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Adhesion Reliability Enhancement of Silicon/Epoxy/Polyimide Interfaces for Flexible Electronics

  • Kim, Sanwi (Department of Mechanical Engineering, KAIST) ;
  • Kim, Taek-Soo (Department of Mechanical Engineering, KAIST)
  • Received : 2012.09.04
  • Accepted : 2012.09.28
  • Published : 2012.09.30

Abstract

Adhesion and mechanical reliability of silicon/epoxy/polyimide interfaces are critical issues for flexible electronics. Bonds between these interfaces are mainly hydrogen bonds, so their adhesion is weaker than cohesive fracture toughness and vulnerable to moisture. In order to enhance adhesion and suppress moisture-assisted debonding, UV/Ozone treatment and innovative sol-gel derived hybrid layers were applied to silicon/epoxy/polyimide interfaces. The fracture energy and subcritical crack growth rate were measured by using a double cantilever beam (DCB) fracture mechanics test. Results showed that UV/Ozone treatment increased the adhesion, but was not effective for improving reliability against humidity. However, by applying sol-gel derived hybrid layers, adhesion increase as well as suppresion of moisture-assisted cracking were achieved.

Keywords

References

  1. D. Hung, F. Liao, S. Molesa, D. Redinger and V. Subramanian, "Plastic-Compatible Low Resistance Printable Gold Nanoparticle Conductors for Flexible Electronics", Journal of The Electrochemical Society, 150(7) G412-G417 (2003). https://doi.org/10.1149/1.1582466
  2. S. Ju, A. Facchetti, Y. Xuan, J. Liu, F. Ishikawa, P. Ye, C. Zhou, T. J. Marks and D. B. Janes, "Fabrication of fully transparent nanowire transistors for transparent and flexible electronics", Nature nanotechnology, 2, 378 (2007). https://doi.org/10.1038/nnano.2007.151
  3. Y. Sun and J. A. Rogers, "Inorganiic Semiconductors for Flexible Electronics", Advanced Materials, 19, 1897 (2007). https://doi.org/10.1002/adma.200602223
  4. K. Yano, A. Usuki, A. Okada, T. Kurauchi and O. Kamigaito, "Synthesis and properties of polyimide-clay hybrid", Journal of Polymer Science Part A: Polymer Chemistry, 31, 2493 (1993). https://doi.org/10.1002/pola.1993.080311009
  5. S. Luo, J. Leisen and C. P. Wong, "Study of mobility of water and polymer chain in epoxy and its influence on adhesion", Journal of applied polymer science, 85, 1 (2002). https://doi.org/10.1002/app.10473
  6. C. E. Park, B. J. Han and H. E. Bair, "Humidity effects on adhesion strength between solder ball and epoxy underfills", Polymer, 38, 3811 (1997). https://doi.org/10.1016/S0032-3861(96)00972-X
  7. M. Shirangi and B. Michel, "Mechanism of Moisture Diffusion, Hygroscopic Swelling, and Adhesion Degradation in Epoxy Molding Compounds", Moisture Sensitivity of Plaastic Packages of IC Devices, 29-69 (2010).
  8. D. C. Hu and H. C. Chen, "Humidity effect on polyimide film adhesion", Journal of materials science, 27, 5262 (1992). https://doi.org/10.1007/BF02403827
  9. S. Luo and C. P. Wong, "Influence of temperature and humidity on adhesion of underfills for flip chip packaging", Components and Packaging Technologies, IEEE Transactions on 28, 88 (2005). https://doi.org/10.1109/TCAPT.2004.838872
  10. S. Y. Kim, S. S. Jo, J. S. Kang and Y. H. Kim, "Adhesion Enhancement of Thin Film Metals on Polyimide Substrates by Bias Sputtering", J. Microelectron. Packag. Soc., 12(3), 207 (2005).
  11. S. Y. Kim, Y. H. Kim and J. S. Yoon, "광반응 폴리이미드위에 RF bias sputtering 방식으로 증착된 Cr의 접착력에 관한 연구", Proc. International Microelectronics and Packaging Society Conference, Seoul, 171, The Korean Microelectronics and Packaging Society (KMEPS) (2001). (in Korean)
  12. N. S. McIntyre, R. D. Davidson, T. L. Walzak, R. Williston, M. Westcott and A. Pekarsky, "Uses of ultraviolet/ozone for hydrocarbon removal: Applications to surfaces of complex composition or geometry", Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, 9, 1355 (1991). https://doi.org/10.1116/1.577626
  13. M. S. Olilver, K. Y. Blohowiak and R. H. Dauskardt, "Molecular structure and fracture properties of ZrO X/Epoxysilane hybrid films", Journal of sol-gel science and technology, 55, 360 (2010). https://doi.org/10.1007/s10971-010-2262-1
  14. M. F. Kannine, "An augmented double cantilever beam model for studying crack propagation and arrest", International Journal of Fracture, 9(1), 83 (1973).
  15. R. J. Hohlfelder, D. A. Maidenberg, R. H. Dauskardt, Y. Wei and W. Hutchinson, "Adhesion of benzocyclobutene-passivated silicon in epoxy layered structures", Journal of Materials Research, 16(1), 243 (2001). https://doi.org/10.1557/JMR.2001.0037
  16. J. R. Vig and J. W. LeBus, "UV/Ozone cleaning of surfaces", Parts, Hybrids, and Packaging, IEEE Transactions on 12, 365 (1976). https://doi.org/10.1109/TPHP.1976.1135156
  17. J. A. Poulis, J. C. Cool and E. H. P. Logtenberg, "UV/Ozone cleaning, a convenient alternative for high quality bonding preparation", International journal of adhesion and adhesives, 13, 89 (1993). https://doi.org/10.1016/0143-7496(93)90019-6
  18. M. L. Sham, J. Li, P. C. Ma and J. K. Kim, "Cleaning and functionalization of polymer surfaces and nanoscale carbon fillers by uv/ozone treatment: A review", Journal of composite materials, 43, 1537 (2009). https://doi.org/10.1177/0021998308337740
  19. D. O. H. Teare, C. Ton-That and R. H. Bradley, "Surface characterization and ageing of ultraviolet-ozone-treated polymers using atomic force microscopy and x-ray photoelectron spectroscopy", Surface and interface analysis, 29, 276 (2000). https://doi.org/10.1002/(SICI)1096-9918(200004)29:4<276::AID-SIA740>3.0.CO;2-P
  20. S. Zhang, Z. Xianting, W. Yongsheng, C. Kui and W. Wenjian, "Adhesion strength of sol-gel derived fluoridated hydroxyapatite coatings", Surface and Coatings Technology, 200, 6350 (2006). https://doi.org/10.1016/j.surfcoat.2005.11.033
  21. J. Liu, M. K. Chaudhury, D. H. Berry, J. E. Seebergh, J. H. Osborne, K. Y. Blohowiak, "Effect of surface morphology on crack growth at a sol-gel reinforced epoxy/aluminum interface", The Journal of Adhesion, 82, 487 (2006). https://doi.org/10.1080/00218460600713725
  22. C. L. Soles and A. F. Yee, "A discussion of the molecular mechanisms of moisture transport in epoxy resins", Journal of Polymer Science Part B: Polymer Physics, 38, 792 (2000). https://doi.org/10.1002/(SICI)1099-0488(20000301)38:5<792::AID-POLB16>3.0.CO;2-H

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