Bulletin of the Korean Chemical Society

  • 제32권9호
  • /
  • Pages.3448-3452
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  • 2011
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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A Rapid and Practical Protocol for Solvent-Free Reduction of Oximes to Amines with NaBH4/ZrCl4/Al2O3 System

  • Zeynizadeh, Behzad (Department of Chemistry, Faculty of Science, Urmia University) ;
  • Kouhkan, Mehri (Department of Chemistry, Faculty of Science, Urmia University)
  • 투고 : 2011.06.13
  • 심사 : 2011.08.01
  • 발행 : 2011.09.20
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초록

Solvent-free reduction of various aldoximes and ketoximes to the corresponding amines was performed easily and efficiently with $NaBH_4$ in the presence of $ZrCl_4$ supported on $Al_2O_3$. The reactions were carried out rapidly (within 2 min) at room temperature to afford the amines in high to excellent yields.

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피인용 문헌

  1. System. vol.43, pp.9, 2012, https://doi.org/10.1002/chin.201209037
  2. The efficient solvent-free reduction of oximes to amines with NaBH3CN catalyzed by ZrCl4/nano Fe3O4 system vol.12, pp.5, 2015, https://doi.org/10.1007/s13738-014-0550-3
  3. Rapid and green reduction of aromatic/aliphatic nitro compounds to amines with NaBH4 and additive Ni2B in H2O vol.12, pp.7, 2015, https://doi.org/10.1007/s13738-014-0585-5
  4. A review on green Lewis acids: zirconium(IV) oxydichloride octahydrate (ZrOCl2·8H2O) and zirconium(IV) tetrachloride (ZrCl4) in organic chemistry vol.42, pp.5, 2016, https://doi.org/10.1007/s11164-015-2260-6
  5. Magnetic Fe3O4 nanoparticles as recovery catalyst for preparation of oximes under solvent-free condition vol.3, pp.1, 2013, https://doi.org/10.1186/2193-8865-3-57
  6. An improved and practical synthesis of Fmoc Rink linker vol.43, pp.3, 2011, https://doi.org/10.1177/1747519819836490
  7. Heterogeneous palladium-based catalyst promoted reduction of oximes to amines: using H2 at 1 atm in H2O under mild conditions vol.4, pp.6, 2011, https://doi.org/10.1039/c9re00003h