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토양 중 미규제된 유기오염물질 분석연구 (다환방향족탄화수소 16종을 중심으로)

Research on the Analysis of Unregulated Organic Pollutant Compounds in Soil (Focusing on 16 Polycyclic Aromatic Hydrocarbons)

  • 김종향 (경상남도보건환경연구원) ;
  • 강종민 (경상남도보건환경연구원) ;
  • 이방희 (경상남도보건환경연구원) ;
  • 허종수 (경상남도보건환경연구원)
  • Kim, Jong-Hyang (Institute of Health & Environment Gyeongnam Provincial Government) ;
  • Gang, Jong-Min (Institute of Health & Environment Gyeongnam Provincial Government) ;
  • Lee, Bang-Hee (Institute of Health & Environment Gyeongnam Provincial Government) ;
  • Her, Jong-Sou (Institute of Health & Environment Gyeongnam Provincial Government)
  • 투고 : 2011.02.17
  • 심사 : 2011.03.21
  • 발행 : 2011.03.30

초록

The aim of study was to investigate polluted amounts 16 PAHs in railroad(waste railway ties) area, factory area and land-fill area. All of the samples were analyzed by GC-MSD(SIM mode), and the recovery range, detection limit and standard deviation obtained by this experiment were 73.88 ~ 94.75%, 0.009 ~ 2.252 ${\mu}g$/kg and 1.861 ~ 12.373, respectively. The concentrations of total PAHs(t-PAHs) and total carcinogenic PAHs(t-PAHcarc) in soils of three area were in the range of 12.54 ~ 3274.95 ${\mu}g$/kg on a wet weight basis with a mean value of 499.8 ${\mu}g$/kg and 0 ~122.77 ${\mu}g$/kg with a mean value of 20.16 ${\mu}g$/kg, respectively. The correlation between t-PAHs and t-PAHcarc appeared very high in railroad(waste railway ties) area ($R^2$ = 0.8301), factory area ($R^2$ = 0.9217) except land-fill area($R^2$ = 0.3782), indicated that t-PAHcarc concentration increases in proportion with t-PAHs.

키워드

참고문헌

  1. S. Y. Kim, Y. H. Chung, and G. Ok, Concentraction Levels and Distribution Characteristics of Polycyclic Aromatic Hydrocarbons(PAHs) at Soils in Changwon City, J. Korea Soc. Environ. Anal., 3(3), 171(2000).
  2. C. A. Menzie, B. B. Potocki, and J.Santodonato, Exposure to Carinogenic PAHs in the Environment, Environ. Sci. Technol., 36, 1278(1992).
  3. P. Garrigues, H. H. Soclo, M. P. Marniesse and M. Ewald, Origin of Polycyclic Aromatic Hydrocarbons in Recent Sediments from the Continental Shelf of the Golfe de Gascogne (Atlantic Ocean) and in the Gironde Estuary, Intem. J. Environ. Anal. Chem., 28, 121(1987). https://doi.org/10.1080/03067318708078404
  4. T. L. Potter and K. E. Simmons, Total Petroleum Hydrocarbon Criteria Working Group Series-Composition of Petroleum Mixtures, Vol. 2, U.S.A.(1998).
  5. M. Blumer, Benzoprenes in Soils, Science, 134, 474(1961). https://doi.org/10.1126/science.134.3477.474
  6. Y. S. You. H. S. Cho and Y. C. Choi, A Study on the Pollution of Polycyclic Aromatic Hydrocarbons(PAHs) in the Surface Sediments around Gwangyang Bay, J. Kor. Soci. of Marine Environ., 13(1), 9(2007).
  7. J. M. Park, M. J. Kim, J. P. Kim, S. B. Lee, O. S. Kwon and S. H. Lee, Concentration of Heavy Metals and PAHs in Sewage Sludge, J. Korean Soc. for Environ. Anal., 11(4), 275(2008).
  8. H. H. Chung, H. S. Jeong and S. W. Choi, Distribution Characteristics of Polycyclic Aromatic Hydrocarbons in the sediments of Kwangyang Bay in Korea, J. Kor. Ind. Eng. Chem., 17(2), 210(2006).
  9. J. S. Lim, S. S. Kim, D. S. Park, J. H. Joo, C. K. Lim, and J. H. Hur, Monitering of Polycyclic Aromatic Hydrocarbon Residues in Environmental Samples in Korea, J. of Korea Pesticide Sci., 11(2), 95-105(2007).
  10. C. K. Park, J. S. Yoon, M. Y. Kim, J. Y. Soon and S. Y. Mo, PAHs Source Fingerprints for Municipal Incinerator Motor Vehicle and Industrial Boilers Emission, Kor. Soci. for Atom. Environ., 20(3), 331(2004).
  11. H. Budzinski, I. Jones, J. Bellocq, C. Z. Pierard and P. Garrigues, Evalution of Sediment Contamination by Polycyclic Aromatic Hydrocarbons in the Gironde Estuary. Mar. Chem., 58, 89(1997).
  12. Minister of Environment, Standard of Soil Pollutants, p. 157-172 (2009, 10).
  13. IARC, IRAC Monograps on the Evalution of Carcinogenic Risks to Humans, Diesel and Gasoline Engine Exhausts and Some Nitroarenes, Monographs, 46, 41(1989).
  14. Y. K. Jin, M. G. Lee and S. K. Kam, Distribution Characteristics of Polycyclic Aromatic Hydrocarbons(PAHs) in Soil in Jeju City of Jeju Island, Korean, J. Environ. Sci., 15(5), 405(2006).
  15. D. H. Kim and G. Ok, Survey on Concentration Characteristics of Polycyclic Aromatic Hydrocarbons in Soil in Seoul, J. Environ. Sci., 14(1), 81(2005).