Study of Surfactant Sensitized Fluorescence of Europium-Salicylic Acid Complex for the Determination of Salicylic Acid

Salicylic Acid 정량을 위한 Europium-Salicylic Acid 복합체의 계면활성제 증감 형광법에 관한 연구

  • Alam, MD R-Mahmnur (Department of Chemistry, Kyungpook National University) ;
  • Kamruzzaman, Mohammad (Department of Chemistry, Kyungpook National University) ;
  • Kim, So Yeon (Department of Chemistry, Kyungpook National University) ;
  • Jo, Hae Jin (Department of Chemistry, Kyungpook National University) ;
  • Lee, Sang Hak (Department of Chemistry, Kyungpook National University) ;
  • Kim, Young Ho (Research Institute of Advanced Energy Technology, Kyungpook National University) ;
  • Suh, Jung Kee (Health Metrology Group, Korea Research Institute of Standards and Science)
  • ;
  • ;
  • 김소연 (경북대학교 화학과) ;
  • 조해진 (경북대학교 화학과) ;
  • 이상학 (경북대학교 화학과) ;
  • 김영호 (경북대학교 차세대에너지기술연구소) ;
  • 서정기 (한국표준과학연구원 삶의질측정표준본부)
  • Published : 2011.03.31

Abstract

Surfactant enhanced fluorescence (FL) of europium-salicylic acid (SA) complex has been studied. It was observed that weak FL of Eu(III) at the wavelength of 589 nm and 612 nm was found to be enhanced after addition of salicylic acid and cetyltrimethylammonium bromide (CTAB) surfactant upon excitation at 395 nm. Under optimized condition, FL intensity of Eu(III) at 612 nm responded linearly with the concentration of SA in the range of 5.5×10-9 to 1.5×10-6 M of SA. The detection limit was calculated from the calibration curve(3Sb/m) as 9.27×10-9 M.

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Acknowledgement

This Research was supported by Kyungpook National University Research Fund, 2009.