Bulletin of the Korean Chemical Society

대한화학회 (Korean Chemical Society)
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Palladium-Catalyzed Cross-Coupling Reaction and Gold-Catalyzed Cyclization for Preparation of Ethyl 2-Aryl 2,3-Alkadienoates and α-Aryl γ-Butenolides

  • Mo, Jun-Tae (Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University) ;
  • Hwang, Hoon (Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University) ;
  • Lee, Phil-Ho (Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University)
  • 투고 : 2010.12.14
  • 심사 : 2011.01.08
  • 발행 : 2011.08.20
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초록

Efficient synthetic method for the preparation of ethyl 2-aryl-2,3-alkadienoates through Pd-catalyzed selective allenyl cross-coupling reactions of aryl iodides with organoindiums generated in situ from indium and ethyl 4-bromo-2-alkynoate was developed. The cyclization reaction of ethyl 2-aryl-2,3-alkadienoates catalyzed by $AuCl_3$ and AgOTf in the presence of AcOH or TfOH produced various ${\alpha}$-aryl ${\gamma}$-butenolides or ${\gamma}$-substituted ${\alpha}$-aryl ${\gamma}$-butenolides.

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참고문헌

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