Bulletin of the Korean Chemical Society

대한화학회 (Korean Chemical Society)
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Facile Formation of Unexpected [m,6,n]-tricyclic Spiranes via Intramolecular [3+2] Cyclization of Platinum-bound Pyrylium with Alkenes

  • Oh, Chang-Ho (Department of Chemistry, Institute of Natural Science, Hanyang University) ;
  • Tak, Sang-Yong (Department of Chemistry, Institute of Natural Science, Hanyang University) ;
  • Lee, Ji-Ho (Department of Chemistry, Institute of Natural Science, Hanyang University) ;
  • Piao, Lanhua (Department of Chemistry, Institute of Natural Science, Hanyang University)
  • 투고 : 2011.03.13
  • 심사 : 2011.04.01
  • 발행 : 2011.08.20
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초록

Enynals bearing an olefinic pendant were successfully cyclized via Huisgen-type [3+2] cycloaddition to the tetracyclic Pt-carbene complexes which would undergo insertion into a C-H bond of the ${\beta}$-position to afford the fused cyclopropane intermediates. Their tandem rearrangement afforded diverse types of spiranes depending on the tethered alkenes of the enynals.

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참고문헌

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