Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Solvent Extraction, Preconcentration and Determination of Thorium with Monoaza 18-Crown-6 Derivative

  • Dolak, I. (Department of Chemistry, Faculty of Science, University of Dicle) ;
  • Karakaplan, M. (Department of Chemistry, Faculty of Science, University of Dicle) ;
  • Ziyadanogullar, B. (Department of Chemistry, Faculty of Science, University of Dicle) ;
  • Ziyadanogullari, R. (Department of Chemistry, Faculty of Science, University of Dicle)
  • Received : 2010.10.09
  • Accepted : 2011.03.02
  • Published : 2011.05.20
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Abstract

A solvent extraction separation, preconcentration and determination of thorium with a new crown, 2-ethyl-N-benzyl-4,7,10,13,16-pentaoxa-1-azacyclooctadecane (MACE), is described in the study. The amount of thorium in the aqueous phase and organic phase was determined by Inductively Coupled Plasma-Optical Emission Spectroscopy and Ultraviolet-Visible, respectively. Thorium loaded organic phase was quantitatively stripped in a stage by using 1.0 M $HNO_3$. Thorium was effectively extracted with MACE in the pH range of 6-7 to produce a 3:2 complex ratio in the chloroform. A highly sensitive and rapid spectrophotometric method was described for determination of trace amounts of thorium with MACE. The effective molar absorption coefficient at 281 nm is $1.98{\times}10^3\;mol^{-1}cm^{-1}$, and the system complies with Beer's law in the range from 0.464 to 2.32 ${\mu}gm\;L^{-1}$ of thorium. Thorium was also determined in standard and environmental samples.

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References

  1. He, Q.; Chang, X.; Wu, Q.; Huang, X.; Hu, Z.; Zhai, Y. Analytica. Chimica. Acta 2007, 605, 192-197. https://doi.org/10.1016/j.aca.2007.10.026
  2. Shtangeeva, I.; Ayrault, S.; Jain, J. Environ. Radioactiv. 2005, 81, 283-293. https://doi.org/10.1016/j.jenvrad.2004.01.041
  3. Rao, T. P.; Matilda, P.; Gladis, J. M. Talanta 2006, 68, 1047-1064. https://doi.org/10.1016/j.talanta.2005.07.021
  4. Hicyilmaz, U.; Eral, M. J. Alloys Compd. 1998, 271-273, 620- 624. https://doi.org/10.1016/S0925-8388(98)00172-8
  5. Nash, K. L. Solvent Extr. and Ion Exch. 1993, 11, 729-768. https://doi.org/10.1080/07366299308918184
  6. Nash, K. L., Jensen, M., Gschneider, K. A., Eyring, L., Eds.; In Handbook of the Physics and Chemistry of Rare Earths; Elsevier: Amsterdam 2002; Chapter 180.
  7. Shariati, S.; Yamini, Y.; Zanjani, M. K.; Hazard, J. Mater. 2008, 156, 583-590.
  8. Aydin, F. A.; Soylak, M. Talanta 2007, 72, 187-192. https://doi.org/10.1016/j.talanta.2006.10.013
  9. Yonezawa, C.; Kurosawa, T. Bunseki Kagaku 1996, 45, 435-440. https://doi.org/10.2116/bunsekikagaku.45.435
  10. Prabhakaran, D.; Subramanian, M. S. Anal. Lett. 2003, 36, 2277- 2289. https://doi.org/10.1081/AL-120023718
  11. Zolotov, Y. A., Kuzmin, N. M., Shevla, G., Eds.; Elsevier: New York, Vol. XXV 1990; pp 11-45.
  12. Rydberg, J.; Musikas, C.; Choppin, G. R. Marcel Dekker, Inc.: New York, 1992; pp 11-513.
  13. Horwitz, E. P.; Chiarizia, R. In Chipmen, N. A., Wai, C. M., Eds.; CRC: Florida, 1996.
  14. Sabale, S. R.; Jadhav, D. V.; Mohite, B. S. Journal of Rare Earths 2009, 27(5), 825-829. https://doi.org/10.1016/S1002-0721(08)60343-9
  15. Hasegawa, Y.; Masuda, S. M.; Hirose, K. Ion-Pair Extraction of Lanthanoid(III) with Crown Ethers and Picrate Ion; Solvent Extr. Ion Exch. 1987, 5, 255-263. https://doi.org/10.1080/07366298708918565
  16. Zamani, A. A.; Yaftian, M. R. Separation and Purification Technology 2004, 40, 115-121. https://doi.org/10.1016/j.seppur.2004.01.012
  17. Gonzalez-Lorenzo, M.; Platas-Iglesias, C.; Mato-Iglesias, M.; Esteban-Gomez, D.; De Blas, A.; Rodriguez-Blas, T. Polyhedron 2008, 27, 1415-1422. https://doi.org/10.1016/j.poly.2008.01.004
  18. Magennis, S. W.; Craig, J.; Gardner, A.; Fucassi, F.; Cragg, P. J.; Robertson, N.; Parsons, S.; Pikramenou, Z. Polyhedron 2003, 22, 745-754. https://doi.org/10.1016/S0277-5387(02)01405-5
  19. Tsurubou, S.; Mizunati, M.; Kaduta, Y.; Yamamoto, T.; Umetani, S.; Sasaki, T.; Le, Q. T. H.; Matsui, M. Anal. Chem. 1995, 67, 1465-1476. https://doi.org/10.1021/ac00104a025
  20. Umetani, S.; Tsurubou, S.; Sasaki, T.; Komatsu, Y. Anal. Chim. Acta 1999, 394, 317-324. https://doi.org/10.1016/S0003-2670(99)00299-8
  21. Karakaplan, M.; Turgut, Y.; Aral, T.; Ho goren, H. Journal of Inclusion Phenomena and Macrocyclic Chemistry 2006, 54, 315- 319. https://doi.org/10.1007/s10847-005-9011-z
  22. Kondo, S.; Kinjo, T.; Yano, Y. Tetrahedron Letters 2005, 46, 3183-3186. https://doi.org/10.1016/j.tetlet.2005.03.054