for trace uranium determinations by inductively coupled plasma mass spectrometry. International Journal of Mass Spectrometry, 178, 51-63. https://doi.org/10.1016/S1387-3806(98)80001-8
  15. Saccomanno, G., Huth, G.C., Auerbach, O. and Kuschner, M. (1988). Relationship of radioactive radon daughters and cigarette smoking in the genesis of lung cancer in uranium miners. Cancer, 62, 1402-1408.
  16. Salama, T.A., El-Asser, M.R., Perelygin, V.P., Belov, A.C., Kravets, L.I. and Petrova, R.I. (2003). Uranium and thorium content determination in solids using thermal neutron and double gamma irradiation methods. Radiation Measurements, 36, 537-539. https://doi.org/10.1016/S1350-4487(03)00197-5
  17. Sela, H., Karpas, Z., Zoriy, M., Pickhardt, C. and Becker, J.S. (2007). Biomonitoring of hair samples by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). International Journal of Mass Spectrometry, 261, 199-207. https://doi.org/10.1016/j.ijms.2006.09.018
  18. Storm, H.H., Jorgensen, H.O., Kejs, A.M. and Engholm, G. (2006). Depleted uranium and cancer in Danish Balkan veterans deployed 1992-2001. Eur. J. Cacer, 42, 2355-2358.
  19. Zheng, J. and Yamada, M. (2006). Determination of U isotope ratios in sediments using ICP-QMS after sample cleanup with anion-exchange and extraction chromatography. Talanta., 68, 932-939. https://doi.org/10.1016/j.talanta.2005.06.065