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Measurement of Phosphorus in Soil and Water

  • Kim, Hye-Jin (Department of Bio-Environmental Chemistry, College of Agriculture and Life Sciences, Chungnam National University) ;
  • Hwang, Seong-Woo (Department of Bio-Environmental Chemistry, College of Agriculture and Life Sciences, Chungnam National University) ;
  • Chung, Doug-Young (Department of Bio-Environmental Chemistry, College of Agriculture and Life Sciences, Chungnam National University)
  • Received : 2011.07.19
  • Accepted : 2011.08.14
  • Published : 2011.08.31

Abstract

The relative focus about phosphorus (P) which causes eutrophication characterized by increased growth of undesirable algae has increased in recent years. Phosphorus forms in soil and water include both organic and inorganic forms. There are also a large number of soil P determination methods that have been designed to account for various types of P and mechanisms controlling the chemistry of P in soil, water, and residual materials for environmentally relevant forms of P. However, phosphorus forms in soil, water, and residual materials are also difficult to standardize with any reasonable consensus, due to the number of different disciplines involved. Hence, it is essential to accurately define how P can be measured in soil, water, or residual material samples to avoid potential misinterpretations or inappropriate recommendations in determining amount and types of P. Therefore, we reviewed the testing methods which have appeared in the scientific literature to provide an overview of the soil test P most commonly used.

Keywords

References

  1. Binkowski J. and P. Rutkowski. 1986. Elemental analysis of organic phosphorus compounds. X. Schoeniger-flask method for phosphorus. Mikrochim. Acta. I:245-247.
  2. Bray, R.H. and L.T. Kurtz. 1945. Determination of total, organic, and available forms of phosphorus in soils. Soil Sci. 59:39-45. https://doi.org/10.1097/00010694-194501000-00006
  3. Busman, L.M., R.P. Dick, and M.A. Tabatabai. 1983. Determination of Total Sulfur and Chlorine in Plant Materials by Ion Chromatography. Soil Sci. Soc. of Am. J. 47:1167-1170. https://doi.org/10.2136/sssaj1983.03615995004700060022x
  4. Christoff Van-M., E. Smolders, F. Degryse, L. Six, E. Vandamme, and R. Merckx. Comparison of colorimetric analysis, ion chromatography, ICP and DGT for model phosphorus solutions and natural water samples.
  5. de Boer, J.L.M., U. Kohlmeyer, P.M. Breugem, and T. van der Velde-Koerts. 1998. Determination of total dissolved phosphorus in water samples by axial inductively coupled plasma emission spectrometry. J. Anal. Chem. 360:132-136. https://doi.org/10.1007/s002160050660
  6. Grob, R.L. and M.E.P. McNally. 1980. Use of the lead(II) cation as precipitating agent in quantitative determination of phosphorus in organophosphorus compounds. Study of the lead phosphate - lead EDTA system. Anal. Lett. 13: 219-231. https://doi.org/10.1080/00032718008082556
  7. Gurley, T.W. and W.M. Ritchey. 1976. Analysis of organophosphorus compounds at the parts-per-million level by phosphorus-31 Fourier transform nuclear magnetic resonance spectroscopy Anal. Chem. 48:1137-1140. https://doi.org/10.1021/ac50002a018
  8. Jones, Jr. J.B. 2001. Laboratory guide for conducting soil tests and plant analysis. CRC Press.
  9. Kovar, J.L. and G.M. Pierzynski. 2009. Methods of Phosphorus Analysis for Soils, Sediments, Residuals, and Waters Second Edition. Southern Cooperative Series Bulletin No. 408.
  10. Kuo, S. 1996. Phosphorus. p. 869-919. In D.L. Sparks. (ed.). Methods of Soil Analysis: Part 3- Chemical Methods. SSSA, Madison, WI.
  11. Mallarino. A.P. 2003. Field calibration for corn of the Mehlich-3 soil phosphorus test with colorimetric and inductively coupled plasma emission spectroscopy determination methods. Soil Sci. Soc. Am. J. 68:1928-1934.
  12. Mehlich, A. 1984. Mehlich 3 soil test extractant: A modification of Mehlich 2 extractant. Comm. Soil Sci. Plant An. 15: 1409-1416. https://doi.org/10.1080/00103628409367568
  13. Murphy J. and J.P. Riley. 1962. A modified single solution method for the determination of phosphate in natural waters. Analytica Chimica Acta 27 (1962), pp. 31-36. https://doi.org/10.1016/S0003-2670(00)88444-5
  14. Myers R.G., A.N. Sharpley, S.J. Thien, and G.M. Pierzynski. 2005. Ion-Sink phosphorus extraction methods applied on 24 soils from the continental USA. Soil Sci. Soc. Am. J. 69:511- 521. https://doi.org/10.2136/sssaj2005.0511
  15. Novozamsky, I., D. van Dijk, J.J. van der Lee, and V.J.G. Houba. 1993. Automated determination of trace amounts of phosphate in soil extracts using malachite green. Commun. Soil Sci. Plant Anal., 24:10651076.
  16. Olsen, S.R., C.V. Cole, F.S. Watanabe, and L.A. Dean. 1954. Estimation of available phosphorus in soils by extraction with sodium bicarbonate. U.S. Dep. of Agric. Circ. 939.
  17. Pittman, J.J., H. Zhang, J.L. Schroder, and M.E. Payton. 2005. Differences of phosphorus in Mehlich 3 extracts determined by colorimetric and spectroscopic methods. Commun. Soil Sci. Plant Anal. 36:1641-1659. https://doi.org/10.1081/CSS-200059112
  18. Quinna, A.M., K.W.M. Siua, G.J. Gardnera, and S.S. Berman 1986, Determination of heteroatoms in organic compounds by ion chromatography after Schoniger flask decomposition. Journal of Chromatography A. 370:203-205. https://doi.org/10.1016/S0021-9673(00)94690-9
  19. Sharpley, A.N., S.J. Smith, O.R. Jones, W.A. Berg, and G.A. Coleman. 1992. The transport of bioavailable phosphorus in agricultural runoff. J. Environ. Qual. 21:30-35.
  20. Sharpley, A.N., T. Daniel, T. Sims, J. Lemunyon, R. Stevens, and R. Parry. 1999. Agriculture phosphorus and eutrophication. ARS-149, U.S. Dep. of Agric., Washington, D.C.
  21. Sharpley, A.N. 2000. Bioavailable phosphorus in soil. pp. 38-43. In G.M. Pierzynski (ed.), Methods for phosphorus analysis for soils, sediments, residuals, and waters. Southern Cooperative Series Bull. XXX.
  22. Sibbesen, E. and A.N. Sharpley. 1997. Setting and justifying upper critical limits for phosphorus in soils. p. 151-176. In H. Tunney et al., (ed.) Phosphorus Loss from Soil to Water. CAB International, London.
  23. Sims, J.T. 1993. Environmental soil testing for phosphorus. J. Prod. Agric. 6:501-507. https://doi.org/10.2134/jpa1993.0501
  24. Sims, J.T. and A.M. Wolf. 1995. Recommended soil testing procedures for the Northeastern United States. (2nd ed.). Bull. No. 493. Univ. Delaware, Newark, DE.
  25. Sims, J.T. 1997. Phosphorus soil testing: Innovations for water quality protection. p. 47-63. Proc. 5th Intl. Symp. Soil and Plant Analysis. Minneapolis, MN.
  26. Sims, J.T. 1998. Soil testing for phosphorus: Environmental uses and implications. So. Coop. Series Bull. No. 389. Univ. Delaware, Newark, DE.
  27. Sims, J.T., S.C. Hodges, and J. Davis. 1998. Soil testing for phosphorus: Current status and uses in nutrient management programs. p.13-20. In Sims, J.T. (ed.) 1998. Soil testing for phosphorus: Environmental uses and implications. So. Coop. Series Bull. No. 389. Univ. Delaware, Newark, DE.
  28. Sims, J.T., A.C. Edwards, O.F. Schoumans, and R.R. Simard. 2000. Integrating soil phosphorus testing into environmentally based agricultural management practices. J. Environ. Qual. 29:60-71
  29. Sirokia, M., G. Vujicica, V. Miluna, Z. Hudovskya, and L. Maric Determination of phosphorous in organic compounds and metal complexes by inductively-coupled plasma atomic emission spectrometry Analytica Chimica Acta Volume 192, 1987, Pages 175-182. https://doi.org/10.1016/S0003-2670(00)85702-5
  30. Soltanpour P.N., R.L. Fox, and R.C. Jones. 1987. A quick method to extract organic phosphorus from soils. Soil Sci. Soc. Am. J. 51:255-256. https://doi.org/10.2136/sssaj1987.03615995005100010052x
  31. Tanaka, T., K. Hiiro, A. Kawahara, and S. Wakida. 1983. イオンクロマトグラフィーによる次亜リン酸,亜リン酸及びリン酸イオンの定量. Bunseki Kagaku, 32:771-773. https://doi.org/10.2116/bunsekikagaku.32.12_771
  32. Tiessen, H., J. W.B. Stweart, and C.V. Cole. 1984. Pathways of Phosphorus Transformations in Soils of Differing Pedogenesis. Soil Science Society of America Journal 48:853-858. https://doi.org/10.2136/sssaj1984.03615995004800040031x
  33. Umalia, J.C., G.M. Morana, and P.R. Haddadb. 1995. Determination of phosphorus by sample combustion followed by non-suppressed ion chromatography. Journal of Chromatography A. 706:199-207. https://doi.org/10.1016/0021-9673(94)01160-G