DOI QR코드

DOI QR Code

Preparation of Emulsion from Biodegradable Polymer (I) - Preparation of PLA and PBS Emulsions -

생분해성 고분자를 이용한 발수 에멀션의 제조 (I) - PLA 및 PBS 에멀션의 제조 -

  • Lee, Min-Hyung (Dept. of Wood Science and Technology, College of Agriculture and Life Science, Kyungpook National University) ;
  • Kim, Kang-Jae (Dept. of Wood Science and Technology, College of Agriculture and Life Science, Kyungpook National University) ;
  • Eom, Tae-Jin (Dept. of Wood Science and Technology, College of Agriculture and Life Science, Kyungpook National University)
  • 이민형 (경북대학교 농업생명과학대학 임산공학과) ;
  • 김강재 (경북대학교 농업생명과학대학 임산공학과) ;
  • 엄태진 (경북대학교 농업생명과학대학 임산공학과)
  • Received : 2012.11.19
  • Accepted : 2012.12.18
  • Published : 2012.12.30

Abstract

Water-in-oil emulsion (W/O) and oil-in-water emulsion (O/W) types biodegradable polymer emulsions prepared to PLA and PBS. The optimal mixing ratio of polymer : solvent : OA : TEA : water was found be 10 : 40 : 4 : 6 : 30(g) when preparing emulsions. Biodegradability was most retained after preparation of polymer emulsions. Particle size of PLA and PBS emulsions were 2-3 ${\mu}m$ and 3-4 ${\mu}m$, respectively. Molecular weight of PLA and PBS emulsions were 108,000 and 92,000, respectively. And molecular weight of PLA and PBS emulsions became slightly lower than those of pellets.

Keywords

References

  1. 국윤환, 이정민, 조순채, 여수동, 콜로이드와 계면활성제, 대광서림, pp. 9-14 (1995).
  2. Park, H. J. and Kim, S. C., The characteristic control of spherical silica particle using by W/O type emulsion( I); The analysis of particle shape and size distribution of silica as a function mixing speed, J. Korean Oil Chemist' Soc. 23(1):1-11 (2006). https://doi.org/10.1007/BF02705684
  3. Choi, M. J., Lee, Y. M. and Jin, B. S., Studies on the formation of liquid crystal and the stability in W/O emulsion systems using beewax and silicone surfactant, J. Korean Oil Chemist' Soc. 21(4):279-288 (2004).
  4. Brooks, B. W. and Richmond, H. N., Dynamics of liquid- liquid phase inversion using nonionic surfactant, Colloids and Surfaces 58:131-148 (1991). https://doi.org/10.1016/0166-6622(91)80203-Z
  5. Park, C. H. and Hong E. Y., Effects of spinning speed and heat treatment on the mechanical property and biodegradability of polylactic acid fibers, J. Korean Society of Clothing and Textiles 30(4):607-614 (2006).
  6. Finkenstadt, V. L. and Tisserat, B., Poly(lactic acid) and osage orange wood fiber composites for agricultural mulch films, Industrial Crops and Products 31:316-320 (2010). https://doi.org/10.1016/j.indcrop.2009.11.012
  7. 김성훈, 생분해성 폴리락타이드의 블렌드 연구, 전남대학교 신화학소재공학과 석사학위논문, pp. 1-15 (2010).
  8. 윤승택, PBS/PVC 및 PBS/PVAc의 블렌드에 관한 연구, 인하대학교 고분자공학과 석사학위논문, pp. 1-9 (2003).
  9. Ray, S. S., Okamoto, K. and Okamoto, M., Structure property relationship in biodegradable poly(butylene succinate)/layered silicate nanocomposites, Macromolecules 36:2355-2367 (2003). https://doi.org/10.1021/ma021728y
  10. Liu, R., Ma, G. H., Wan, Y. H. and Su, Z. G., Influence of process parameters on the size distribution of PLA microcapsules prepared by combining membrane emulsification technique and double emulsion-solvent evaporation method, Colloids and Surfaces B: Biointerfaces 45(3-4): 144-153 (2005). https://doi.org/10.1016/j.colsurfb.2005.08.004
  11. Zambaux, M. F., Bonneaux, F., Gref, R., Maincent, P., Dellacherie, E., Alonso, M. J., Labrude, P. and Vigneron, C., Influence of experimental parameters on the characteristics of poly(lactic acid) nanoparticles prepared by a double emulsion method, Journal of Controlled Release 50:31-40 (1998). https://doi.org/10.1016/S0168-3659(97)00106-5
  12. Uchida, T., Nagareya, N., Sakakibara, S., Konishi, Y., Nakai, A., Nishikata, M., Matsuyama, K. and Yoshida, K., Preparation and characterization of polylactic acid microspheres containing bovine insulin by a W/O/W emulsion solvent evaporation method, Chemical & Pharmaceutical Bulletin 45(9):1539-1543 (1997). https://doi.org/10.1248/cpb.45.1539
  13. Kim, K. J., Park, S. B., Eom and T. J., Properties of current fruiting bag and preparation water repelling fruiting bag with wax emulsion, Journal of Korea TAPPI 40(2):23-28 (2008).
  14. Kim, Y. C., Jun, H. S., Chang, H. N. and Woo, S. I., Optimal conditions for enzymatic degradation of polycaprolactone, Hwahak Konghak 30(6):718-724 (1992).
  15. Cho, K. S., Choi, H. S., Ryu, H. W., Cho, K. H. and Park, S. Y., Characteristics of biodegradable plastics production by fermentation strategies with Alcaligenes latus, J. Korea Society of Environmental Biology 16:47-66 (1998).

Cited by

  1. 생분해성 고분자를 이용한 발수 에멀션의 제조(II) - PLA 및 PBS 에멀션 코팅 과일봉지의 물성 비교 - vol.45, pp.2, 2012, https://doi.org/10.7584/ktappi.2013.45.2.013
  2. 용매증발법을 이용한 Poly-L-Lactic Acid (PLLA) 마이크로스피어 제조 vol.56, pp.4, 2018, https://doi.org/10.9713/kcer.2018.56.4.461