Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Morita-Baylis-Hillman Route to Dimethyl 2,3-Dihydrobenzo[b]oxepine-2,4-dicarboxylates and Methyl 2-(2-Carbomethoxybenzo[b]furan-3-yl)propanoates from Salicylaldehydes

  • Ahn, Sang-Hyun (Department of Chemical Engineering, Hanyang University) ;
  • Jang, Seung-Soon (Department of Chemical Engineering, Hanyang University) ;
  • Kim, Young-Keun (Department of Chemical Engineering, Hanyang University) ;
  • Lee, Kee-Jung (Department of Chemical Engineering, Hanyang University)
  • Received : 2011.11.17
  • Accepted : 2011.11.21
  • Published : 2012.01.20
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Abstract

A new synthetic method for dimethyl 2,3-dihydrobenzo[b]oxepine-2,4-dicarboxylates and methyl 2-(2-carbomethoxybenzo[b]furan-3-yl)propanoates by an intramolecular conjugate displacement reaction or an $S_N2$ reaction of acetates of Morita-Baylis-Hillman adducts of methyl (2-formylphenoxy)acetates has been described.

Keywords

References

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