한국대기환경학회지 (Journal of Korean Society for Atmospheric Environment)

  • 제27권4호
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  • Pages.379-386
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  • 2011
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  • 1598-7132(pISSN)
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  • 2383-5346(eISSN)
한국대기환경학회 (Korean Society for Atmospheric Environment)
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촉매-플라즈마 반응 시스템을 이용한 황화수소의 처리특성 연구

Characteristics of Hydrogen Sulfide Removal by a Catalyst-assisted Plasma System

  • 투고 : 2011.06.09
  • 심사 : 2011.07.28
  • 발행 : 2011.08.31
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초록

Catalyst-assisted plasma system with a DBD (Dielectric Barrier Discharge) reactor was used to remove hydrogen sulfide, which is one of the odorous species in this study. The ${\gamma}-Al_2O_3$ and ${\beta}$-Zeolite catalysts impregnated by Ag, Cu and Mn species were employed as catalysts and their $H_2S$ removal characteristics under plasma irradiation were investigated. From the experimental study, we found that the $H_2S$ removal efficiency increases with decreasing space velocity in the system and increasing specific input energy. Furthermore, ${\beta}$-Zeolite catalysts are efficient to remove $H_2S$ than ${\gamma}-Al_2O_3$ catalysts. Especially, the catalysts impregnated by Ag have higher removal efficiency than other catalysts (Cu, Mn).

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참고문헌

  1. Cheon, T.J., S.W. Choi, and C.S. Lee (2005) Decomposition of toluene over transition metal oxide catalysts, Journal of Korean Society of Environmental Engineers, 27(6), 651-656. (in Korean with English abstract)
  2. Cho, E.S. and Y.-S. Park (2009) Adsorption characteristics of $H_2S$ on adsorbent made by sewage sludge, Odor Research and Engineering, 8(2), 78-84. (in Korean with English abstract)
  3. Holzer, F., U. Roland, and F.-D. Kopinke (2002) Combination of non-thermal plasma and heterogenous catalysis for oxidation of volatile organic compounds: 1, Applied Catalysis B: Environmental, 38(3), 163-181. https://doi.org/10.1016/S0926-3373(02)00040-1
  4. Hwang, H.J., H.-Y. Ann, S.-K. Shin, and J.-H. Song (2010) Application of non-thermal plasma for the simultaneous removal of odor and sludge, Journal of Korean Society of Water and Wastewater, 24(1), 85-92. (in Korean with English abstract)
  5. Francke, K.P., H. Miessnerm, and R. Rudolph (2000) Cleaning of air streams from organic pollutants by plasmacatalytic oxidation, Plasma Chem. Plasma Process, 20(3), 393-403. https://doi.org/10.1023/A:1007048428975
  6. Jang, H.T., Y.K. Park, Y.S. Ko, and W.S. Cha (2008) Selective catalytic oxidation of ammonia in the presence of manganese catalysts, Korean Chem. Eng. Res., 46(3), 498-505. (in Korean with English abstract)
  7. Jeon, E.C., J.H. Sa, S.T. Kim, J.H. Hong, and K.H. Kim (2006) Odorous emissions from household-related sources: a case study on a sewage treatment plant, Journal of Korean Society Atmospheric Environment, 22(3), 337-351. (in Korean with English abstract)
  8. Jung, S.H., B.R. Kim, G.H. Kum, Y.G. Seo, and J.H. Ahn (2001) A study on the ion-exchange characteristics of zeolites (4A, 13X), Journal of institute of Environmental Protection, 9, 29-38. (in Korean with English abstract)
  9. Kim, B.S. and Y.-S. Park (2007) VOCs oxidation characteristics of transition $metals/{\gamma}-Al_2O_3$ catalyst, Journal of Korean Society of Environmental Engineers, 29(4), 444-451. (in Korean with English abstract)
  10. Kim, H.-H., A. Ogata, and S. Fuatamura (2006) Nonthermal plasma-driven catalysis of benzene and toluene, Journal of Korean Society Atmospheric Environment, 22(1), 43-51. (in Korean with English abstract)
  11. Kim, H.H., J.H. Kim, and A. Ogata (2009) Interaction of nonthermal plasma with catalyst and its application to VOC decomposition, Proceeding of the 49th Meeting of KOSAE, Korean Soc. Atmos. Environ., 587-588.
  12. Kim, S.T. (2000) A study on installation of treatment equipment of malodorous substances using the $O_3$, Korean J. Sanitation, 15(3), 70-74. (in Korean with English abstract)
  13. Lee, J.H. and S.H. Kang (2007) The foul smelling from sewer pipe near large apartment complexes and its countermeasures 1: characteristics of the foul-smelling sewer pipe in residential areas, Journal of Korean Society of Water and Wastewater, 21(5), 621-629. (in Korean with English abstract)
  14. Lee, J.S. (2001) Removal technology of odors gases by surface discharge induced plasma, Journal of Korean Society of Environmental Administration, 7(1), 69-75. (in Korean with English abstract)
  15. Lee, S.B., Y.S. Yoon, I.K. Hong, and J.D. Lee (2001) Kinetics prediction of binary aromatic solvent mixtures in catalytic oxidation process, Korea J. Sanit., 16(1), 66-71. (in Korean with English abstract)
  16. Masuda, S., S. Hosokawa, X. Tu., M. Tsutsumi., T. Ohtani, T. Tsukahara, and N. Natsuda (1993) The performance of an integrated air purifier for control of aerosol microbial and odor, IEEE Trans. Lnd Appl., 29(4), 774-780. https://doi.org/10.1109/28.231993
  17. Mok, Y.S., H.-C. Kang, H.-W Lee, and I.-S. Nam. (2003) Effect of plasma discharge on selective catalytic reduction of nitrogen oxides, Korean Chemical Engineering Research, 41(2), 256-263. (in Korean with English abstract)
  18. Moon, S.I. (2003) A study on plasma/catalytic synergy effect for VOCs removal, J. of KSEE, 25(7), 810-815. (in Korean with English abstract)
  19. Ogata A., D. Ito, K. Mizuno, S. Jushiyama, and T. Yamamoto (2001) Removal of dilute benzene using a zeolitehybrid plasma reactor, IEEE Tran. Indust. Appl. 37(4), 959-964. https://doi.org/10.1109/28.936384
  20. Park, J.O., K.-C. Dhoi, H.-H. Kim, A. Ogata, and S. Futamura (2005) Removal of styrene sing different types of non-thermal plasma reactors, Journal of Korean Society of Environmental Engineers, 27(2), 215-223. (in Korean with English abstract)
  21. Park, Y.-G., S.-H. Kim, and J.-C. Ko (2003) Effects of alumina- biofilter for treatment of foul odor, J. Korean Ind. Eng. Chem., 14(1), 109-112. (in Korean with English abstract)
  22. Penetrante, B.M., M.C. Hsiao, B.T. Merritt, G.E. Vogtlin, P.H. Wallman, M. Neiger, O. Wolf, T. Hammer, and S. Broer (1996) Pulsed corona and dielectric-barrier discharge processing of NO in $N_2$, Applied Physics Letters, 68(26), 3719-3721.
  23. Song, B.J., J.-E. Jeong, S.-Y. Jeong, and J.-G. Won (2004) A study of odorous compounds in the food waste Treatment Processing, J. Korean Society of Waste Management, 21(2), 107-116. (in Korean with English abstract)
  24. Stobbe, E.R., B.A. de Boer, and J.W. Geus (1999) The reduction and oxidation behaviour of manganese oxides, Catalysis Today, 47(1-4), 161-167. https://doi.org/10.1016/S0920-5861(98)00296-X
  25. Yamamoto, T. (1997) VOC decomposition by nonthermal plasma processing-a new approach, Journal of Electrostatics, 42(1-2), 227-238. https://doi.org/10.1016/S0304-3886(97)00144-7

피인용 문헌

  1. Application of DBD Plasma Catalysis Hybrid Process to remove Organic Acids in Odors vol.23, pp.9, 2014, https://doi.org/10.5322/JESI.2014.23.9.1627
  2. Catalytic conversion of 2,5-dichlorotoluene over Hβ zeolite, Ag/Hβ and Cu/Hβ catalysts in N2 or H2 atmosphere vol.122, pp.1, 2017, https://doi.org/10.1007/s11144-017-1209-8