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Evaluating Heavy Metal Stabilization Efficiency of Chemical Amendment in Agricultural Field: Field Experiment

안정화제 처리에 따른 중금속 오염 농경지 복원의 효율성 평가: 현장실증시험

  • Oh, Se-Jin (Department of Biological Environment, Kangwon National University) ;
  • Kim, Sung-Chul (Department of Biological Environment, Kangwon National University) ;
  • Yoon, Hyun-Soo (Department of Biological Environment, Kangwon National University) ;
  • Kim, Ha-Na (Department of Biological Environment, Kangwon National University) ;
  • Kim, Tae-Hwan (Department of Biological Environment, Kangwon National University) ;
  • Yeon, Kyu-Hun (Korea Mine Reclamation Corporation) ;
  • Lee, Jin-Soo (Korea Mine Reclamation Corporation) ;
  • Hong, Sung-Jo (Tae Seo, Inc.) ;
  • Yang, Jae-E. (Department of Biological Environment, Kangwon National University)
  • 오세진 (강원대학교 바이오자원환경학과) ;
  • 김성철 (강원대학교 바이오자원환경학과) ;
  • 윤현수 (강원대학교 바이오자원환경학과) ;
  • 김하나 (강원대학교 바이오자원환경학과) ;
  • 김태환 (강원대학교 바이오자원환경학과) ;
  • 연규훈 (한국광해관리공단) ;
  • 이진수 (한국광해관리공단) ;
  • 홍성조 ((주)태서산업) ;
  • 양재의 (강원대학교 바이오자원환경학과)
  • Received : 2011.11.20
  • Accepted : 2011.12.15
  • Published : 2011.12.31

Abstract

Residual of heavy metals originated from abandoned metal mines in agricultural field can cause adverse effect on ecosystem and eventually on human health. For this reason, remediation of heavy metal contaminated agriculture field is a critical issue. In this study, five different amendments, agriculture lime, dolomite, steel slag, zeolite, and compost, were evaluated for stabilization efficiency of heavy metals in agricultural field. Applied mixing ratio of amendments was varied (2% or 6%) depending on properties of amendments. Result showed that soil pH was increased compared to control (6.1-6.7) after mixing with amendments and ordered as dolomite (7.2~8.3) > steel slag (6.7~8.1) > agriculture lime (6.6~7.4) > zeolite (6.2~6.9) > compost (6.1~7.1). Among other amendments, agriculture lime, steel slag, and dolomite showed the highest stabilization efficiency of heavy metals in soil. For Cd, stabilization efficiency was 49~72%, 51~83%, and 0~36% for agriculture lime, steel slag, and dolomite respectively. In case of Pb, 43~64, 37~73%, and 51~73% of stabilization efficiency was observed for agriculture lime, steel slag, and dolomite respectively. However, minimal effect of heavy metal stabilization was observed for zeolite and compost. Based on result of this study, amendments that can increase the soil pH were the most efficient to stabilize heavy metal residuals and can be adapted for remediation purpose in agricultural field.

Keywords

References

  1. Adriano, D.C. 1986. Trace Elements in the Terrestrial Environment. Springer Verlag New York Inc. 390-420.
  2. Ahn, B.K., J.S. Park, E.H. Ha, and M.K. Kim. 2002. Speciation of Heavy Metals in Organic Solid Wastes during Composting. Journal of Waste Management. 19:740-748.
  3. Brookins D.G. 1988. Eh-pH Diagrams for Geochemistry. Springer-Verlag. Berlin. 200.
  4. Chung, D.Y. and H.H. Noh. 2005. Competitive Adsorption of Multi-species of Heavy Metals onto Sandy Clay Loam and Clay Soils. Korean J. Soil Sci. Fert. 38(5):238-246.
  5. Dermatas D. and X. Meng. 2003. Utilization of fly ash for stabilization /solidification of heavy metal contaminated soils. Enging. Geol.. 70:377-394. https://doi.org/10.1016/S0013-7952(03)00105-4
  6. Franchi A. and A.P. Davis. 1997. Desorption of cadmium (II) from artificially contaminated sediments. Water, Air, and Soil Pollution. 100:181-196. https://doi.org/10.1023/A:1018392022843
  7. Jeong, C.H. and S.J. Kim. 2002. Application of Statistical Model and Thermodynamic Analysis on Sorption of Heavy Metals by Bentonite. J. Engineering Geology. 12(2):203-214.
  8. Kim, H.G., S.B. Lee, and Y.D. Lee. 1998. Effect of Humic Acid for Cd Adsorption. Korean Journal of Environmental Engineers. 20(7):937-943.
  9. Kim, K.J. and J.W. Kim. 1981. A Study on the Use of Dolomite as a Water Treatment Aid. Korean Journal of Civil Engineers. 29(3):145-152.
  10. Kim, K.R., J.S. Park, M.S. Kim, N.I. Koo, S.H. Lee, J.S. Lee, S.C. Kim, J.E. Yang, and J.G. Kim. 2010. Changes of Heavy Metal Phytoavailability by Application of Immobilizing Agents and Soil Cover in the Upland Soil Nearby Abandoned Mining Area and Subsequent Metal Uptake by Red Pepper. Korean J. Soil Sci. Fert. 43(6):864-871.
  11. Kim, S.J., T.W. Kim, P.J. Kim, H.M. Roh, M. Park, C.W. Park, D.M. Sa, Y.K. Son, Y.S. Ok, W.G. Jeong, Y.S. Jeong, J.H. Joo, K.H. Han, S.H. Hyun, H.N. Hyun, and S.D. Hong. 2011. Elements of The Nature and Properties of Soils. 315-335.
  12. Kim, T.H. 2010. Efficiency of Chemical Remediation Technology and Stabilization Mechanism in Heavy Metal Contaminated Soil. Master Thesis, Kangwon National University. Chunchon, Korea.
  13. Ko, J.I., S.J. Park, S.H. Lee, and J.S. Lee. 2009. A Study on the Behaviors of Heavy Metals in Crop Fields Subsequent to the Remediation Project. J. Mine Reclam. Technol. 3(2):148-160.
  14. Lee, H.K., H.S. Jin, I.S. Hwang, and J.Y. Park. 2002. Prediction of Leaching Behavior of Steel Slag Using a Chemical Equilibrium Model. J. Waste Management. 19:79-87.Lee, H.K., H.S. Jin, I.S. Hwang, and J.Y. Park. 2002. Prediction of Leaching Behavior of Steel Slag Using a Chemical Equilibrium Model. J. Waste Management. 19:79-87.
  15. Lee, J.Y., Lee, C.H., Yoon, Y.S., Ha, B.Y., Jang, B.C., Lee, K.S., Lee, D.K., and Kim, P.J. 2005. Effects of Oyster-Shell Meal on Improving Spring Chinese Cabbage Productivity and Soil Properties. Korean J. Soil Sci. Fert. 38:274-280.
  16. Lee, M., Y. Lee, M. Yang, J. Kim, and S. Wang. 2008. Lime (CaO) and Limestone ($CaCO_3$) Treatment as the Stabilization Process for Contaminated Farmland Soil around Abamdoned Mine. Korea, Econ. Environ. Geol. 41(2):201-210.
  17. Lee, Y.D. and D.Y. Ko. 2007. A Study on the Removal of Heavy Metals Using Functional Group on the Surface of Discarded Automotive Tires. Journal of Environmental Engineers. 29(3):357-364.
  18. Lim, J.E., K.R. Kim, S.S. Lee, O.K. Kwon, J.E. Yang, and Y.S. Ok. 2010. Stabilization of As (arsenic(V) or roxarsone) Contaminated Soils using Zerovalent Iron and Basic Oxygen Furnace Slag. Korean J. Environmental Engineers. 32(6):555-562.
  19. Lim, S.K., C.Y. Chung, Y.S. Ok, and J.K. Kim. 2002. Competitive Adsorption of Cd and Cu on Surface of Humic Acid Extracted from Peat. Korean J. Soil Sci. Fert. 35:344-351.
  20. MOE (Ministry of Environment). 2002. The Korean standard method of environmental pollutions for soil pollution.
  21. Moon, D.H., K.H. Cheong, T.S. Kim, J.H. Kim, S.B. Choi, Y.S. Ok, and O.R. Moon. 2010. Stabilization of Pb Contaminated Army Firing Range Soil using Calcined Waste Oyster Shells. Korean J. Environmental Engineers. 32:185-192.
  22. Moon, Y.H., Y.G. Song, H.S. Moon, and Y.S. Zhang. 2010. Mobility of Metals in Tailings using a Column Experiment from the Guryong Copper Mine. Korean J. Soil Sci. Fert. 43(3):275-282.
  23. NIAST. 1988. Methods of soil chemical analysis. National Institute of Agricultural Science and Technology, RDA, Suwon, Korea.
  24. Nriagu J.O. and J.M. Pacyna. 1988, Quantitative assessment of worldwide contamination of air, water and soil by trace metal. Nature. 333:134-139. https://doi.org/10.1038/333134a0
  25. Paik, K.H., D.H. Kim, and S.H. Choi. 1997. Effect of Light Metal Ions and Competition among Heavy Metal Ions during the Adsorption of Heavy Metal Ions by Bark. Korea J. Environ. Agric. 16(2):115-118.
  26. Park, J.Y., H.A. Kim, J.Y. Kim, and K.W. Kim. 2009. Phytoremediation of Heavy Metal Contaminated Soil Using Brassica napus. J. Mine Reclam. Technol. 3(2):161-171.
  27. Pickering, W.F. 1982. Extraction of copper, lead, zinc or cadmium ions sorbed on calcium carbonate. Water, Air and Soil Pollution. 20:299-309.
  28. Rob, N., J. Comans, and J. Middelburg. 1987. Sorption of trace metals on calcite: Applicability of the surface precipitation model. Geochtmlcon Cosmochrmrca Acfa. 51:2587-2591.
  29. Song, H.K. 2004. Immobilization of Cadmium in the Paddy Soils Using the Chemical Remedial Agents. Master Thesis, Kangwon National University. Chunchon, Korea.
  30. Um, T.H. and Y.T. Kim. 2003. Stabilization Behavior of Heavy Metal ions by Treatment Conditions. J. Ceramic. 40(6):583-588.
  31. US EPA. 2007. The Use of Soil Amendments for Remedation, Revitalization, and Reuse. Solid Waste and Emergency Response. 5203.
  32. Yang, J.E., S.J. Lee, D.K. Kim, S.E. Oh, S.H. Yoon, and Y.S. Ok. 2008. Effect of Organic Matter and Moisture Content on Reduction of Cr(VI) in Soils by Zerovalent Iron. Korea J. Environ. Agric. 27(1):60-65. https://doi.org/10.5338/KJEA.2008.27.1.060
  33. Yang, J.E., S.J. Oh, T.H. Kim, S.C. Kim, D.K. Kim, and J.S. Lee. 2009. Remediation of Cd-contaminated paddy soil by layer reversing management combined with zero-valent iron and lime. J. Mine Reclam. Technol. 347-350.
  34. Yoo, K.Y., Y.S. Ok, and J.E. Yang. 2006. Mechanism and adsorption capacity of arsenic in water by zero-valent iron, Korean J. Soil Sci. Fert. 39:157-162.
  35. Young R.N., G. Mcdonald, and J. M. Randall. 1975. Effect of light metal ion on the sorption of heavy metal ions on natural polymer. J. Appl. Polm. Sci., 23: 1027-1035.
  36. Yun, S.W., H.G. Jin, S.I. Kang, S.J. Choi, Y.C. Lim, and C. Yu. 2010. A Comparison on the Effect of Soil Immprovement Methods for the Remediation of Heavy Metal Contaminated Farm Land Soil. J. Korean Geotec. Soci. 26(7):59-70.

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