DOI QR코드

DOI QR Code

Characterization of TiO2 Nanocrystalline Films for High Performance Dye-Sensitized Solar Cells

  • Jung, Heung-Joe (Department of Biotechnology and Life Science, Shin Gyeong University)
  • Received : 2011.05.03
  • Accepted : 2011.05.12
  • Published : 2011.06.25

Abstract

Titanium dioxide ($TiO_2$) thin films were deposited by the sol-gel method with a surfactant-assisted mechanism. Its application for dye-sensitized solar cells (DSSCs) was investigated. Brunauer-Emmett-Teller, X-ray diffraction and field emission scanning electron microscopy techniques were used to characterize the surface characteristics of thin films. Photovoltaic-current density measurements were performed to determine the photoelectrochemical properties of the thin films and the performance of DSSCs. Energy conversion efficiency of about 6.1% was achieved for cells with conductive glass under illumination with AM 1.5 (100 $mWcm^{-2}$) simulated sunlight. Investigation showed higher photo-energy conversion efficiency for mesoporous $TiO_2$ nanocrystalline films used in DSSCs relative to commercially available Degussa P25 films.

Keywords

References

  1. B. O'Regan and M. Gratzel, Nature 353, 737 (1991) [DOI: 10.1038/353737a0].
  2. M. Gratzel, Chem. Lett. 34, 8 (2005) [DOI: 10.1246/cl.2005.8].
  3. Y. Li, J. Hagen, W. Schaffrath, P. Otschik, and D. Haarer, Sol. Energy Mater. Sol. Cells 56, 167 (1999) [DOI: 10.1016/s0927-0248(98)00157-3].
  4. N. N. Dinh, N. T. T. Oanh, P. D. Long, M. C. Bernard, and A. Hugot-Le Goff, Thin Solid Films 423, 70 (2003) [DOI: 10.1016/s0040-6090(02)00948-3].
  5. K. H. Park and C. K. Hong, Electrochem. Commun. 10, 1187 (2008) [DOI: 10.1016/j.elecom.2008.05.046].
  6. W. J. Lee, D. Y. Lee, I. S. Kim, S. J. Jeong, and J. S. Song, Trans. Electr. Electron. Mater. 6, 140 (2005). https://doi.org/10.4313/TEEM.2005.6.4.140
  7. S. R. Scully, M. T. Lloyd, R. Herrera, E. P. Giannelis, and G. G. Malliaras, Synth. Met. 144, 291 (2004) [DOI: 10.1016/j.synthmet.2004.04.011].
  8. M. Ni, M. K. H. Leung, D. Y. C. Leung, and K. Sumathy, Sol. Energy Mater. Sol. Cells 90, 1331 (2006) [DOI: 10.1016/j.solmat.2005.08.006].
  9. B. K. Koo, D. Y. Lee, H. J. Kim, W. J. Lee, J. S. Song, and H. J. Kim, J. Electroceram. 17, 79 (2006) [DOI: 10.1007/s10832-006-9941-x].
  10. J. Yang, D. Li, X. Wang, X. Yang, and L. Lu, J. Solid State Chem. 165, 193 (2002) [DOI: 10.1006/jssc.2001.9526].
  11. W. Parrish and J. I. Langford, International Tables for Crystallography. Volume C: Mathematical, Physical and Chemical Tables, 3rd ed. ed. E. Prince (Springer, 2004) p. 42.
  12. L. X. Chen, T. Rajh, Z. Wang, and M. C. Thurnauer, J. Phys. Chem. B 101, 10688 (1997) [DOI: 10.1021/jp971930g].
  13. Z. Y. Wu, J. Zhang, K. Ibrahim, D. C. Xian, G. Li, Y. Tao, T. D. Hu, S. Bellucci, A. Marcelli, Q. H. Zhang, L. Gao, and Z. Z. Chen, Appl. Phys. Lett. 80, 2973 (2002) [DOI: 10.1063/1.1470699].

Cited by

  1. Research and Development Aspects on Chemical Preparation Techniques of Photoanodes for Dye Sensitized Solar Cells vol.2014, 2014, https://doi.org/10.1155/2014/518156
  2. Effect of oxygen partial pressure on properties of asymmetric bipolar pulse dc magnetron sputtered TiO_2 thin films vol.54, pp.13, 2015, https://doi.org/10.1364/AO.54.003817
  3. TiO2 nanofiber solid-state dye sensitized solar cells with thin TiO2 hole blocking layer prepared by atomic layer deposition vol.536, 2013, https://doi.org/10.1016/j.tsf.2013.03.029
  4. Gold Nanoparticles and Silicate Microsheet Modified Photoanode for Dye Sensitized Solar Cells vol.936, pp.1662-9752, 2018, https://doi.org/10.4028/www.scientific.net/MSF.936.77