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Development of Edible Laminate-Composite Films Using Defatted Mustard Meal and Whey Protein Isolate

탈지겨자씨와 유청단백질을 재료로 사용한 가식성 적층필름의 개발

  • Kim, Dayeon (Department of Food Science and Technology, Seoul Women's University) ;
  • Park, Ji Won (Department of Food Science and Technology, Seoul Women's University) ;
  • Noh, Bong-Soo (Department of Food Science and Technology, Seoul Women's University) ;
  • Min, Sea Cheol (Department of Food Science and Technology, Seoul Women's University)
  • 김다연 (서울여자대학교 식품공학과) ;
  • 박지원 (서울여자대학교 식품공학과) ;
  • 노봉수 (서울여자대학교 식품공학과) ;
  • 민세철 (서울여자대학교 식품공학과)
  • Received : 2012.08.06
  • Accepted : 2012.09.02
  • Published : 2012.12.31

Abstract

A laminate-composite film was developed using industry co-products of defatted mustard meal (DMM) and whey protein isolate (WPI). An individually prepared DMM-based film (DMM film) and a WPI-based film (WPI film) were thermally laminated at $130^{\circ}C$ at a rate of 30 cm/min. Microscopic images exhibited that the DMM film and the WPI film were continuously attached in the laminate without void spaces. The tensile strength, elongation at break, and water vapor permeability for the laminate were 0.7MPa, 4.0%, and $6.9g{\cdot}mm/kPa/h/m^2$, respectively. Stretchability and heat seal strength of the laminate were higher than those of the un-laminated DMM film. The film layers of the laminate were physically overlapped, not forming new biopolymer units induced by molecular interactions. The opportunity for DMM films to be used as food packaging materials for wrapping and sealing could be increased by thermal lamination with WPI films, which improves the stretchability and heat sealability of DMM films.

생고분자를 이용한 포장 소재에 관한 연구는 많이 이루어지고 있으나 그 것의 상업적 식품 적용은 순수 생고분자의 비용과 생고분자 소재의 불충분한 물리적 성질에 의해 많은 제한을 받고 있다. 본 연구에서는 식품 가공 부산물인 DMM과 WPI를 이용하여 가식성 적층필름을 개발하였다. WPI 필름과의 적층을 통해 DMM 필름의 신장성과 열접합강도를 높일 수 있었고, 이로써 적층기술이 DMM 필름의 식품 포장에서의 적용 가능성을 높이는 방법으로 제시될 수 있었다. DMM 외 다른 식품 가공 부산물을 기초로 한 생고분자 필름들 개발에 있어서도 그들의 식품 적용성 향상의 방법으로 적층방법을 제안할 수 있으리라 사료된다.

Keywords

References

  1. Kester JJ, Fennema OR. Edible films and coatings: A review. Food Technol. 12: 47-59 (1986)
  2. Krochta JM. Mulder-Johnston CD. Edile and biodegradable polymer films. Food Technol. 51: 61-74 (1997)
  3. Choi SJ, Kim SY, Oh DK, Noh BS. Physical properties of locust bean gum-based edible film. Korean J. Food Sci. Technol. 30: 363-371 (1998)
  4. Han TJ, Kim SS. Physical properties of mixed k/${\lambda}$ and k/${\iota}$-carrageenan films. Korean J. Food Sci. Technol. 40: 42-46 (2008)
  5. Han YH, Kim SS. Physical properties of methyl cellulose and hydroxyprophlated methyl cellulose films. Korean J. Food Sci. Technol. 39: 521-526 (2007)
  6. Han YJ, Roh HJ, Kim SS. Preparation and physical properties of curdlan composite edible films. Korean J. Food Sci. Technol. 39: 158-163 (2007)
  7. Min SC, Janjarasskul T, Krochta JM. Tensile and moisture barrier properties of whey protein-beeswax layered composite films. J. Sci. Food Agr. 89: 251-257 (2009) https://doi.org/10.1002/jsfa.3434
  8. Peterson M, Stading M. Water vapour permeability and mechanical properties of mixed starch-monoglyceride films and effect of film forming conditions. Food Hydrocolloids 19: 123-132 (2005) https://doi.org/10.1016/j.foodhyd.2004.04.021
  9. Shellhammer TH, Krochta JM. Whey protein emulsion film performance as affected by lipid type and amount. J. Food Sci. 62: 390-394 (1997) https://doi.org/10.1111/j.1365-2621.1997.tb04008.x
  10. Sablani SS, Dasse F, Bastarrachea L, Dhawan S, Hendrix KM, Min SC. Apple peel-based edible film development using a highpressure homogenization. J. Food Sci. 74: 372-381 (2009)
  11. Ahmadi E, Sareminezhad S, Azizi MH. The effect of ultrasound treatment on some properties of methylcellulose films. Food Hydrocolloids 25: 1399-1401 (2010)
  12. Banerjee R, Chen H, Wu J. Milk protein-based edible film mechanical strength changes due to ultrasound process. J. Food Sci. 61: 824-828 (1996) https://doi.org/10.1111/j.1365-2621.1996.tb12211.x
  13. Cheng W, Chen J, Liu D, Ye X, Ke F. Impact of ultrasonic treatment on properties of starch film-forming dispersion and the resulting films. Carbohyd. Polym. 81: 707-711 (2010) https://doi.org/10.1016/j.carbpol.2010.03.043
  14. Kang HJ, Min SC. Potato peel-based biopolymer film development using high-pressure homogenization, irradiation, and ultrasound. Food Sci. Technol. 43: 903-909 (2010)
  15. Gennadios A, Weller CL, Testin RF. Property modification of wheat, gluten-based films. Trans. ASAE 36: 465-470 (1993) https://doi.org/10.13031/2013.28360
  16. Rhim JW. Modification of soy protein film by formaldehyde. Korean J. Food Sci. Technol. 30: 372-378 (1998)
  17. Chick J, Ustunol Z. Mechanical and barrier properties of lactic acid and rennet precipitated casein-based edible films. J. Food Sci. 63: 1024-1027 (1998)
  18. Abdorreza MN, Cheng LH, Karim AA. Effects of plasticizers on thermal properties and heat sealability of sago starch films. Food Hydrocolloids 25: 56-60 (2011) https://doi.org/10.1016/j.foodhyd.2010.05.005
  19. Hendrix KM, Morra MJ, Lee HB, Min SC. Defatted mustard seed meal-based biopolymer film development. Food Hydrocolloids 26: 118-125 (2012) https://doi.org/10.1016/j.foodhyd.2011.04.013
  20. Kim IH, Yang HJ, Noh BS, Chung SJ, Min SC. Development of a defatted mustard meal-based composite lm and its application to smoked salmon to retard lipid oxidation. Food Chem. 133: 1501-1509 (2012) https://doi.org/10.1016/j.foodchem.2012.02.040
  21. Lee H, Paek HJ, Min SC. Defatted soybean meal-based edible film development. Food Eng. Prog. 15: 305-310 (2011)
  22. McHugh TH, Krochta JM. Sorbitol- vs. glycerol-plasticized whey protein edible films: Integrated oxygen permeability and tensile property evaluation. J. Agr. Food Chem. 42: 841-845 (1994) https://doi.org/10.1021/jf00040a001
  23. McHugh TH, Krochta JM. Water vapor permeability properties of edible whey protein-lipid emulsion films. J. Am. Oil Chem. Soc. 71: 307-312 (1994) https://doi.org/10.1007/BF02638058
  24. ASTM. Standard test method for tensile properties of thin plastic sheeting. D822-01. American Society for Testing and Matereals, Philadelphia, PA, USA (1997)
  25. McHugh TH, Avena-Bustillos R, Krochta JM. Hydrophilic edible films: Modified procedure for water vapor permeability and explanation of thickness effects. J. Food Sci. 58: 899-903 (1993) https://doi.org/10.1111/j.1365-2621.1993.tb09387.x
  26. ASTM. Standard test method for seal strength of flexible barrier materials. F88. American Society for Testing and Materals, Philadelphia, PA, USA (2005)
  27. Chiou BS, Avena-Bustillos RJ, Shey J, Yee E, Bechtel PJ, Imam SH, Glenn GM, Orts WJ. Rheological and mechanical properties of cross-linked fish gelatins. Polymer 47: 6379-6386 (2006) https://doi.org/10.1016/j.polymer.2006.07.004
  28. Brandenburg AH, Weller CL, Testin RF. Edible films and coatings fromfrom soy protein. J. Food Sci. 58: 1086-1089 (1993) https://doi.org/10.1111/j.1365-2621.1993.tb06120.x
  29. Yang HJ, Noh BS, Kim JH, Min SC. Effects of a carbohydrase mixture, ultrasound, and irradiation treatments on the physical properties of defatted mustard meal-based edible films. Korean J. Food Sci. Technol. 43: 30-38 (2011) https://doi.org/10.9721/KJFST.2011.43.1.030
  30. Overberger, Menges G, Kroschwitz J (eds.). Encyclopedia of Polymer Science and Technology, Vol. 2, Wiley, New York, NY, USA p. 180 (2003)
  31. Barrie JA, Crank J, Park GS (eds.). Diffusion in Polymers. Academic Press, London, UK. pp. 259-308 (1968)
  32. Andrianaivo M, Rakotonirainy, Graciela W. Effects of lamination and coating with drying oils on tensile and barrier properties of zein films. J. Agr. Food Chem. 49: 2860-2863 (2001) https://doi.org/10.1021/jf000845u
  33. Lee HB, Yang HJ, Ahn JB, Lee YS, Min SC. Zizyphus jujubebased edible film development by the depolymerization processes. Korean J. Food Sci. Technol. 43: 321-328 (2011) https://doi.org/10.9721/KJFST.2011.43.3.321
  34. Rhim JW, Mohanty Ka, Singh SP, Ng PKW. Preparation and properties of biodegradable multilayer films based on soy protein isolate and poly(lactide). Ind. Eng. Chem. Res. 45: 3059-3066 (2006) https://doi.org/10.1021/ie051207+