유사 식품인 오징어 젓갈과 한치 젓갈의 판별을 위한 MS-전자코 분석

in Economically Motivated Authentication Food Using Electronic Nose Based on Mass Spectrometer

  • 홍은정 (서울여자대학교 식품공학과) ;
  • 김기화 (서울여자대학교 식품공학과) ;
  • 박수지 (서울여자대학교 식품공학과) ;
  • 강지원 (서울여자대학교 식품공학과) ;
  • 김동술 (식품의약품안전평가원 식품감시과학팀) ;
  • 이화정 (식품의약품안전평가원 식품감시과학팀) ;
  • 김은정 (식품의약품안전평가원 식품감시과학팀) ;
  • 이재황 (식품의약품안전평가원 식품감시과학팀) ;
  • 김승희 (식품의약품안전평가원 식품감시과학팀) ;
  • 이광호 (식품의약품안전평가원 식품감시과학팀) ;
  • 노봉수 (서울여자대학교 식품공학과)
  • Hong, Eun Jeung (Department of Food Science and Technology, Seoul Women's University) ;
  • Kim, Ki Hwa (Department of Food Science and Technology, Seoul Women's University) ;
  • Park, Sue Jee (Department of Food Science and Technology, Seoul Women's University) ;
  • Kang, Jee Won (Department of Food Science and Technology, Seoul Women's University) ;
  • Kim, Dong-Sul (National Institute of Food and Drug Safety Evaluation) ;
  • Lee, Hwa Jung (National Institute of Food and Drug Safety Evaluation) ;
  • Kim, Eun Jeong (National Institute of Food and Drug Safety Evaluation) ;
  • Lee, Jae Hwang (National Institute of Food and Drug Safety Evaluation) ;
  • Kim, Seung-Hee (National Institute of Food and Drug Safety Evaluation) ;
  • Lee, Kwang-Ho (National Institute of Food and Drug Safety Evaluation) ;
  • Noh, Bong Soo (Department of Food Science and Technology, Seoul Women's University)
  • 투고 : 2011.02.15
  • 심사 : 2011.03.11
  • 발행 : 2011.05.30

초록

오징어 젓갈과 한치 젓갈의 차이를 질량분석기를 기반으로 한 전자코를 이용하여 분석한 결과 두 시료의 mass spectrum은 뚜렷한 차이를 보였다. 판별함수분석을 통해 휘발성분의 패턴을 분석한 결과 오징어 젓갈과 한치 젓갈이 뚜렷이 구분되었으며 젓갈의 양념을 제거한 후 분석하였을 때 구분이 더 잘되었다. 결과적으로 전자코를 이용하여 유사 식품 간의 차이를 충분히 구분 가능하였으며 이러한 결과는 추후 젓갈뿐 아니라 다양한 방면에 적용 가능할 것으로 보여 EMA 식품을 선별하는 데에도 도움이 될 것으로 기대된다.

In this study, discrimination of salted cuttle fish and salted mitra squid was carried out using electronic nose based on mass spectrometer. Intensities of each fragment from salted cuttlefish by electronic nose were completely different from those of salted mitra squid. Each sample was analyzed, and discriminant function analysis (DFA) was used for the discrimination of similar products. DFA plot indicated a significant separation of each salted cuttlefish and mitra squid ($r^2$= 0.8789, F= 162.13). Electronic nose based on mass spectrometer could be used as an efficient method for discrimination of Economically Motivated Authentication (EMA) foods.

키워드

참고문헌

  1. Ampuero S, Bogdanov S, Bosset JO. 2004. Classification of unifloral honeys with an MS-based electronic nose using different sampling modes: SHS, SPME and INDEX. European Food Res. Technol. 218(2): 198-207. https://doi.org/10.1007/s00217-003-0834-9
  2. Baeten V, Dardenne P, Aparicio R. 2001. Interpretation of fourier transform raman spectra of unsaponifiable matter in a selection of edible oils. J. Agric. Food Chem. 49(11): 5098-5107. https://doi.org/10.1021/jf010146x
  3. Calvo JH, Zaregoza P, Osta R. 2001. Random amplified polymorphic DNA fingerprints for identification of species in poultry pate. Poultry Sci. 80(4): 522-524.
  4. Calvo JH, Osta R, Zaragoza P. 2002. Quantitative PCR detection of pork in raw and heated ground beef and pate. J. Agric. Food Chem. 50(19): 5265-5267. https://doi.org/10.1021/jf0201576
  5. Casal S. Rui Alves M, Mendes E, Oliveira MBPP, Ferreira MA. 2003. Discrimination between arabica and robusta coffee species on the basis of their amino acid enantiomers. J. Agric. Food Chem. 51(22): 6495-6501. https://doi.org/10.1021/jf034354w
  6. Castillo MLR Del. Caja MM, Blanch GP, Herraiz M. 2003. Enantiomeric distribution of chiral compounds in orange juices according to their geographical origins. J. Food Prot. 66(8): 1448-1454.
  7. Contal L, Leon V, Downey G. 2002. Detection and quantification of apple adulteration in strawberry and raspberry purees using visible and near infrared spectroscopy. J. Near Infrared Spec. 10(4): 289-299.
  8. Downey G, Fouratier V, Kelly JD. 2003. Detection of honey adulteration by addition of fructose and glucose using near infrared transflectance spectroscopy. J. Near Infrared Spec. 11(6): 447-456.
  9. Goodacre R, Radovic BS, Anklam E. 2002. Progress toward the rapid nondestructive assessment of the floral origin of European honey using dispersive raman spectroscopy. Applied Spec. 56(4): 521-527. https://doi.org/10.1366/0003702021954980
  10. James D, Scott SM, O'Hare WT, Ali Z, Rowell FJ. 2004. Classification of fresh edible oils using a coated piezoelectric sensor array-based electronic nose with soft computing approach for pattern recognition. Trans. Institute Measurement Control 26(1): 3-18. https://doi.org/10.1191/0142331204tm0102oa
  11. Ki KS, Kim SB, Lee HJ, Yang SH, Lee JS, Jin ZL. 2009. Prediction on the quality of total mixed ration for dairy cows by near infrared reflectance spectroscopy. J. Korean Grassl. Forage Sci. 29(3): 253-262. https://doi.org/10.5333/KGFS.2009.29.3.253
  12. Kim SK. 2010. Analysis of adulteration of red ginseng, bokbunja and plum extracts by the $^{13}C/^{12}C$ isotopic ratio. Master's thesis, University of Sejong, Seoul, Korea.
  13. Lee YJ, Lee KT. 2007. Identification of volatile compounds of 4 grape species by storage conditions. J. Korean Soc. Food Sci. Nutr. 36(7): 874-880. https://doi.org/10.3746/jkfn.2007.36.7.874
  14. Lopez-Diez EC, Bianchi G, Goodacre R. 2003. Rapid quantitative assessment of the adulteration of virgin olive oils with hazelnut oils using raman spectroscopy and chemometrics. J. Agric. Food Chem. 51(21): 6145-6150. https://doi.org/10.1021/jf034493d
  15. Maraboli A, Cattaneo TMP, Giangiacomo R. 2002. Detection of vegetable proteins from soy, pea and wheat isolates in milk powder by near infrared spectroscopy. J. Near Infrared Spec. 10(1): 63-69. https://doi.org/10.1255/jnirs.322
  16. Noh BS. 2005. Analysis of volatile compounds using electronic nose and its application in food industry. Korean J. Food Sci. Technol. 37(6): 1048-1064.
  17. Official J. 2002. The European communities; Article 8. Regulation (EC) No. 178.
  18. Paradkar MM, Sakhamuri S, Irudayaraj J. 2002. Comparision of FTIR, FT-Raman, and NIR spectroscopy in a maple syrup adulteration study. J. Food Sci. 67(6): 2009-2015. https://doi.org/10.1111/j.1365-2621.2002.tb09493.x
  19. Pillonel L, Ampuero S, Tabacchi R, Bosset J. 2003. Analytical methods for the determination of the geographic origin of emmental cheese: Volatile compounds by GC/MS-FID and electronic nose. European Food Res. Technol. 216(2): 179-183.
  20. Reid LM, O'Donnell CP, Downey G. 2004. Potential of SPME-GC and chemometrics to detect adulteration of soft fruit purees. J. Agric. Food Chem. 52(3): 421-427. https://doi.org/10.1021/jf034962b
  21. Rodriguez-Saona LE, Fry FS, Mclaughlin MA. Calvey EM. 2001. Rapid analysis of sugars in fruit juices by FT-NIR Spectroscopy. Carbohydrate Res. 336(1): 63-74. https://doi.org/10.1016/S0008-6215(01)00244-0
  22. Rui Alves M, Casal S, Oliveira MBPP, Ferreira MA. 2003. Contribution of FA profile obtained by high-resolution GC/ chemometric techniques to the authenticity of green and roasted coffee varieties. J. Amer. Oil Chem. Soc. 80(6): 511-517. https://doi.org/10.1007/s11746-003-0730-0
  23. Ruiz del Castillo ML, Caja MM, Herraiz M. 2003. Use of the enantiomeric composition for the assessment of the authenticity of fruit beverages. J. Agric. Food Chem. 51(5): 1284-1288. https://doi.org/10.1021/jf025711q
  24. Sawyer J, Wood C, Shanahan D, Gout S, McDowell D. 2003. Realtime PCR for quantitative meat species testing. Food Control 14(8): 579-583. https://doi.org/10.1016/S0956-7135(02)00148-2
  25. Son HJ, Kang JH, Hong EJ, Lim CL, Choi JY, Noh BS. 2009a. Authentication of sesame oil with addition of perilla oil using electronic nose based on mass spectrometry. Korean. J. Food Sci. Technol. 41(6): 609-614.
  26. Son HJ, Hong EJ, Ko SH, Choi JY, Noh BS. 2009b. Identification of vegetable oil-added sesame oil by a mass spectrometer-based electronic nose. Food Eng. Progress. 13(4): 275-281.
  27. Steine C, Beaucousin F, Siv C, Peiffer G. 2001. Potential of semiconductor sensor arrays for the origin authentication of pure valencia orange juices. J. Agric. Food Chem. 49(7): 3151-3160. https://doi.org/10.1021/jf0014664
  28. Woon JH, Lim KJ. 2008. Understanding and response of melamin in food. Food Ind. 206: 51-65.
  29. YTN. 2009. Iintestine of Chinese parasilurus asotus taking the form of fermented pollack tripe Available from: http://www.ytn.co.kr/_ln/ 0102_200911221202116478, Nov. 22.