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Temporal and Spatial Variation and Removal Efficiency of Heavy Metals in the Stream Water Affected by Leachate from the Jiknaegol Tailings Impoundment of the Yeonhwa II Mine

제2연화광산 직내골 광미장 침출수에 오염된 하천수계의 시.공간적 수질변화 및 중금속 제거효율

  • Lee, Pyeong-Koo (Department of Geological and Environmental Hazards, Korea Institute of Geoscience and Mineral Resources) ;
  • Kang, Min-Ju (Department of Soil and Ground Water, Korea Environment Corporation) ;
  • Choi, Sang-Hoon (Department of Earth and Environmental Sciences, Chungbuk National University)
  • 이평구 (한국지질자원연구원 지질환경재해연구부) ;
  • 강민주 (한국환경공단 토양지하수처) ;
  • 최상훈 (충북대학교 지구환경과학과)
  • Received : 2010.07.15
  • Accepted : 2010.09.09
  • Published : 2011.02.28

Abstract

This study had been carried out to investigate spatial and temporal variations of the concentrations of trace metals for contaminated surface water in creek affected by leachate from the tailings impoundment of the Yeonhwa II mine for about 2 years. It was also to ascertain the metal removal efficiency for potentially deleterious metals by the artificial and natural attenuation processes such as retention ponds and hydrologic mixing of uncontaminated tributaries. The concentrations of As, Pb, Cd, and Cu for leachate in the rainy season were not detected. On the other hand, the concentrations of Zn, Fe, Mn, Al, and $SO_4^{2-}$ in the rainy season for leachate were 2-66 times higher than those in the dry season, due to the oxidation of the sulfide minerals and the dissolution of the secondary minerals. The concentrations of Zn and Cd for leachate and surface water of the upper creek in the rainy season exceeded the criteria of River Water Quality and Drinking Water Quality but in the dry season, those of analyzed all the metals (As, Pb, Cd, Cu, Zn, Cd, Fe, Mn, and Al) for surface water sampled at the study area were below the criteria of River Water Quality and Drinking Water Quality. In regard of the attenuation efficiency for the concentrations of metals, Fe, Mn, Al, Zn, Cd, As, and Cu were removed highly at retention ponds, while the removal efficiency for major cations and sulfate ($SO_4^{2-}$) were related to mixing of the uncontaminated tributaries. Therefore, the major attenuation processes of the metal and sulfate contents in creek affected by leachate from a tailing dump were precipitation (accompanied by metal co-precipitation and sorption), water dilution, and neutralization.

Keywords

References

  1. 강민주, 이평구, 염승준, 2006, 세창 폐금속광산 수계에서 미량원소의 지구화학적 거동특성 규명, 자원환경지질, 39(3), 213-227.
  2. 강민주, 이평구, 최상훈, 2007, 인대광산 지역 광산배수에 영향을 받은 하천에서 미량원소의 계절적인 수질변화와 자연저감, 자원환경지질, 40(3), 277-293.
  3. 대한광업진흥공사, 1981, 한국의 광상 8호, 184-185.
  4. 한갑수, 1972, 제2연화광산의 지질광상에 대하여, 자원환경지질, 5(4), 211-220.
  5. Berger, A.C., Bethke, C.M., and Krumhansl, J.L., 2000, A process model of natural attenuation in drainage from a historic mining district, Appl. Geochem., 15, 655-666. https://doi.org/10.1016/S0883-2927(99)00074-8
  6. Bowell, R.J. and Bruce, I., 1995, Geochemistry of iron ochres and mine waters from Levant Mine, Cornwall, Appl. Geochim., 10, 237-250. https://doi.org/10.1016/0883-2927(94)00036-6
  7. Buffle, J., Filella, M., Stoll, S., and Zhang, J., 1995, Nature and behavior of colloids in surface waters (abstract), Terra Abstract, 7, 247.
  8. Chapman, B.M., Jones, D.R., and Jung, R.F., 1983, Processes controlling metal ion attenuation in acid mine drainage stream, Geochim. Cosmochim., Acta 47, 1957-1973. https://doi.org/10.1016/0016-7037(83)90213-2
  9. Courtin-Nomade, A., Bril, H., Neel, C., and Lenain, J.F., 2003, Arsenic in iron cements developed within tailings of a former metalliferous mine-Enguiales, Aveyron. France, Appl. Geochem., 18, 395-408. https://doi.org/10.1016/S0883-2927(02)00098-7
  10. Dold, B. and Fontbote, L., 2002, A mineralogical and geochemical study of element mobility in sulfide mine tailings of Fe oxide Cu-Au deposits from the Punta del Cobre belt, northern Chile, Chem. Geol., 189, 135-163. https://doi.org/10.1016/S0009-2541(02)00044-X
  11. Frau, F., 2000, The formation-dissolution-precipitation cycle of melanterite at the abandoned pyrite mine of Genna Luas in Sardinia, Italy: environmental implications, Mineral. Mag., 64, 995-1006. https://doi.org/10.1180/002646100550001
  12. Fukushi, K., Sasaki, M., Sato, T., Yanase, N., Amano, H., and Ikeda, H., 2003, A natural attenuation of arsenic in drainage from an abandoned arsenic mine dump, Appl. Geochem., 18, 1267-1278. https://doi.org/10.1016/S0883-2927(03)00011-8
  13. Hudson-Edwards, K.A., Schell, C., and Macklin, M.G., 1999, Mineralogy and geochemistry of alluvium contaminated by metal minig in the Rio Tionto area, southwest Spain, Appl. Geochim., 14, 1015-1030. https://doi.org/10.1016/S0883-2927(99)00008-6
  14. International Organization for Standardization, 1995, International Standard. Soil quality : Extraction of trace elements soluble in aqua regia, ISO 11466.
  15. Kimball, B.A., Broshears, R.A., McKnight, D.M., and Bencala, K.E., 1994, Effects of instream pH modification on transport of sulfide-oxidation products. In: Alpers, C.N. and Blowes, D.W., Editors, 1994. The Environmental Geochemistry of Sulfide Oxidation, Am. Chem. Soc. Symp. Series, 550, 224-243.
  16. Lee, P.K., Baillif, P., and Touray, J.C., 1997, Geochemical behaviour and relative mobility of metals (Mn, Cd, Zn and Pb) in recent sediments of a retention pond along the A-71 motor-way in Sologne, France, Environ. Geol., 32, 142-152. https://doi.org/10.1007/s002540050203
  17. Lee, P.K., Kang, M.J., Choi, S.H., and Touray, J.C., 2005, Sulfide oxidation and the natural attenuation of arsenic and trace metals in the waste rocks of the abandoned Seobo tungsten mine, Korea, Appl. Geochem., 20, 1687-1703. https://doi.org/10.1016/j.apgeochem.2005.04.017
  18. Mascaro, I., Benvenuti, B., Corsini, F., Costagliola, P., Lattanzi, P., Parrini, P., and Tanelli, G., 2001, Mine wastes at the polymetallic deposit of Fenice Capanne (southern Tuscany, Italy). Mineralogy, geochemistry, and environmental impact, Environ. Geol., 41, 417-429. https://doi.org/10.1007/s002540100408
  19. McGregor, R.G., Blowes, D.W., Jambor, J.L., and Robertson, W.D., 1998, The solid-phase controls on the mobility of heavy metals at the Copper Cliff tailings area, Sudbury, Ontario, Canada, J. Contaminant Hydrol., 33, 247-271. https://doi.org/10.1016/S0169-7722(98)00060-6
  20. Shaw, S.C., Groat, L.A., Jambor, J.L., Blowes, D.W., Hanton-Fong, C.J., and Stuparyk, R.A., 1998, Mineralogical study of base metal tailings with various sulfide contents, oxidized in laboratory columns and field lysimeters, Environ. Geol., 33, 209-217. https://doi.org/10.1007/s002540050239