Bulletin of the Korean Chemical Society

  • 제32권10호
  • /
  • Pages.3692-3695
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  • 2011
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Poly(N,N'-Dichloro-N-ethyl-benzene-1,3-disulfonamide) and N,N,N',N'-Tetrachlorobenzene-1,3-disulfonamide as Efficient Reagents to Direct Oxidative Conversion of Thiols and Disulfide to Sulfonyl Chlorides

  • Veisi, Hojat (Chemistry Department, Payame Noor University) ;
  • Ghorbani-Vaghei, Ramin (Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University) ;
  • Mahmoodi, Jafar (Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University)
  • 투고 : 2011.07.06
  • 심사 : 2011.08.19
  • 발행 : 2011.10.20
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초록

Poly(N,N'-Dichloro-N-ethyl-benzene-1,3-disulfonamide) (PCBS) and N,N,N',N'-Tetrachlorobenzene-1,3-disulfonamide (TCBDA) were found to be a mild and efficient reagent for the direct oxidative conversion of sulfur compounds to the corresponding arenesulfonyl chlorides in good to excellent yields through the oxidative chlorination. The overall process is simple, practical, and it provides convenient access to a variety of aryl or heteroarylsulfonyl chlorides. The mild reaction conditions and the broad substrate scope render this method attractive, and complementary to existing syntheses of aryl or heteroarylsulfonyl chlorides.

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참고문헌

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피인용 문헌

  1. ChemInform Abstract: Poly(N,N′-dichloro-N-ethyl-benzene-1,3-disulfonamide) and N,N,N′,N′-Tetrachlorobenzene-1,3-disulfonamide as Efficient Reagents to Direct Oxidative Conversion of Thiols and Disulfide to Sulfonyl Chlorides. vol.43, pp.10, 2012, https://doi.org/10.1002/chin.201210072
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  6. ]pyrazole] derivatives vol.54, pp.1, 2016, https://doi.org/10.1002/jhet.2605
  7. Conversion of thiols into sulfonyl halogenides under aerobic and metal-free conditions vol.19, pp.9, 2017, https://doi.org/10.1039/C7GC00556C