Bulletin of the Korean Chemical Society

  • 제32권10호
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  • Pages.3624-3628
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  • 2011
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Facile Synthesis of Aldehyde-focal Fréchet Type Dendrons and Dendrimers via Staudinger/Aza-Wittig Reactions

  • Han, Seung-Choul (Department of Chemistry and Department of Medical Bioscience, Dong-A University) ;
  • Jin, Sung-Ho (Department of Chemistry Education, Pusan National University) ;
  • Lee, Jae-Wook (Department of Chemistry and Department of Medical Bioscience, Dong-A University)
  • 투고 : 2011.08.01
  • 심사 : 2011.08.08
  • 발행 : 2011.10.20
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초록

Fr$\acute{e}$chet-type dendritic benzaldehydes were efficiently synthesized using 3,5-dihydroxybenzaldehyde as an aldehyde focal point functionalized unit by adding a generation to the existing dendron or direct oxidation of Fr$\acute{e}$chet-type dendritic benzyl alcohols. These dendritic benzaldehydes were applied for the construction of dendrimers containing secondary amines as connectors via Staudinger/aza-Wittig Reactions with ${\alpha}$,${\alpha}'$,-diazidop-xylene core.

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피인용 문헌

  1. Synthesis of dendrimers via Staudinger/aza-Wittig reaction of Fréchet-type dendritic benzyl azides and Fréchet-type dendritic benzaldehydes vol.20, pp.10, 2012, https://doi.org/10.1007/s13233-012-0149-4
  2. Synthesis of Fréchet-type Dendrimers with Tripodal Core via Staudinger/Aza-Wittig Reactions vol.38, pp.3, 2014, https://doi.org/10.7317/pk.2014.38.3.386
  3. Dendritic [2]Rotaxanes: Synthesis, Characterization, and Properties vol.79, pp.2, 2014, https://doi.org/10.1021/jo402428y